GB441119A - Improvements in or relating to the manufacture of polynuclear compounds - Google Patents

Improvements in or relating to the manufacture of polynuclear compounds

Info

Publication number
GB441119A
GB441119A GB1084134A GB1084134A GB441119A GB 441119 A GB441119 A GB 441119A GB 1084134 A GB1084134 A GB 1084134A GB 1084134 A GB1084134 A GB 1084134A GB 441119 A GB441119 A GB 441119A
Authority
GB
United Kingdom
Prior art keywords
aluminium chloride
benzene
give
anthracene
treated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1084134A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Priority to GB1084134A priority Critical patent/GB441119A/en
Publication of GB441119A publication Critical patent/GB441119A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B3/00—Dyes with an anthracene nucleus condensed with one or more carbocyclic rings
    • C09B3/78—Other dyes in which the anthracene nucleus is condensed with one or more carbocyclic rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Polynuclear compounds are prepared by fusing a "mono- or di-ketone of the anthracene series" with a metallic halide condensing agent, e.g. aluminium chloride or sodium-aluminium chloride, preferably in presence of an oxidizing-agent such as manganese dioxide, potassium chlorate, oxygen or air. A "mono-or di-ketone of the anthracene series" describes a - monoaroylanthracenes, a . a - diaroylanthracenes and a . meso - diaroylanthracenes. These starting materials are prepared by converting the corresponding acids to the acid chlorides and condensing these with an aromatic hydrocarbon in presence of a metal halide condensing agent. The 1.10-diaroylanthracene is obtained by treating the 1-aroylanthracene with benzoyl chloride in presence of aluminium chloride. In examples: (1) 1.4-anthracene dicarboxylic acid is treated with phosphorus pentachloride and then with benzene in presence of aluminium chloride; the resulting 1.4-diaroylanthracene is condensed with sodium aluminium chloride in presence of oxygen to give a pyrene - quinone derivative; (2) 1.5-anthracene dicarboxylic acid (prepared by reducing the 1.5-anthraquinone dicarboxylic acid with zinc and ammonia) is treated with phosphorus pentachloride and then with benzene as in (1); the 1.5-diaroyl body so obtained is condensed by means of aluminium chloride in presence of manganese dioxide to give a dibenzperylenequinone (dyes reddish violet); (3) a -anthracene carboxylic acid is treated with phosphorus pentachloride in benzene, aluminium chloride added and the mass heated to 50 DEG C. to give 1-benzoylanthracene; this is further condensed in nitrobenzene and in presence of aluminium chloride with benzene at 60 DEG C. and the resulting 1.10-dibenzoylanthracene heated with sodium aluminium chloride at 160--180 DEG C., if desired in presence of oxidizing agents to give probably a mixture of a pyrenequinone and a perylenequinone.
GB1084134A 1934-04-10 1934-04-10 Improvements in or relating to the manufacture of polynuclear compounds Expired GB441119A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1084134A GB441119A (en) 1934-04-10 1934-04-10 Improvements in or relating to the manufacture of polynuclear compounds

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1084134A GB441119A (en) 1934-04-10 1934-04-10 Improvements in or relating to the manufacture of polynuclear compounds

Publications (1)

Publication Number Publication Date
GB441119A true GB441119A (en) 1936-01-09

Family

ID=9975309

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1084134A Expired GB441119A (en) 1934-04-10 1934-04-10 Improvements in or relating to the manufacture of polynuclear compounds

Country Status (1)

Country Link
GB (1) GB441119A (en)

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