GB463300A - Process of imparting hydrophobic properties to cellulose fibres - Google Patents

Process of imparting hydrophobic properties to cellulose fibres

Info

Publication number
GB463300A
GB463300A GB17898/35A GB1789835A GB463300A GB 463300 A GB463300 A GB 463300A GB 17898/35 A GB17898/35 A GB 17898/35A GB 1789835 A GB1789835 A GB 1789835A GB 463300 A GB463300 A GB 463300A
Authority
GB
United Kingdom
Prior art keywords
solution
derivative
aldehyde
acid
stearinamide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB17898/35A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Publication of GB463300A publication Critical patent/GB463300A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/425—Carbamic or thiocarbamic acids or derivatives thereof, e.g. urethanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/41—Phenol-aldehyde or phenol-ketone resins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/423—Amino-aldehyde resins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/17—Glyoxal and polyaldehyde treatment of textiles
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2904—Staple length fiber
    • Y10T428/2907—Staple length fiber with coating or impregnation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Artificial Filaments (AREA)

Abstract

Artificial cellulosic textile materials are rendered capable of repelling water by incorporating in the spinning solution a urea derivative or an aliphatic carboxylic acid amide containing an alkyl radicle of at least 11 carbon atoms, and then condensing the derivative with an aliphatic aldehyde. The necessary condensation is effected by heating the materials charged with the urea &c. derivative to, for example, 100--140 DEG C., if desired, in an acid or alkaline medium. As an alternative, the condensation product of the urea &c. derivative and the aldehyde may be added to the spinning solution, and the subsequent heating carried out with or without the presence of aldehyde. The process may also be adapted to the treatment of cellulosic textiles. The aldehyde may be used as a solution, or in the vapour phase, in which latter case the heating step may be carried out simultaneously. The following are suitable derivatives: lauric acid amide; stearoyl-methylamide, -butylamide and -octadecylamide; monododecylurea; monoctadecylurea; stearoylurea. In examples, the following media are used: a pyridine solution of octadecyl-heptadecylurea; an emulsion of stearinamide containing formaldehyde and preferably lactic acid, the emulsifying agent being the reaction product of ethylene oxide and octadecenyl alcohol; a pyridine solution of methylolstearinamide; a carbon-tetrachloride solution of methylol-stearinamide, and afterwards a lactic acid solution; a lactic or glycollic acid solution, followed by a carbon-tetrachloride solution of the condensation product of montanic acid amide and formaldehyde; a methylenechloride solution of carbamic acid octadecyl ester.ALSO:To produce an emulsion of stearinamide there is used as the emulsifying agent the reaction product of ethylene oxide and octadecenyl alcohol. The emulsion also contains formaldehyde and lactic acid.
GB17898/35A 1935-05-12 1935-06-21 Process of imparting hydrophobic properties to cellulose fibres Expired GB463300A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DEI52329D DE762964C (en) 1935-05-12 1935-05-12 Process for making cellulose fibers water repellent
DE2111698X 1935-09-28
DE485593X 1935-11-23

Publications (1)

Publication Number Publication Date
GB463300A true GB463300A (en) 1937-03-22

Family

ID=32045547

Family Applications (4)

Application Number Title Priority Date Filing Date
GB4212/37A Expired GB463472A (en) 1935-05-12 1935-06-21 Process of imparting hydrophobic properties to cellulose fibres
GB17898/35A Expired GB463300A (en) 1935-05-12 1935-06-21 Process of imparting hydrophobic properties to cellulose fibres
GB30934/35A Expired GB467166A (en) 1935-05-12 1935-11-08 Process of imparting hydrophobic properties to cellulose fibres
GB32028/36A Expired GB485593A (en) 1935-05-12 1936-11-23 Process for imparting hydrophobic properties to fibrous materials or like substances

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB4212/37A Expired GB463472A (en) 1935-05-12 1935-06-21 Process of imparting hydrophobic properties to cellulose fibres

Family Applications After (2)

Application Number Title Priority Date Filing Date
GB30934/35A Expired GB467166A (en) 1935-05-12 1935-11-08 Process of imparting hydrophobic properties to cellulose fibres
GB32028/36A Expired GB485593A (en) 1935-05-12 1936-11-23 Process for imparting hydrophobic properties to fibrous materials or like substances

Country Status (6)

Country Link
US (3) US2165265A (en)
BE (3) BE415480A (en)
DE (1) DE762964C (en)
FR (3) FR806170A (en)
GB (4) GB463472A (en)
NL (3) NL45055C (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2574114A (en) * 1948-04-26 1951-11-06 Bozel Maletra Prod Chimiques Amide-glyoxal-formaldehyde reaction product and shrinkproofing cellulose textile fibers therewith
US4497715A (en) * 1982-08-03 1985-02-05 Colgate-Palmolive Company N-Alkylisostearamides as antistatic agents
US4563288A (en) * 1982-08-03 1986-01-07 Colgate-Palmolive Company N-Alkyl isostearamide antistatic agents, detergent compositions containing such agents, and processes for washing laundry in the presence of such agents, and with such compositions

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE907163C (en) * 1938-06-07 1954-03-22 Hoechst Ag Process for making natural fibers of animal or vegetable origin or artificial fibers water-repellent
US2423185A (en) * 1939-07-08 1947-07-01 Hydronapthene Corp Process for the manufacture of coated and impregnated materials
DE766083C (en) * 1940-01-26 1954-02-01 Ig Farbenindustrie Ag Preparations for refining fiber materials
US2418696A (en) * 1942-03-09 1947-04-08 Courtaulds Ltd Modifying the dyeing properties of cellulose or cellulose derivative textile materials
US2451426A (en) * 1943-11-25 1948-10-12 Du Pont Bright zinc plating
US2446864A (en) * 1944-06-26 1948-08-10 Quaker Chemical Products Corp Composition and process for imparting durable water repellent finish to textiles
NL60268C (en) * 1944-08-14 1947-11-15
US2510522A (en) * 1944-12-09 1950-06-06 Montclair Res Corp Textile treating products and process of making
US2431202A (en) * 1945-03-01 1947-11-18 Gen Aniline & Film Corp Self-dispersing methylolstear-amides
US2594384A (en) * 1946-11-12 1952-04-29 Monsanto Chemicals Fungi and bacteria resistant papermakers' felts and process for preparing same
US2507700A (en) * 1946-11-27 1950-05-16 Monsanto Chemicals N, n', n''-triacylmelamines
US2540726A (en) * 1946-12-03 1951-02-06 Du Pont Treatment of a heat set, oriented nylon fabric with formaldehyde
US2565194A (en) * 1947-03-27 1951-08-21 American Cyanamid Co Chlorotriazine resins and process of making the same
BE480227A (en) * 1947-08-14
US2562161A (en) * 1948-02-06 1951-07-31 Cluett Peabody & Co Inc Stabilization of regenerated cellulose fabric with glyoxal-amide reaction product
US2608494A (en) * 1948-08-28 1952-08-26 Walkden Makin & Co Ltd Treatment of textile fabrics for imparting antishrink properties thereto
US2600698A (en) * 1948-11-13 1952-06-17 Monsanto Chemicals Reaction products from an aldehyde, an aminotriazine, and a mono-nheterocyclic compound
US2641558A (en) * 1948-12-24 1953-06-09 Nat Lead Co Water repellence fixative treatment
US2805196A (en) * 1952-02-11 1957-09-03 Tno Permselective electrodialysis
US3128272A (en) * 1957-06-11 1964-04-07 Minnesota Mining & Mfg Perfluoroalkyl-substituted triazines
NL114029C (en) * 1958-02-20
US3232697A (en) * 1959-07-01 1966-02-01 Nalco Chemical Co Textile treatment
NL272600A (en) * 1960-12-17
US3112155A (en) * 1962-02-02 1963-11-26 Sidney L Vail Glyoxal-amide reaction products
US4103051A (en) * 1975-11-03 1978-07-25 Milliken Research Corporation Pilling reduction in textiles
DE2757582A1 (en) * 1977-12-23 1979-06-28 Cassella Ag METHOD FOR THE PRODUCTION OF STORAGE-STABLE AQUEOUS EMULSIONS OF N.ALKYL-N'-ALKYLOL UREAS AND THEIR APPLICATION FOR SOFTENING LEATHER AND TEXTILE MATERIAL
US4295930A (en) * 1980-03-17 1981-10-20 Nalco Chemical Company Alkoxylated dioxolanes as paper sizing agents
US7713215B2 (en) * 2008-01-31 2010-05-11 Shriver Edgar L Steering, piercing, anchoring, distending extravascular guidewire

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE197965C (en) * 1906-04-24
AT118595B (en) * 1926-12-01 1930-07-25 Tootal Broadhurst Lee Co Ltd Process for impregnating textile yarns, fabrics and fabrics with synthetic resins.
DE542186C (en) * 1929-06-14 1932-01-21 Alexander Nathansohn Dr Process for waterproofing raw, chemically uncleaned textile fibers
FR751641A (en) * 1932-02-29 1933-09-07 Ig Farbenindustrie Ag Process for the preparation of auxiliary condensation products
AT136377B (en) * 1933-01-13 1934-01-25 Heberlein & Co Ag Finishing process for vegetable textiles.

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2574114A (en) * 1948-04-26 1951-11-06 Bozel Maletra Prod Chimiques Amide-glyoxal-formaldehyde reaction product and shrinkproofing cellulose textile fibers therewith
US4497715A (en) * 1982-08-03 1985-02-05 Colgate-Palmolive Company N-Alkylisostearamides as antistatic agents
US4563288A (en) * 1982-08-03 1986-01-07 Colgate-Palmolive Company N-Alkyl isostearamide antistatic agents, detergent compositions containing such agents, and processes for washing laundry in the presence of such agents, and with such compositions

Also Published As

Publication number Publication date
NL50083C (en) 1941-04-15
GB485593A (en) 1938-05-23
FR813868A (en) 1937-06-10
GB463472A (en) 1937-03-22
US2165265A (en) 1939-07-11
DE762964C (en) 1953-11-30
NL45055C (en) 1939-02-15
GB467166A (en) 1937-06-08
BE418549A (en)
US2111698A (en) 1938-03-22
BE417657A (en)
BE415480A (en) 1936-06-30
NL44056C (en) 1938-09-15
US2211976A (en) 1940-08-20
FR806170A (en) 1936-12-09
FR47692E (en) 1937-06-16

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