GB541167A - Improvements in and relating to the preparation of rubber derivatives or resins - Google Patents

Improvements in and relating to the preparation of rubber derivatives or resins

Info

Publication number
GB541167A
GB541167A GB561141A GB561141A GB541167A GB 541167 A GB541167 A GB 541167A GB 561141 A GB561141 A GB 561141A GB 561141 A GB561141 A GB 561141A GB 541167 A GB541167 A GB 541167A
Authority
GB
United Kingdom
Prior art keywords
rubber
cellulose
maleic anhydride
ether
ethyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB561141A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BRITISH RUBBER PROD RES
ERNEST HAROLD FARMER
Original Assignee
BRITISH RUBBER PROD RES
ERNEST HAROLD FARMER
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to NL62236D priority Critical patent/NL62236C/xx
Application filed by BRITISH RUBBER PROD RES, ERNEST HAROLD FARMER filed Critical BRITISH RUBBER PROD RES
Priority to GB561141A priority patent/GB541167A/en
Publication of GB541167A publication Critical patent/GB541167A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00Compositions of cellulose, modified cellulose or cellulose derivatives
    • C08L1/08Cellulose derivatives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08BPOLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B15/00Preparation of other cellulose derivatives or modified cellulose, e.g. complexes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08CTREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00Chemical modification of rubber
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08CTREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00Chemical modification of rubber
    • C08C19/28Reaction with compounds containing carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00Compositions of cellulose, modified cellulose or cellulose derivatives
    • C08L1/08Cellulose derivatives
    • C08L1/10Esters of organic acids, i.e. acylates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00Compositions of cellulose, modified cellulose or cellulose derivatives
    • C08L1/08Cellulose derivatives
    • C08L1/26Cellulose ethers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Biochemistry (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

541,167. Cellulose and rubber compounds. BRITISH RUBBER PRODUCERS RESEARCH ASSOCIATION, and FARMER. E. H. July 26, 1940, Nos. 5611/41 (divided out of 535,889) and 9561/41. [Class 2 (ii)] Compounds of rubber with cellulose esters or ethers and maleic anhydride are obtained by heating the ingredients together, preferably in presence of a peroxide catalyst. If desired a rubber-maleic anhydride may be first obtained and this compound may then be heated with a cellulose ester or ether. Cellulose acetate, nitrate, or other ester, or ethyl or benzyl cellulose or other ether may be used. In an example, crepe rubber, maleic anhydride, ethyl cellulose, and benzoyl peroxide are dissolved in xylene, placed on a steam bath, and then heated under reflux at 150-160‹ C. A product is obtained which is completely soluble in ethyl alcohol, acetone, ether, and benzene, but insoluble in petroleum ether. The product may be plasticized, e.g. by milling with dibutyl phthalate or " Arochlor." Other examples describe the production of products from the same ingredients but in varying proportions. When the proportion of rubber is greater than that of the ethyl cellulose, the product is insoluble in ethyl alcohol. In another example, a solution of cellulose acetate, rubber, maleic anhydride, and benzoyl peroxide in tetrachlorethane is heated at 146‹ C. The solvent is removed and the residue is dissolved in acetone and reprecipitated with alcohol. In another example, a solution of cellulose nitrate, rubber, and maleic anhydride in amyl acetate is heated to 150‹ C. The product obtained is soluble in alcohol and acetone but not in petroleum ether. The rubber may be used in the form of crepe, smoked sheet, or natural, preserved, or synthetic latex. The products may be used for making transparent wrappings or bottle caps, or for other purposes. Specifications 507,996 and 535,889 are referred to.
GB561141A 1940-07-26 1940-07-26 Improvements in and relating to the preparation of rubber derivatives or resins Expired GB541167A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
NL62236D NL62236C (en) 1940-07-26
GB561141A GB541167A (en) 1940-07-26 1940-07-26 Improvements in and relating to the preparation of rubber derivatives or resins

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB561141A GB541167A (en) 1940-07-26 1940-07-26 Improvements in and relating to the preparation of rubber derivatives or resins

Publications (1)

Publication Number Publication Date
GB541167A true GB541167A (en) 1941-11-14

Family

ID=9799336

Family Applications (1)

Application Number Title Priority Date Filing Date
GB561141A Expired GB541167A (en) 1940-07-26 1940-07-26 Improvements in and relating to the preparation of rubber derivatives or resins

Country Status (2)

Country Link
GB (1) GB541167A (en)
NL (1) NL62236C (en)

Also Published As

Publication number Publication date
NL62236C (en)

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