GB475552A - Improvements in and relating to the manufacture of polymerisation products - Google Patents
Improvements in and relating to the manufacture of polymerisation productsInfo
- Publication number
- GB475552A GB475552A GB1406936A GB1406936A GB475552A GB 475552 A GB475552 A GB 475552A GB 1406936 A GB1406936 A GB 1406936A GB 1406936 A GB1406936 A GB 1406936A GB 475552 A GB475552 A GB 475552A
- Authority
- GB
- United Kingdom
- Prior art keywords
- produced
- esters
- benzoyl peroxide
- vinyl
- polymerized
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004519 manufacturing process Methods 0.000 title 1
- 239000004342 Benzoyl peroxide Substances 0.000 abstract 11
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 abstract 11
- 235000019400 benzoyl peroxide Nutrition 0.000 abstract 11
- 150000002148 esters Chemical class 0.000 abstract 11
- 239000000203 mixture Substances 0.000 abstract 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 10
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 abstract 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 10
- 239000007788 liquid Substances 0.000 abstract 10
- 229920000642 polymer Polymers 0.000 abstract 9
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 7
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 7
- 239000011248 coating agent Substances 0.000 abstract 5
- 238000000576 coating method Methods 0.000 abstract 5
- 229910052742 iron Inorganic materials 0.000 abstract 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 abstract 4
- 238000000034 method Methods 0.000 abstract 4
- 238000006116 polymerization reaction Methods 0.000 abstract 4
- 239000007787 solid Substances 0.000 abstract 4
- 239000001828 Gelatine Substances 0.000 abstract 3
- 238000001035 drying Methods 0.000 abstract 3
- 229920000159 gelatin Polymers 0.000 abstract 3
- 235000019322 gelatine Nutrition 0.000 abstract 3
- 239000003921 oil Substances 0.000 abstract 3
- 150000002894 organic compounds Chemical class 0.000 abstract 3
- 229920001568 phenolic resin Polymers 0.000 abstract 3
- 230000000379 polymerizing effect Effects 0.000 abstract 3
- 229920002689 polyvinyl acetate Polymers 0.000 abstract 3
- 239000011118 polyvinyl acetate Substances 0.000 abstract 3
- 239000000344 soap Substances 0.000 abstract 3
- 239000004902 Softening Agent Substances 0.000 abstract 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 2
- 230000001464 adherent effect Effects 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 229920002678 cellulose Polymers 0.000 abstract 2
- 229920003086 cellulose ether Polymers 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- -1 chlorcaoutchouc Polymers 0.000 abstract 2
- 239000004744 fabric Substances 0.000 abstract 2
- 239000000945 filler Substances 0.000 abstract 2
- 239000011521 glass Substances 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 abstract 2
- AUBDSFLQOBEOPX-UHFFFAOYSA-N hexa-1,5-dien-3-yne Chemical group C=CC#CC=C AUBDSFLQOBEOPX-UHFFFAOYSA-N 0.000 abstract 2
- 238000007654 immersion Methods 0.000 abstract 2
- 239000011261 inert gas Substances 0.000 abstract 2
- 150000002576 ketones Chemical class 0.000 abstract 2
- 125000005395 methacrylic acid group Chemical class 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract 2
- 229920001290 polyvinyl ester Polymers 0.000 abstract 2
- 229920005989 resin Polymers 0.000 abstract 2
- 239000011347 resin Substances 0.000 abstract 2
- 239000012265 solid product Substances 0.000 abstract 2
- 239000007858 starting material Substances 0.000 abstract 2
- 229920001567 vinyl ester resin Polymers 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/02—Polymerisation in bulk
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C39/00—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
- B29C39/003—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor characterised by the choice of material
- B29C39/006—Monomers or prepolymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/003—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor characterised by the choice of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/02—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
- B29C41/04—Rotational or centrifugal casting, i.e. coating the inside of a mould by rotating the mould
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2025/00—Use of polymers of vinyl-aromatic compounds or derivatives thereof as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2029/00—Use of polyvinylalcohols, polyvinylethers, polyvinylaldehydes, polyvinylketones or polyvinylketals or derivatives thereof as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2031/00—Use of polyvinylesters or derivatives thereof as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2033/00—Use of polymers of unsaturated acids or derivatives thereof as moulding material
- B29K2033/04—Polymers of esters
Abstract
Liquid monomeric or partially polymerized vinyl compounds are polymerized or partially polymerized during subjection to centrifugal force, followed in the latter case by heating. Vinyl compounds specified are acrylic and methacrylic acids and their esters, organic and inorganic vinyl esters, vinyl ethers and ketones, divinyl acetylene, styrene, and itaconic esters; singly or in admixture. There may also be present dyestuffs, fillers, turbidifying agents, softening agents, natural and artificial resins, chlorcaoutchouc, cellulose ethers and esters, and inserts, e.g. of fabric or wire. The centrifugal force may be produced by rotation of the polymerization chamber about its own or another axis, e.g. tubes are produced by rotating a cylindrical chamber about its axis, disposed horizontally or vertically. The hollow or other bodies produced, e.g. tubes, rods, or blocks, may be released from the chamber, e.g. by immersion in liquids, e.g. water or by the use of an auxiliary coating on the chamber wall. The process may be carried out continuously, e.g. liquid monomer may be continuously passed into a rotating tube, to produce a rod or tube; under normal, reduced, or increased pressure, e.g. in the presence of inert gases under pressure; at an increased temperature; and in the presence of catalysts, light, or both. Films may be produced by skiving from tubes produced in tubular moulds. In lining containers a primer may be used, e.g. gelatine, drying oils, soap, phenol-formaldehyde resins, alone or mixed with polymers such as polyacrylic esters or polyvinyl acetate, or p a single coating of an adherent polymer may be applied, e.g. of polyacrylic esters or polyvinyl esters. In examples: (1) an internally highly-polished iron or glass tube, 25 per cent filled with a mixture of methyl methacrylate, di-n-butyl phthalate and benzoyl peroxide, is rotated about its axis, a tube of polymer being obtained; (2) an iron cylinder as in example 1 is first 2 per cent filled with methyl acrylate and benzoyl peroxide, and this is polymerized to form a layer, then a further layer may be produced by polymerizing methyl methacrylate or styrene or mixtures thereof; (3) as in example 1, but as starting material there is used a mixture of methyl acrylate, vinyl chloride, and benzoyl peroxide, and the process is carried out under a nitrogen pressure of 20 atmospheres; (4) a centrifuge has two opposite cylindrical containers rotated about an axis such that the centrifugal force acts perpendicularly to the bases thereof, the containers being 80 per cent filled with vinyl acetate and benzoyl peroxide, and two cylindrical bodies are produced; (5) apparatus is used as in example 4, but concentric pairs of cylinders are used, and methyl methacrylate and benzoyl peroxide are polymerized therein to produce hollow bodies. The Provisional Specification refers to the use of liquid unsaturated organic compounds or mixtures containing them which upon polymerization yield solid or semi-solid products.ALSO:Liquid monomeric or partially polymerized vinyl compounds are polymerized during subjection to centrifugal force. In lining containers a primer may be used, e.g. gelatine, drying oils, soap, phenol-formaldehyde resins, alone or mixed with polymers such as polyacrylic esters or polyvinyl acetate. In an example: an internally highly - polished iron cylinder, 2 per cent filled with a mixture of methyl acrylate and benzoyl peroxide, is rotated about its axis and a coating of polymer produced which is covered with a further layer by polymerizing methyl methacrylate or styrene or mixtures thereof. The Provisional Specification refers to the use of liquid unsaturated organic compounds or mixtures containing them yielding solid or semi-solid polymers.ALSO:Liquid monomeric or partially polymerized vinyl compounds are polymerized or partially polymerized during subjection to centrifugal force, followed in the latter case by heating. Vinyl compounds specified are acrylic and methacrylic acids and their esters, organic and inorganic vinyl esters, vinyl ethers and ketones, divinyl acetylene, styrene, and itaconic esters; singly or in admixture. There may also be present dyestuffs, fillers, turbidifying agents, softening agents, natural and artificial resins, chlorcaoutchouc, cellulose ethers and esters, and inserts, e.g. of fabric or wire. The centrifugal force may be produced by rotation of the polymerization chamber about its own or another axis, e.g. tubes are produced by rotating a cylindrical chamber about its axis, disposed horizontally or vertically. The hollow or other bodies produced, e.g. tubes, rods, or blocks, may be released from the chamber, e.g. by immersion in liquids, e.g. water or by the use of an auxiliary coating on the chamber wall. The process may be carried out continuously, e.g. liquid monomer may be continuously passed into a rotating tube, to produce a rod or tube; under normal, reduced, or increased pressure, e.g. in the presence of inert gases under pressure; at an increased temperature; and in the presence of catalysts, light, or both. Films may be produced by skiving from tubes produced in tubular moulds. In lining containers a primer may be used, e.g. gelatine, drying oils, soap, phenol-formaldehyde resins, alone or mixed with polymers such as polyacrylic esters or polyvinyl acetate, or a single coating of an adherent polymer may be applied, e.g. of polyacrylic esters or polyvinyl esters. In examples: (1) an internally highly polished iron or glass tube, 25 per cent filled with a mixture of methyl methacrylate, di-n-butyl phthalate and benzoyl peroxide, is rotated about its axis, a tube of polymer being obtained: (2) an iron cylinder as in example 1 is first 2 per cent filled with methyl acrylate and benzoyl peroxide, and this is polymerized to form a layer, then a further layer may be produced by polymerizing methyl methacrylate or styrene or mixtures thereof; (3) as in example 1, but as starting material there is used a mixture of methyl acrylate, vinyl chloride, and benzoyl peroxide and the process is carried out under a nitrogen pressure of 20 atmospheres; (4) a centrifuge has two opposite cylindrical containers rotated about an axis such that the centrifugal force acts perpendicularly to the bases thereof, the containers being 80 per cent filled with vinyl acetate and benzoyl peroxide, and two cylindrical bodies are produced; (5) apparatus is used as in example 4, but concentric pairs of cylinders are used and methyl methacrylate and benzoyl peroxide are polymerized therein to produce hollow bodies. The Provisional Specification refers to the use of liquid unsaturated organic compounds or mixtures containing them which upon polymerization yield solid or semi-solid products.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1406936A GB475552A (en) | 1936-05-18 | 1936-05-18 | Improvements in and relating to the manufacture of polymerisation products |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1406936A GB475552A (en) | 1936-05-18 | 1936-05-18 | Improvements in and relating to the manufacture of polymerisation products |
Publications (1)
Publication Number | Publication Date |
---|---|
GB475552A true GB475552A (en) | 1937-11-18 |
Family
ID=10034415
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1406936A Expired GB475552A (en) | 1936-05-18 | 1936-05-18 | Improvements in and relating to the manufacture of polymerisation products |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB475552A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1101750B (en) * | 1953-03-02 | 1961-03-09 | Polymer Corp | Tubular hollow mold rotating around its horizontal longitudinal axis for the production of hollow bodies from organic plastic by centrifugal casting |
-
1936
- 1936-05-18 GB GB1406936A patent/GB475552A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1101750B (en) * | 1953-03-02 | 1961-03-09 | Polymer Corp | Tubular hollow mold rotating around its horizontal longitudinal axis for the production of hollow bodies from organic plastic by centrifugal casting |
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