GB295213A - Improvements in and relating to the production of benzanthrone derivatives - Google Patents
Improvements in and relating to the production of benzanthrone derivativesInfo
- Publication number
- GB295213A GB295213A GB305027A GB305027A GB295213A GB 295213 A GB295213 A GB 295213A GB 305027 A GB305027 A GB 305027A GB 305027 A GB305027 A GB 305027A GB 295213 A GB295213 A GB 295213A
- Authority
- GB
- United Kingdom
- Prior art keywords
- diamino
- naphthylphenyl
- carboxylic acid
- alkoxy
- hydroxy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B3/00—Dyes with an anthracene nucleus condensed with one or more carbocyclic rings
- C09B3/02—Benzathrones
- C09B3/04—Preparation by synthesis of the nucleus
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
295,213. Anderson, I. B., Thomson, R. F., Thomas, J., and Scottish Dyes, Ltd. Feb. 2, 1927. Benzanthrone derivatives are prepared by trearing 3-alkoxy or hydroxy-4: 4<1>-diamino 1: 1<1>-naphthylphenyl-2<1>-carboxylic acid with an alkali in aqueous solution. The starting material may also be substituted in the 2, 5, 6, 7, 3', 5<1> or 6<1> position by univalent groups such as alkyl, halogen or alkoxy. According to the examples, a mixture of 6-Bz1-diamino-Bz2-methoxybenezanthrone and 6-aminobenzanthrone-Bx1. Bz2.oxide is formed when 4 : 4<1>-diamino-3-methoxy-1 : 1<1>- naphthylphenyl-2<1>-carboxylic acid hydrochloride is dissolved in caustic soda solution and heated until no more methylamine, is evolved: similar treatment of 4: 4<1>-diamino-3-oxy-1 : 1<1>-naphthylphenyl-2<1>-carboxylic acid gives 6-Bz1-diamino- Bz2-oxybenzanthrone in the cold, and then on heating a mixture of this and 6-aminohenzanthrone-Bz1. Bz2-oxide by Joss of ammonia. 4 : 4<1>-Diamino-3-alkoxy or hydroxy-1: 1<1>-naphthylphenyl-2<1>-carboxylic acid is prepared by coupling #-naphthol with diazotized m-aminobenzoic acid, reducing the resulting azo compound in acid solution, and if necessary alkylating the product.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB305027A GB295213A (en) | 1927-02-02 | 1927-02-02 | Improvements in and relating to the production of benzanthrone derivatives |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB305027A GB295213A (en) | 1927-02-02 | 1927-02-02 | Improvements in and relating to the production of benzanthrone derivatives |
Publications (1)
Publication Number | Publication Date |
---|---|
GB295213A true GB295213A (en) | 1928-08-02 |
Family
ID=9751004
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB305027A Expired GB295213A (en) | 1927-02-02 | 1927-02-02 | Improvements in and relating to the production of benzanthrone derivatives |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB295213A (en) |
-
1927
- 1927-02-02 GB GB305027A patent/GB295213A/en not_active Expired
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