GB436345A - A process for the preparation of alkylenes - Google Patents

A process for the preparation of alkylenes

Info

Publication number
GB436345A
GB436345A GB1414/35A GB141435A GB436345A GB 436345 A GB436345 A GB 436345A GB 1414/35 A GB1414/35 A GB 1414/35A GB 141435 A GB141435 A GB 141435A GB 436345 A GB436345 A GB 436345A
Authority
GB
United Kingdom
Prior art keywords
acid
prepared
undecylphenylamine
ethylheptadecylamine
diheptadecylmethylenephenylamine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1414/35A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
H TH BOEHME AG
Original Assignee
H TH BOEHME AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by H TH BOEHME AG filed Critical H TH BOEHME AG
Publication of GB436345A publication Critical patent/GB436345A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/32Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
    • C07C1/321Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom
    • C07C1/323Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom the hetero-atom being a nitrogen atom

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

High molecular olefines are prepared by heating secondary amines having at least one aliphatic chain of more than eight carbon atoms, until the amino group is eliminated, with compounds of an acid nature which form salts with amines. In examples: (1) heptadecylphenylamine is heated in a stream of hydrogen chloride; heptadecylene and heptadecylchloride distil over and the latter may be converted with heptadecylene by removal of hydrogen chloride; (2) undecylphenylamine is heated with zinc chloride to give pure undecylene. Pentadecylphenylamine, ethylheptadecylamine and diheptadecylmethylenephenylamine are specified as starting materials. Undecylphenylamine, ethylheptadecylamine and diheptadecylmethylenephenylamine may be prepared by removal of carbon dioxide from anilinolauric acid, ethylaminostearic acid and diheptadecylanilinoacetic acid respectively. The latter may be prepared by reacting aniline with diheptadecylbromacetic acid which may be obtained by saponification of diheptadecylbromacetylbromide.
GB1414/35A 1934-03-17 1935-01-15 A process for the preparation of alkylenes Expired GB436345A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE436345X 1934-03-17

Publications (1)

Publication Number Publication Date
GB436345A true GB436345A (en) 1935-10-09

Family

ID=6506882

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1414/35A Expired GB436345A (en) 1934-03-17 1935-01-15 A process for the preparation of alkylenes

Country Status (1)

Country Link
GB (1) GB436345A (en)

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