GB566795A - Improvements in and relating to the production of relief images - Google Patents
Improvements in and relating to the production of relief imagesInfo
- Publication number
- GB566795A GB566795A GB595743A GB595743A GB566795A GB 566795 A GB566795 A GB 566795A GB 595743 A GB595743 A GB 595743A GB 595743 A GB595743 A GB 595743A GB 566795 A GB566795 A GB 566795A
- Authority
- GB
- United Kingdom
- Prior art keywords
- monomers
- composition
- relief
- solvent
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
Landscapes
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- General Physics & Mathematics (AREA)
- Polymerisation Methods In General (AREA)
- Photosensitive Polymer And Photoresist Processing (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
A relief image is produced by polymerizing to a rigid article a liquid polymerizable ethenoid composition, preferably containing a polymerization catalyst, by means of heat and/or light rays passed through a suitable image bearing transparency, and subsequently developing the latent image produced by heat or treatment with a solvent for the polymerized composition. The degree of polymerization in the rigid polymer varies according to the intensity of light to which it is subjected, and the variation is converted into a surface relief, (1) by heating (causing the under-polymerized material to shrink) or (2) treatment with a solvent with consequent preferential dissolution of the underpolymerized material. By a liquid polymerizable ethenoid composition is intended a monomer containing one or more CH2=C< groups or a mixture of such monomers, or a solution in such monomers of one or more polymers or partial polymers of such monomers. Specified are methyl acrylate, methacrylate and chloracrylate, vinyl acetate and styrene with or without dyes, pigments, fillers, plasticizers and inhibitors. Catalysts specified are benzoyl and lauroyl peroxides, benzoin and diacetyl. Solvents mentioned for the development of the relief image are an 80 : 20 mixture of methyl and n-butyl alcohol and 10 per cent solution of caustic soda.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB595743A GB566795A (en) | 1943-04-14 | 1943-04-14 | Improvements in and relating to the production of relief images |
FR917046D FR917046A (en) | 1943-04-14 | 1945-11-06 | Production of relief images |
DEP260A DE807894C (en) | 1943-04-14 | 1948-10-21 | Process for the production of relief images |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB595743A GB566795A (en) | 1943-04-14 | 1943-04-14 | Improvements in and relating to the production of relief images |
Publications (1)
Publication Number | Publication Date |
---|---|
GB566795A true GB566795A (en) | 1945-01-15 |
Family
ID=9805808
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB595743A Expired GB566795A (en) | 1943-04-14 | 1943-04-14 | Improvements in and relating to the production of relief images |
Country Status (3)
Country | Link |
---|---|
DE (1) | DE807894C (en) |
FR (1) | FR917046A (en) |
GB (1) | GB566795A (en) |
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2760863A (en) * | 1951-08-20 | 1956-08-28 | Du Pont | Photographic preparation of relief images |
US2902365A (en) * | 1956-08-14 | 1959-09-01 | Du Pont | Photopolymerizable compositions and elements and process of making reliefs therefrom |
US3038800A (en) * | 1957-12-19 | 1962-06-12 | Eastman Kodak Co | Photopolymerization of olefinicallyunsaturated monomers by silver halides |
US3047422A (en) * | 1956-01-09 | 1962-07-31 | Miehle Goss Dexter Inc | Coating material and method of drying same |
DE1140080B (en) * | 1957-02-18 | 1962-11-22 | Du Pont | Plate for the production of relief printing forms by photopolymerization |
US3663222A (en) * | 1968-06-06 | 1972-05-16 | Asahi Chemical Ind | Process for preparing steric block with liquid photopolymerizable composition |
US3678850A (en) * | 1966-05-02 | 1972-07-25 | Xerox Corp | Porous printing plate prepared from particulate photosensitive resinous material |
US3944417A (en) * | 1968-11-27 | 1976-03-16 | Hoechst Aktiengesellschaft | Process for the electrophotographic production of printing plates |
US4294782A (en) * | 1979-04-10 | 1981-10-13 | Jerome Bauer | Method for substantially instantaneous liquid molding of an article |
US4929402A (en) * | 1984-08-08 | 1990-05-29 | 3D Systems, Inc. | Method for production of three-dimensional objects by stereolithography |
US5071337A (en) * | 1990-02-15 | 1991-12-10 | Quadrax Corporation | Apparatus for forming a solid three-dimensional article from a liquid medium |
US5174943A (en) * | 1984-08-08 | 1992-12-29 | 3D Systems, Inc. | Method for production of three-dimensional objects by stereolithography |
US5213949A (en) * | 1986-11-12 | 1993-05-25 | Asahi Kasei Kogyo Kabushiki Kaisha | Method for selectively curing a liquid photosensitive resin by masking exposure |
US5236637A (en) * | 1984-08-08 | 1993-08-17 | 3D Systems, Inc. | Method of and apparatus for production of three dimensional objects by stereolithography |
US5344298A (en) * | 1984-08-08 | 1994-09-06 | 3D Systems, Inc. | Apparatus for making three-dimensional objects by stereolithography |
US5358673A (en) * | 1990-02-15 | 1994-10-25 | 3D Systems, Inc. | Applicator device and method for dispensing a liquid medium in a laser modeling machine |
US5554336A (en) * | 1984-08-08 | 1996-09-10 | 3D Systems, Inc. | Method and apparatus for production of three-dimensional objects by stereolithography |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE536847A (en) * | 1954-03-26 | |||
DE1200130B (en) * | 1955-08-22 | 1965-09-02 | Du Pont | Photopolymerizable layer for the production of relief images or printing forms |
DE1205386B (en) * | 1955-10-03 | 1965-11-18 | Du Pont | Photopolymerizable layer for the production of relief images or printing forms |
BE582954A (en) * | 1958-12-30 | |||
DE1772662B1 (en) * | 1968-06-15 | 1971-10-14 | Asahi Chemical Ind | Process for the photographic production of a relief plate bearing a photopolymerizate three-dimensional image |
US4431263A (en) * | 1979-06-25 | 1984-02-14 | University Patents, Inc. | Novel nonlinear optical materials and processes employing diacetylenes |
-
1943
- 1943-04-14 GB GB595743A patent/GB566795A/en not_active Expired
-
1945
- 1945-11-06 FR FR917046D patent/FR917046A/en not_active Expired
-
1948
- 1948-10-21 DE DEP260A patent/DE807894C/en not_active Expired
Cited By (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2760863A (en) * | 1951-08-20 | 1956-08-28 | Du Pont | Photographic preparation of relief images |
US2791504A (en) * | 1951-08-20 | 1957-05-07 | Du Pont | Photopolymerizable elements |
DE1093209B (en) * | 1951-08-20 | 1960-11-17 | Du Pont | Photosensitive material and process for making relief images for printing |
US3047422A (en) * | 1956-01-09 | 1962-07-31 | Miehle Goss Dexter Inc | Coating material and method of drying same |
US2902365A (en) * | 1956-08-14 | 1959-09-01 | Du Pont | Photopolymerizable compositions and elements and process of making reliefs therefrom |
DE1140080B (en) * | 1957-02-18 | 1962-11-22 | Du Pont | Plate for the production of relief printing forms by photopolymerization |
US3038800A (en) * | 1957-12-19 | 1962-06-12 | Eastman Kodak Co | Photopolymerization of olefinicallyunsaturated monomers by silver halides |
US3678850A (en) * | 1966-05-02 | 1972-07-25 | Xerox Corp | Porous printing plate prepared from particulate photosensitive resinous material |
US3663222A (en) * | 1968-06-06 | 1972-05-16 | Asahi Chemical Ind | Process for preparing steric block with liquid photopolymerizable composition |
US3944417A (en) * | 1968-11-27 | 1976-03-16 | Hoechst Aktiengesellschaft | Process for the electrophotographic production of printing plates |
US4294782A (en) * | 1979-04-10 | 1981-10-13 | Jerome Bauer | Method for substantially instantaneous liquid molding of an article |
US5571471A (en) * | 1984-08-08 | 1996-11-05 | 3D Systems, Inc. | Method of production of three-dimensional objects by stereolithography |
US5569431A (en) * | 1984-08-08 | 1996-10-29 | 3D Systems, Inc. | Method and apparatus for production of three-dimensional objects by stereolithography |
US5174943A (en) * | 1984-08-08 | 1992-12-29 | 3D Systems, Inc. | Method for production of three-dimensional objects by stereolithography |
US6027324A (en) * | 1984-08-08 | 2000-02-22 | 3D Systems, Inc. | Apparatus for production of three dimensional objects by stereolithography |
US5236637A (en) * | 1984-08-08 | 1993-08-17 | 3D Systems, Inc. | Method of and apparatus for production of three dimensional objects by stereolithography |
US5344298A (en) * | 1984-08-08 | 1994-09-06 | 3D Systems, Inc. | Apparatus for making three-dimensional objects by stereolithography |
US5814265A (en) * | 1984-08-08 | 1998-09-29 | 3D Systems, Inc. | Method and apparatus for production of three-dimensional objects by stereolithography |
US5554336A (en) * | 1984-08-08 | 1996-09-10 | 3D Systems, Inc. | Method and apparatus for production of three-dimensional objects by stereolithography |
US5556590A (en) * | 1984-08-08 | 1996-09-17 | 3D Systems, Inc. | Apparatus for production of three-dimensional objects by stereolithography |
US5785918A (en) * | 1984-08-08 | 1998-07-28 | Seagate Technology, Inc. | Method and apparatus for production of three-dimensional objects by stereolithography |
US4929402A (en) * | 1984-08-08 | 1990-05-29 | 3D Systems, Inc. | Method for production of three-dimensional objects by stereolithography |
US5573722A (en) * | 1984-08-08 | 1996-11-12 | 3D Systems, Inc. | Method and apparatus for production of three-dimensional objects by stereolithography |
US5630981A (en) * | 1984-08-08 | 1997-05-20 | 3D Systems, Inc. | Method for production of three-dimensional objects by stereolithography |
US5762856A (en) * | 1984-08-08 | 1998-06-09 | Hull; Charles W. | Method for production of three-dimensional objects by stereolithography |
US5779967A (en) * | 1984-08-08 | 1998-07-14 | 3D Systems, Inc. | Method and apparatus for production of three-dimensional objects by stereolithography |
US5213949A (en) * | 1986-11-12 | 1993-05-25 | Asahi Kasei Kogyo Kabushiki Kaisha | Method for selectively curing a liquid photosensitive resin by masking exposure |
US5071337A (en) * | 1990-02-15 | 1991-12-10 | Quadrax Corporation | Apparatus for forming a solid three-dimensional article from a liquid medium |
US5358673A (en) * | 1990-02-15 | 1994-10-25 | 3D Systems, Inc. | Applicator device and method for dispensing a liquid medium in a laser modeling machine |
Also Published As
Publication number | Publication date |
---|---|
FR917046A (en) | 1946-12-23 |
DE807894C (en) | 1951-07-09 |
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