GB473058A - Colloidized pigments of basic dyes - Google Patents

Colloidized pigments of basic dyes

Info

Publication number
GB473058A
GB473058A GB2494/36A GB249436A GB473058A GB 473058 A GB473058 A GB 473058A GB 2494/36 A GB2494/36 A GB 2494/36A GB 249436 A GB249436 A GB 249436A GB 473058 A GB473058 A GB 473058A
Authority
GB
United Kingdom
Prior art keywords
sodium
lake
kneaded
dextrin
sulphonate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2494/36A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CALCO CHEMICAL CO Inc
Original Assignee
CALCO CHEMICAL CO Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CALCO CHEMICAL CO Inc filed Critical CALCO CHEMICAL CO Inc
Publication of GB473058A publication Critical patent/GB473058A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0071Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
    • C09B67/0092Dyes in solid form

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Cosmetics (AREA)

Abstract

Highly dispersible lake preparations are prepared from lake pigments obtained by the reaction of basic dyes with complex metal acids by kneading the pigment with defined protective agents in the form of a thick paste. The products may be dried and ground. The protective agents are defined as carbohydrate colloids such as the dextrins, the alkali salts of lignin sulphonic acids, gelatine, alkali metal silicates, pectin and colloidal clays. There may also be present in the paste (a) deflocculating agents such as dextrin, (b) a combined deflocculating and wetting agent, e.g. sodium dinaphthylmethane disulphonate, (c) wetting agents such as sodium isopropyl-naphthalene sulphonate or sodium secondary butylnaphthalene sulphonate, alkali and alkaline earth metal salts of lignin sulphonic acids, sodium salts of sulphonated lauryl, cetyl, and similar high-molecular alcohols, and ethers of polyglycols such as the ethyl ether of diethylene glycol, (d) diluting agents, such as sugar, dextrose, cerelose and xylose and (e) antidusting agents such as glycerine, or esters of ether alcohols with low-molecular weight organic acids, e.g. the acetates or formates of ethyl, methyl or butyl ethers of ethylene glycols. Groups of basic dyes specified are amino polyarylmethane derivatives such as Methyl and Crystal violet, thiazines such as Methylene blue, acridines, phosphines, xanthines such as Rhodamine, ketone imides such as Auramine, basic azo dyes such as Chrysoidine, basic quinoline dyes such as the cyanines, indamines, thiazoles, oxazines or sulphonation products of basic dyes in which the degree of sulphonation is not such as to destroy their basicity. Complex metal acids specified are phosphotungstic, phosphomolybdic, phosphotungstomolybdic, silicotungstic, silicomolybdic or silicotungstomolybdic. In examples: (1) a Methyl violet phosphotungstate lake press cake is kneaded with sodium isopropylnaphthalene sulphonate and dextrin, the product is vacuum dried and ground, 25 per cent of water added, and the mass again kneaded, dried and granulated, after which it is blended dry with cerelose and a little monoethyl ether of ethylene glycol; (2) a Methyl violet phosphomolybdate lake press cake is kneaded as above with sodium isopropylnaphthalene sulphonate and the sodium salt of lignin sulphonic acid residue, followed by blending dry with xylose and a little sodium secondary butylnaphthalene sulphonate; (3) a Methylene blue N phosphotungstate lake press cake is kneaded with sodium dinaphthylmethane sulphonate and dextrin, the product being blended dry with cane sugar and a little of the monoethyl ether of diethylene glycol; (4) a Methyl violet phosphotungstate lake press cake is kneaded with sodium isopropylnaphthalene sulphonate and dextrin, followed by blending dry with cerelose and the monoethyl ether of diethylene glycol; (5) a Methyl violet phosphotungstate lake is kneaded with dextrin, sodium isopropylnaphthalene sulphonate is added, and the product dried and ground; (6) a Victoria blue phosphotungstate lake is kneaded with dextrin, sodium disulphodinaphthylmethane is incorporated, and the product dried and ground; (7) a Victoria blue-methyl violet phosphotungstate lake is kneaded with dextrin; (8) a Methylene blue phosphotungstate lake is kneaded with dextrin and blended dry with dextrose; (9) a Methyl violet-Victoria blue p phosphotungstate lake is kneaded with sodium dinaphthylmethane sulphonate, dextrin, and powdered bentonite, followed by blending dry with sodium secondary butylnaphthalene sulphonate. Tests are described for estimating the dispersibility and hygroscopicity of the products.ALSO:Highly dispersible lake preparations are prepared from lake pigments obtained by the reaction of basic dyes with complex metal acids by kneading the pigment with defined protective agents in the form of a thick paste. The products may be dried and ground. The protective agents are defined as carbohydrate colloids such as the dextrins, the alkali salts of lignin sulphonic acids, gelatine, alkali metal silicates, pectin and colloidal clays. There may also be present in the paste (a) deflocculating agents such as dextrin, (b) a combined deflocculating and wetting agent, e.g. sodium dinaphthylmethane disulphonate, (c) wetting agents such as sodium isopropyl naphthalene sulphonate or sodium secondary butylnaphthalene sulphonate, alkali and alkaline earth metal salts of lignin sulphonic acids, sodium salts of sulphonated lauryl, cetyl, and similar high-molecular alcohols and ethers of polyglycols such as the ethyl ether of diethylene glycol, (d) diluting agents, such as sugar, dextrose, cerelose and xylose, and (e) antidusting agents such as glycerine, or esters of ether alcohols with low-molecular weight organic acids, e.g. the acetates or formates of ethyl, methyl or butyl ethers of ethylene glycols. Groups of basic dyes specified are amino polyarylmethane derivatives such as Methyl and Crystal violet, thiazines such as Methylene blue, acridines, phosphines, xanthines such as Rhodamine. ketone imides such as Auramine, basic azo dyes such as Chrysoidine, basic quinoline dyes such as the cyanines, indamines, thiazoles, oxazines or sulphonation products of basic dyes in which the degree of sulphonation is not such as to destroy their basicity. Complex metal acids specified are phosphotungstic, phosphomolybdic, phosphotungstomolybdic, silicotungstic, silicomolybdic or silicotungstomolybdic. In examples, (1) a Methyl violet phosphotungstate lake press cake is kneaded with sodium isopropylnaphthalene sulphonate and dextrin, the product is vacuum dried and groond, 25 per cent of water added, and the mass again kneaded, dried and granulated, after which it is blended dry with cerelose and a little monoethyl ether of ethylene glycol; (2) a Methyl violet phosphomolybdate lake press cake is kneaded as above with sodium isopropylnaphthalene sulphonate and the sodium salt of lignin sulphonic acid residue, followed by blending dry with xylose and a little sodium secondarybutylnaphthalene sulphonate; (3) a Methylene blue N phosphotungstate lake press cake is kneaded with sodium dinaphthylmethane sulphonate and dextrin, the product being blended dry with cane sugar and a little of the monoethyl ether of diethylene glycol; (4) a Methyl violet phosphotungstate lake press cake is kneaded with sodium isopropylnaphthalene sulphonate and dextrin, followed by blending dry with cerelose and the monoethyl ether of diethylene glycol; (5) a Methyl violet phosphotungstate lake is kneaded with dextrin, sodium isopropylnaphthalene sulphonate is added, and the product dried and ground; (6) a Victoria blue phosphotungstate lake is kneaded with dextrin, sodium disulphotinaphthylmethane is incorporated, and the product dried and ground; (7) a Victoria blue-methyl violet phosphotungstate lake is kneaded with dextrin; (8) a Methylene blue phosphotungstate lake is kneaded with dextrin and blended dry with dextrose; (9) a Methyl violet-Victoria blue phosphotungstate lake is kneaded with sodium dinaphthylmethane sulphonate, dextrin, and powdered bentonite, followed by blending dry with sodium secondary butylnaphthalene sulphonate. Tests are described for estimating the dispersibility and hygroscopicity of the products.
GB2494/36A 1935-02-01 1936-01-27 Colloidized pigments of basic dyes Expired GB473058A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US473058XA 1935-02-01 1935-02-01

Publications (1)

Publication Number Publication Date
GB473058A true GB473058A (en) 1937-09-27

Family

ID=21948233

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2494/36A Expired GB473058A (en) 1935-02-01 1936-01-27 Colloidized pigments of basic dyes

Country Status (1)

Country Link
GB (1) GB473058A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000047681A1 (en) * 1999-02-09 2000-08-17 Bayer Aktiengesellschaft Solid pigment preparations
CN116333362A (en) * 2023-02-10 2023-06-27 西北农林科技大学 Preparation method and application of hypericin/purple phosphorus quantum dot/bacterial cellulose composite membrane

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000047681A1 (en) * 1999-02-09 2000-08-17 Bayer Aktiengesellschaft Solid pigment preparations
US6596073B1 (en) 1999-02-09 2003-07-22 Bayer Aktiengesellschaft Solid pigment preparations
CN116333362A (en) * 2023-02-10 2023-06-27 西北农林科技大学 Preparation method and application of hypericin/purple phosphorus quantum dot/bacterial cellulose composite membrane
CN116333362B (en) * 2023-02-10 2024-03-29 西北农林科技大学 Preparation method and application of hypericin/purple phosphorus quantum dot/bacterial cellulose composite membrane

Similar Documents

Publication Publication Date Title
GB600451A (en) Direct dye planographic printing compositions
GB997017A (en) Water-insoluble azo and phthalocyanine dyestuffs and containing mercapto groups and process for their manufacture and use
GB473058A (en) Colloidized pigments of basic dyes
GB473120A (en) Improvements in or relating to the production and use of coloured printing compositions, and the compositions thus produced
GB474827A (en) Improvements in colloidized vat dyes
GB471247A (en) Improvements in and relating to hair dressing and treating materials
GB644904A (en) Dyestuff preparations comprising leuco-sulphuric ester derivatives of vat dyestuffs
US1744140A (en) Peocess foe hunting with vat dyestuffs
US2110081A (en) Textile printing
GB292655A (en) Improvements in printing colours or inks
GB807089A (en) Manufacture of readily dispersible dry dyestuff preparations
GB275969A (en) An improved process for colouring lacquers
US2203257A (en) Dry dyestuff preparation
US1440037A (en) Manufacture of stable, dry, and readily-soluble vat preparations for dyeing
GB343527A (en) Improvements in or relating to the printing of cotton
GB786252A (en) Synthetic surface active preparations
GB343597A (en) Improvements in or relating to the printing of cotton
GB511424A (en) Improved process for printing textile materials
GB405092A (en) Manufacture of vat-dyestuff preparations
US2003641A (en) Printing of textile fabrics with vat
GB389915A (en) Manufacture of dyestuff preparations
GB575253A (en) Improvements in or relating to diagnostic compositions and methods for employing same
GB489929A (en) Improvements in textile printing or padding
GB592484A (en) Manufacture and use of printing and like compositions
GB371836A (en) Improvements in or relating to the manufacture of vat dyestuff preparations for textile printing