GB436345A - A process for the preparation of alkylenes - Google Patents
A process for the preparation of alkylenesInfo
- Publication number
- GB436345A GB436345A GB1414/35A GB141435A GB436345A GB 436345 A GB436345 A GB 436345A GB 1414/35 A GB1414/35 A GB 1414/35A GB 141435 A GB141435 A GB 141435A GB 436345 A GB436345 A GB 436345A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- prepared
- undecylphenylamine
- ethylheptadecylamine
- diheptadecylmethylenephenylamine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
- C07C1/321—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom
- C07C1/323—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom the hetero-atom being a nitrogen atom
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
High molecular olefines are prepared by heating secondary amines having at least one aliphatic chain of more than eight carbon atoms, until the amino group is eliminated, with compounds of an acid nature which form salts with amines. In examples: (1) heptadecylphenylamine is heated in a stream of hydrogen chloride; heptadecylene and heptadecylchloride distil over and the latter may be converted with heptadecylene by removal of hydrogen chloride; (2) undecylphenylamine is heated with zinc chloride to give pure undecylene. Pentadecylphenylamine, ethylheptadecylamine and diheptadecylmethylenephenylamine are specified as starting materials. Undecylphenylamine, ethylheptadecylamine and diheptadecylmethylenephenylamine may be prepared by removal of carbon dioxide from anilinolauric acid, ethylaminostearic acid and diheptadecylanilinoacetic acid respectively. The latter may be prepared by reacting aniline with diheptadecylbromacetic acid which may be obtained by saponification of diheptadecylbromacetylbromide.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE436345X | 1934-03-17 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB436345A true GB436345A (en) | 1935-10-09 |
Family
ID=6506882
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1414/35A Expired GB436345A (en) | 1934-03-17 | 1935-01-15 | A process for the preparation of alkylenes |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB436345A (en) |
-
1935
- 1935-01-15 GB GB1414/35A patent/GB436345A/en not_active Expired
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