GB409361A - Improvements in or relating to the stabilisation of aqueous solutions containing hydrogen peroxide - Google Patents

Improvements in or relating to the stabilisation of aqueous solutions containing hydrogen peroxide

Info

Publication number
GB409361A
GB409361A GB30511/32A GB3051132A GB409361A GB 409361 A GB409361 A GB 409361A GB 30511/32 A GB30511/32 A GB 30511/32A GB 3051132 A GB3051132 A GB 3051132A GB 409361 A GB409361 A GB 409361A
Authority
GB
United Kingdom
Prior art keywords
solution
stannate
hydrogen peroxide
soluble metal
small amount
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB30511/32A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Roessler and Hasslacher Chemical Co
Original Assignee
Roessler and Hasslacher Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Roessler and Hasslacher Chemical Co filed Critical Roessler and Hasslacher Chemical Co
Publication of GB409361A publication Critical patent/GB409361A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B15/00Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
    • C01B15/01Hydrogen peroxide
    • C01B15/037Stabilisation by additives

Abstract

Aqueous solutions containing hydrogen peroxide are stabilized either by adding to the solution a small amount of a soluble metal stannate, e.g. sodium stannate, and adjusting the pH of the solution to at least 3,5 or by adding a small amount of soluble metal stannate and a small amount of a peptizing agent and adjusting the pH of the solution to at least 2,0. Peptising agents giving rise to polyvalent negative ions such as pyrophosphoric acid or soluble pyrophosphates are referred to. The amount of soluble metal stannate may be 5--100 mg. per litre of solution. A pH of 4--5 is preferable. The soluble metal stannate may be added in the form of an aqueous solution and the stabilizing action is improved if the sodium stannate solution is treated to effect a partial hydrolysis with incipient precipitation before its addition. The partial hydrolysis may be effected for example by allowing the solution to stand for a few days, by heating, by the action of carbon dioxide or by the action of sodium bicarbonate. Examples are given. The use of acetanilide as a stabilizer for hydrogen peroxide is also referred to.
GB30511/32A 1931-11-02 1932-10-31 Improvements in or relating to the stabilisation of aqueous solutions containing hydrogen peroxide Expired GB409361A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US409361XA 1931-11-02 1931-11-02

Publications (1)

Publication Number Publication Date
GB409361A true GB409361A (en) 1934-04-30

Family

ID=21913804

Family Applications (1)

Application Number Title Priority Date Filing Date
GB30511/32A Expired GB409361A (en) 1931-11-02 1932-10-31 Improvements in or relating to the stabilisation of aqueous solutions containing hydrogen peroxide

Country Status (1)

Country Link
GB (1) GB409361A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2426154A (en) * 1942-04-01 1947-08-19 Du Pont Stabilization of peroxide solutions
US3114606A (en) * 1960-03-30 1963-12-17 Shell Oil Co Stabilization of hydrogen peroxide
US3333925A (en) * 1964-05-13 1967-08-01 Du Pont Stannate type stabilizer compositions and preparation thereof
WO2004075944A3 (en) * 2003-02-26 2005-01-13 Coloplast As A medical device having a coating comprising hydrogen peroxide and package therefore

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2426154A (en) * 1942-04-01 1947-08-19 Du Pont Stabilization of peroxide solutions
US3114606A (en) * 1960-03-30 1963-12-17 Shell Oil Co Stabilization of hydrogen peroxide
US3333925A (en) * 1964-05-13 1967-08-01 Du Pont Stannate type stabilizer compositions and preparation thereof
WO2004075944A3 (en) * 2003-02-26 2005-01-13 Coloplast As A medical device having a coating comprising hydrogen peroxide and package therefore
US9028858B2 (en) 2003-02-26 2015-05-12 Coloplast A/S Assembly for the preparation of a medical device having a coating comprising hydrogen peroxide

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