GB446820A - Process for the manufacture of dyestuffs containing chromium - Google Patents

Process for the manufacture of dyestuffs containing chromium

Info

Publication number
GB446820A
GB446820A GB31273/34A GB3127334A GB446820A GB 446820 A GB446820 A GB 446820A GB 31273/34 A GB31273/34 A GB 31273/34A GB 3127334 A GB3127334 A GB 3127334A GB 446820 A GB446820 A GB 446820A
Authority
GB
United Kingdom
Prior art keywords
acid
primary
compound
chromed
naphthol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB31273/34A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kuhlmann SA
Original Assignee
Kuhlmann SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kuhlmann SA filed Critical Kuhlmann SA
Publication of GB446820A publication Critical patent/GB446820A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B45/00Complex metal compounds of azo dyes
    • C09B45/48Preparation from other complex metal compounds of azo dyes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Coloring (AREA)

Abstract

Chromium compounds of azo dyes are made by treating in an acid medium and in the absence of substantial amounts of chroming agents, the primary chromed compounds resulting from the action of chroming agents on o-oxyazo dyes in a neutral or very slightly acid medium, or a mixture of dyestuffs containing chromium of which one at least is such a primary chromed o-oxyazo dyestuff, the acidity of the treating medium being obtained by the addition of mineral, organic or sulphoaromatic acids, acid salts, substances capable of giving rise to acid bodies or mixtures comprising several of these compounds (the treatment of chromed complexes of the o-oxyazo dyes: o-aminophenols or o-aminonaphthols --> pyrazolones being excluded). The products obtained are called secondary chromed compounds. The acid treatment may be applied to the o-oxyazo dyes without separation from their chroming media or after isolation therefrom and may be stopped before the complete transformation of the primary into the secondary chromed compound. The secondary compounds yield brighter and more even shades and are generally faster to light. In examples: (1) the dyestuff 1-amino-2-naphthol-4-sulpho acid --> b -naphthol is autoclaved with common salt, chromium formate and sodium acetate in aqueous solution and the primary chromed compound obtained is heated with hydrochloric acid (pure fast blue on animal fibres); (2) the dyestuff from the nitro-diazo compound of 1 - amino - 2 - naphthol - 4 - sulphonic acid and b - naphthol is heated with a solution of chromium naphthalene-1:5-disulphonate and caustic soda to form the primary compound and the mixture is heated with formic acid to obtain the secondary compound or a mixture of the primary and secondary compounds (black shades on wool); (3) the chromed complex obtained in the absence of mineral acid from the dyestuff 1-amino-2-naphthol-4- sulphonic acid --> 1-phenyl-3-methyl-5-pyrazolone is mixed with sulphuric acid (cf. Specification 358,146) and the primary chromed compound of the azo dye 2-aminophenol-5-sulphonic acid --> b -naphthol and autoclaved for 20 hours (bordeaux); (4) the isolated primary compound of (2) is heated with hydrochloric acid; the ammonium salt of the product gives fast grey shades on animal fibres. Specification 365,113 also is referred to. The Specification as open to inspection under Sect. 91 comprises also the treatment of chromium compounds of o-oxyazo dyes in acid medium in general and the following examples: (1) the dyestuff 2-aminophenol-4-sulphonic acid --> 1-phenyl-3-methyl-5-pyrazolone is refluxed with chrome alum and sodium acetate to form the primary chromium compound and the heating is then continued for 24 hours to form the secondary compound; the free acid of the latter may be used as a pigment dye and the salts for dyeing natural or artificial fibres; (2) the primary compound of the preceding example is mixed with dilute sulphuric acid and the paste obtained is dried in a vacuum; a mixture of primary and secondary compounds is obtained (orange on animal fibres); (3) the primary chromed compound of 1-amino-2-naphthol - 4 - sulphonic acid --> 1 - phenyl - 3-methyl-5-pyrazolone is autoclaved with aqueous benzenesulphonic acid. This subject-matter does not appear in the Specification as accepted.
GB31273/34A 1933-12-02 1934-10-31 Process for the manufacture of dyestuffs containing chromium Expired GB446820A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR446820X 1933-12-02

Publications (1)

Publication Number Publication Date
GB446820A true GB446820A (en) 1936-04-30

Family

ID=8900553

Family Applications (1)

Application Number Title Priority Date Filing Date
GB31273/34A Expired GB446820A (en) 1933-12-02 1934-10-31 Process for the manufacture of dyestuffs containing chromium

Country Status (1)

Country Link
GB (1) GB446820A (en)

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