GB568180A - Improvements in or relating to tanning compositions and processes for tanning - Google Patents
Improvements in or relating to tanning compositions and processes for tanningInfo
- Publication number
- GB568180A GB568180A GB536243A GB536243A GB568180A GB 568180 A GB568180 A GB 568180A GB 536243 A GB536243 A GB 536243A GB 536243 A GB536243 A GB 536243A GB 568180 A GB568180 A GB 568180A
- Authority
- GB
- United Kingdom
- Prior art keywords
- tanning
- sodium
- acid
- compositions
- silicate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C3/00—Tanning; Compositions for tanning
- C14C3/02—Chemical tanning
- C14C3/04—Mineral tanning
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Coloring (AREA)
Abstract
568,180. Tanning compositions. IMPERIAL CHEMICAL INDUSTRIES, Ltd. (Du Pont de Xemours & Co., E.!.). April 3, 1943, No. 5362. [Class i6] [Also in Group III] Solid tanning compositions, adapted to be dissolved in acid to produce a modified silicic acid sol, comprise a hydrogen bonding agent and an acid-soluble double silicate of an alkali metal and aluminium, chromium, iron, zinc, titanium, or zirconium. The term " hydrogen bonding agent " is used to refer to organic compounds which form co-ordination compounds with silicic acid, and which are at least slightly soluble in water without raising the pH of the silicic acid solution above 7. A list of suitable compounds, comprising ethers, amides, ketones, alcohols and esters, is given. Examples describe the use of urea, nonaethylene glycol, tri-butyl phosphate and carbitol acetate. Silicates which may be used in the compositions are those occurring naturally, such as laumonite, analcite, natrolite, nethelite, compounds such as sodium calcium aluminium silicate, or substances prepared as described in U.S.A. Specifications 1,949,360 and 2,244,383, or by heating kaolin with sodium hydroxide solution. Sodium aluminium silicates having an Al2O3: SiO2 molar ratio from about 1 : 2 to 1 : 5 are preferably used, and may be prepared by adding a solution of any aluminium salt more soluble than the reaction product to a solution of a sodium silicate. When the SiO2 : Na2O ratio of the silicate is high, alkali, e.g. sodiwn, or potassium hydroxide, calcium oxide, barium oxide, or an organic base such as tetraethanolammonium hydroxide is added to maintain a pH of 9 or more. The use of aluminium sulphate, hydroxide, nitrate and chloride, and of sodium aluminate is referred to, and in examples, sodium silicate and metasilicate are used. Double silicates of any alkali metal and chromium, iron, zinc, titanium and zirconium may be prepared similarly. The tanning composition may also contain masking agents such as lactates, acetates, propionates, tartrates, glycollates, citrates, oxalates, adipates, succinates or glutarates of sodium, potassium, ammonium or an alkaline earth metal. Other tanning agents and assistants may be added. Acids suitable for dissolving the compositions to give tanning solutions are sulphuric, hydrochloric, nitric, acetic or lactic acids or a thionic acid. Solid acids or acid salts such as sulphamic acid, sodium bisulphate, monosodium phosphate, acid tartrates, zinc chloride, titanium, aluminium or chromium sulphates may be included in the compositions, and in this case either the acid or the silicate may be coated with an inert substance such as calcium stearate and the mixture may be compressed into briquettes to prevent segregation. In tanning with the compositions described, it is sometimes preferable that the pH of the skins to be treated should be adjusted to approximately that of the tanning solution. To increase the speed of tanning, the pH of the solution may be raised by the addition of sodium carbonate, other alkali metal or ammonium hydroxides or carbonates, or organic bases such as ethanolamines.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB536243A GB568180A (en) | 1943-04-03 | 1943-04-03 | Improvements in or relating to tanning compositions and processes for tanning |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB536243A GB568180A (en) | 1943-04-03 | 1943-04-03 | Improvements in or relating to tanning compositions and processes for tanning |
Publications (1)
Publication Number | Publication Date |
---|---|
GB568180A true GB568180A (en) | 1945-03-22 |
Family
ID=9794675
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB536243A Expired GB568180A (en) | 1943-04-03 | 1943-04-03 | Improvements in or relating to tanning compositions and processes for tanning |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB568180A (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2732217A1 (en) * | 1977-07-16 | 1979-02-01 | Henkel Kgaa | USE OF FINE-PIECE WATER-INSOLUBLE ALKALIAL ALUMINUM SILICATES IN THE MANUFACTURING OF LEATHER |
DE2822075A1 (en) * | 1978-05-20 | 1979-11-22 | Henkel Kgaa | Water-insoluble aluminium silicate used in leather mfr. - contain alkali-, di:- and tri:valent ions and have coarser particle size |
DE2822073A1 (en) * | 1978-05-20 | 1979-11-22 | Henkel Kgaa | Water-insoluble partly acid-soluble aluminium silicate - used in leather mfr., contains alkali metal and di:- and/or tri:valent cation |
DE2822072A1 (en) * | 1978-05-20 | 1979-11-29 | Henkel Kgaa | USE OF WATER-INSOLUBLE ALUMINUM SILICATES IN THE MANUFACTURING OF LEATHER |
DE2822076A1 (en) * | 1978-05-20 | 1979-11-29 | Henkel Kgaa | Use of water-insoluble aluminosilicate cpds. in leather mfr. - e.g. in defatting and pre-tanning of hides, tanning of furs and leather, and neutralisation of leather |
DE2832089A1 (en) * | 1978-07-21 | 1980-01-31 | Henkel Kgaa | USE OF WATER-INSOLUBLE ALUMINUM SILICATES AS TANE IN FUR-MAKING |
DE2831846A1 (en) * | 1978-07-20 | 1980-02-07 | Henkel Kgaa | USE OF WATER-INSOLUBLE ALUMINUM SILICATES IN LEATHER PRODUCTION |
US4272242A (en) * | 1977-07-16 | 1981-06-09 | Henkel Kommanditgesellschaft Auf Aktien | Use of water-insoluble aluminosilicates in tanning process for the production of leather |
WO2004048616A1 (en) * | 2002-11-26 | 2004-06-10 | Basf Aktiengesellschaft | Method for producing a leather semi-finished product |
CN104046707A (en) * | 2014-06-30 | 2014-09-17 | 四川大学 | Iron-zirconium-aluminum compound tanning agent and preparation method thereof |
-
1943
- 1943-04-03 GB GB536243A patent/GB568180A/en not_active Expired
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2732217A1 (en) * | 1977-07-16 | 1979-02-01 | Henkel Kgaa | USE OF FINE-PIECE WATER-INSOLUBLE ALKALIAL ALUMINUM SILICATES IN THE MANUFACTURING OF LEATHER |
US4272242A (en) * | 1977-07-16 | 1981-06-09 | Henkel Kommanditgesellschaft Auf Aktien | Use of water-insoluble aluminosilicates in tanning process for the production of leather |
DE2822075A1 (en) * | 1978-05-20 | 1979-11-22 | Henkel Kgaa | Water-insoluble aluminium silicate used in leather mfr. - contain alkali-, di:- and tri:valent ions and have coarser particle size |
DE2822073A1 (en) * | 1978-05-20 | 1979-11-22 | Henkel Kgaa | Water-insoluble partly acid-soluble aluminium silicate - used in leather mfr., contains alkali metal and di:- and/or tri:valent cation |
DE2822072A1 (en) * | 1978-05-20 | 1979-11-29 | Henkel Kgaa | USE OF WATER-INSOLUBLE ALUMINUM SILICATES IN THE MANUFACTURING OF LEATHER |
DE2822076A1 (en) * | 1978-05-20 | 1979-11-29 | Henkel Kgaa | Use of water-insoluble aluminosilicate cpds. in leather mfr. - e.g. in defatting and pre-tanning of hides, tanning of furs and leather, and neutralisation of leather |
DE2831846A1 (en) * | 1978-07-20 | 1980-02-07 | Henkel Kgaa | USE OF WATER-INSOLUBLE ALUMINUM SILICATES IN LEATHER PRODUCTION |
DE2832089A1 (en) * | 1978-07-21 | 1980-01-31 | Henkel Kgaa | USE OF WATER-INSOLUBLE ALUMINUM SILICATES AS TANE IN FUR-MAKING |
WO2004048616A1 (en) * | 2002-11-26 | 2004-06-10 | Basf Aktiengesellschaft | Method for producing a leather semi-finished product |
US7753964B2 (en) | 2002-11-26 | 2010-07-13 | Basf Aktiengesellschaft | Method for producing a leather semi-finished product |
CN104046707A (en) * | 2014-06-30 | 2014-09-17 | 四川大学 | Iron-zirconium-aluminum compound tanning agent and preparation method thereof |
CN104046707B (en) * | 2014-06-30 | 2016-05-11 | 四川大学 | Iron-zirconium-aluminium coordinates tanning agent and preparation method thereof |
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