GB541167A - Improvements in and relating to the preparation of rubber derivatives or resins - Google Patents
Improvements in and relating to the preparation of rubber derivatives or resinsInfo
- Publication number
- GB541167A GB541167A GB561141A GB561141A GB541167A GB 541167 A GB541167 A GB 541167A GB 561141 A GB561141 A GB 561141A GB 561141 A GB561141 A GB 561141A GB 541167 A GB541167 A GB 541167A
- Authority
- GB
- United Kingdom
- Prior art keywords
- rubber
- cellulose
- maleic anhydride
- ether
- ethyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/08—Cellulose derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B15/00—Preparation of other cellulose derivatives or modified cellulose, e.g. complexes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/28—Reaction with compounds containing carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/08—Cellulose derivatives
- C08L1/10—Esters of organic acids, i.e. acylates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/08—Cellulose derivatives
- C08L1/26—Cellulose ethers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
541,167. Cellulose and rubber compounds. BRITISH RUBBER PRODUCERS RESEARCH ASSOCIATION, and FARMER. E. H. July 26, 1940, Nos. 5611/41 (divided out of 535,889) and 9561/41. [Class 2 (ii)] Compounds of rubber with cellulose esters or ethers and maleic anhydride are obtained by heating the ingredients together, preferably in presence of a peroxide catalyst. If desired a rubber-maleic anhydride may be first obtained and this compound may then be heated with a cellulose ester or ether. Cellulose acetate, nitrate, or other ester, or ethyl or benzyl cellulose or other ether may be used. In an example, crepe rubber, maleic anhydride, ethyl cellulose, and benzoyl peroxide are dissolved in xylene, placed on a steam bath, and then heated under reflux at 150-160‹ C. A product is obtained which is completely soluble in ethyl alcohol, acetone, ether, and benzene, but insoluble in petroleum ether. The product may be plasticized, e.g. by milling with dibutyl phthalate or " Arochlor." Other examples describe the production of products from the same ingredients but in varying proportions. When the proportion of rubber is greater than that of the ethyl cellulose, the product is insoluble in ethyl alcohol. In another example, a solution of cellulose acetate, rubber, maleic anhydride, and benzoyl peroxide in tetrachlorethane is heated at 146‹ C. The solvent is removed and the residue is dissolved in acetone and reprecipitated with alcohol. In another example, a solution of cellulose nitrate, rubber, and maleic anhydride in amyl acetate is heated to 150‹ C. The product obtained is soluble in alcohol and acetone but not in petroleum ether. The rubber may be used in the form of crepe, smoked sheet, or natural, preserved, or synthetic latex. The products may be used for making transparent wrappings or bottle caps, or for other purposes. Specifications 507,996 and 535,889 are referred to.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL62236D NL62236C (en) | 1940-07-26 | ||
GB561141A GB541167A (en) | 1940-07-26 | 1940-07-26 | Improvements in and relating to the preparation of rubber derivatives or resins |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB561141A GB541167A (en) | 1940-07-26 | 1940-07-26 | Improvements in and relating to the preparation of rubber derivatives or resins |
Publications (1)
Publication Number | Publication Date |
---|---|
GB541167A true GB541167A (en) | 1941-11-14 |
Family
ID=9799336
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB561141A Expired GB541167A (en) | 1940-07-26 | 1940-07-26 | Improvements in and relating to the preparation of rubber derivatives or resins |
Country Status (2)
Country | Link |
---|---|
GB (1) | GB541167A (en) |
NL (1) | NL62236C (en) |
-
0
- NL NL62236D patent/NL62236C/xx active
-
1940
- 1940-07-26 GB GB561141A patent/GB541167A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
NL62236C (en) |
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