GB602974A - Improvements in or relating to the production of aqueous solutions of polyvinyl acetate derivatives - Google Patents

Improvements in or relating to the production of aqueous solutions of polyvinyl acetate derivatives

Info

Publication number
GB602974A
GB602974A GB3043745A GB3043745A GB602974A GB 602974 A GB602974 A GB 602974A GB 3043745 A GB3043745 A GB 3043745A GB 3043745 A GB3043745 A GB 3043745A GB 602974 A GB602974 A GB 602974A
Authority
GB
United Kingdom
Prior art keywords
acid
partly
alkali
polyvinyl acetate
added
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3043745A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB3043745A priority Critical patent/GB602974A/en
Publication of GB602974A publication Critical patent/GB602974A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment

Abstract

Polyvinyl acetate is heated with a polybasic acid which has an alpha-beta dicarboxylic acid group, not more than one hydroxy group and if unsaturated has a cis formation, till a partially thickened alkali soluble mass is formed. This is washed free from acid, alkali is added to adjust the pH to 7 and the concentrated solution is diluted and caustic alkali added to give an alkali metal salt of an acid ester of a partially esterified polyvinyl alcohol in which the vinyl alcohol groups are partly acetylated, partly unreplaced and partly esterified with the polybasic acid. Acids specified are succinic, citric, malic, maleic and phthalic. More than one acid may be used and an anhydride and water may replace the acid. Addition of these products stabilises aqueous emulsions containing nitrocellulose, dyes, blown linseed and castor oil, butyl alcohol, ethyl and butyl acetates, toluene and methyl cyclohexanone. Specification 552,011 is referred to.
GB3043745A 1945-11-14 1945-11-14 Improvements in or relating to the production of aqueous solutions of polyvinyl acetate derivatives Expired GB602974A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB3043745A GB602974A (en) 1945-11-14 1945-11-14 Improvements in or relating to the production of aqueous solutions of polyvinyl acetate derivatives

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3043745A GB602974A (en) 1945-11-14 1945-11-14 Improvements in or relating to the production of aqueous solutions of polyvinyl acetate derivatives

Publications (1)

Publication Number Publication Date
GB602974A true GB602974A (en) 1948-06-07

Family

ID=10307668

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3043745A Expired GB602974A (en) 1945-11-14 1945-11-14 Improvements in or relating to the production of aqueous solutions of polyvinyl acetate derivatives

Country Status (1)

Country Link
GB (1) GB602974A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE953119C (en) * 1952-01-30 1956-11-29 Ici Ltd Process for the preparation of vinyl chloride polymers
EP0046813B1 (en) * 1980-08-21 1984-06-06 Toray Industries, Inc. A semipermeable membrane
WO2003016359A2 (en) * 2001-08-18 2003-02-27 Clariant Gmbh Partially cross-linked polyvinyl alcohol
EP1437369A1 (en) * 2003-01-07 2004-07-14 Clariant GmbH Partially crosslinked polyvinyl alcohol

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE953119C (en) * 1952-01-30 1956-11-29 Ici Ltd Process for the preparation of vinyl chloride polymers
EP0046813B1 (en) * 1980-08-21 1984-06-06 Toray Industries, Inc. A semipermeable membrane
WO2003016359A2 (en) * 2001-08-18 2003-02-27 Clariant Gmbh Partially cross-linked polyvinyl alcohol
WO2003016359A3 (en) * 2001-08-18 2003-11-20 Clariant Gmbh Partially cross-linked polyvinyl alcohol
US6960627B2 (en) 2001-08-18 2005-11-01 Clariant Gmbh Partially cross-linked polyvinyl alcohol
EP1437369A1 (en) * 2003-01-07 2004-07-14 Clariant GmbH Partially crosslinked polyvinyl alcohol

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