GB487365A - Process for producing plastic masses, foils and threads and other structures from solutions of cellulose in sulphuric acid - Google Patents

Process for producing plastic masses, foils and threads and other structures from solutions of cellulose in sulphuric acid

Info

Publication number
GB487365A
GB487365A GB18811/37A GB1881137A GB487365A GB 487365 A GB487365 A GB 487365A GB 18811/37 A GB18811/37 A GB 18811/37A GB 1881137 A GB1881137 A GB 1881137A GB 487365 A GB487365 A GB 487365A
Authority
GB
United Kingdom
Prior art keywords
cellulose
sulphuric acid
per cent
employed
foils
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB18811/37A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Produktions und Vertriebs GmbH and Co oHG
Original Assignee
Wolff and Co AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wolff and Co AG filed Critical Wolff and Co AG
Publication of GB487365A publication Critical patent/GB487365A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08BPOLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B1/00Preparatory treatment of cellulose for making derivatives thereof, e.g. pre-treatment, pre-soaking, activation
    • C08B1/003Preparation of cellulose solutions, i.e. dopes, with different possible solvents, e.g. ionic liquids
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F2/00Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
    • D01F2/02Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from solutions of cellulose in acids, bases or salts
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2301/00Characterised by the use of cellulose, modified cellulose or cellulose derivatives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Artificial Filaments (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)

Abstract

For producing plastic masses, foils, threads, tubes, sponges and other structures from cellulose natural cellulose fibres are treated, without subsequent dilution, with sulphuric acid of 62,5-64 per cent concentration at a temperature of 0 DEG C. Preferably a bleached sulphate cellulose brought by an alkali treatment to an a -cellulose content of over 90 per cent is employed. Bleached cotton linter, or sulphite or soda cellulose may also be employed. Precipitation of the solution may be effected at room temperature, e.g. with water. After kneading the mass at 0 DEG C., solution is preferably completed by cooling for a few hours to a lower temperature, e.g. -5 to -7 DEG C. The cellulose may be employed in the form of loose tightly pressed board. In an example one part of sulphate cellulose in board form (a -cellulose content 96 per cent) is kneaded with 9 parts of 63,3 per cent sulphuric acid at 0 DEG C. and left for some hours at 0 DEG C. The mass is then cooled to -7 DEG C. while kneading until it is quite clear. A second example employs eight parts of sulphuric acid of 62,8 per strength to 1 part of cotton linters. Specifications 395,947, 427,611, and 427,613 are referred to.
GB18811/37A 1936-07-14 1937-07-06 Process for producing plastic masses, foils and threads and other structures from solutions of cellulose in sulphuric acid Expired GB487365A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE487365X 1936-07-14

Publications (1)

Publication Number Publication Date
GB487365A true GB487365A (en) 1938-06-20

Family

ID=6543604

Family Applications (1)

Application Number Title Priority Date Filing Date
GB18811/37A Expired GB487365A (en) 1936-07-14 1937-07-06 Process for producing plastic masses, foils and threads and other structures from solutions of cellulose in sulphuric acid

Country Status (4)

Country Link
US (1) US2293503A (en)
FR (1) FR824320A (en)
GB (1) GB487365A (en)
NL (1) NL47136C (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE740622C (en) * 1939-07-23 1943-10-25 Ig Farbenindustrie Ag Process for the production of solutions of cellulose in sulfuric acid

Also Published As

Publication number Publication date
FR824320A (en) 1938-02-07
NL47136C (en)
US2293503A (en) 1942-08-18

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