GB153055A - Improvements in the manufacture of anthraquinone derivatives - Google Patents
Improvements in the manufacture of anthraquinone derivativesInfo
- Publication number
- GB153055A GB153055A GB1028518A GB1028518A GB153055A GB 153055 A GB153055 A GB 153055A GB 1028518 A GB1028518 A GB 1028518A GB 1028518 A GB1028518 A GB 1028518A GB 153055 A GB153055 A GB 153055A
- Authority
- GB
- United Kingdom
- Prior art keywords
- methylanthraquinone
- nitrobenzene
- aldehyde
- amino
- potassium carbonate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B1/00—Dyes with anthracene nucleus not condensed with any other ring
- C09B1/16—Amino-anthraquinones
- C09B1/20—Preparation from starting materials already containing the anthracene nucleus
- C09B1/22—Dyes with unsubstituted amino groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Condensation products, probably azomethine compounds, are obtained by heating 1-amino-2-methylanthraquinone or its substitution products, or isomeric amino-2-methylanthraquinones, or 2-methylanthraquinone itself, with aromatic nitro compounds in the presence of alkaline reagents; primary aromatic amines may be added to the reaction mixture. The products are vat dyestuffs, and may be hydrolyzed by acids to give 1-aminoanthraquinone-2-aldehyde, or its substitution products or isomers, or anthraquinone-2-aldehyde, respectively. According to examples, condensation products are obtained by heating (1) 1-amino-2-methylanthraquinone with nitrobenzene and potassium carbonate or with nitrobenzene, aniline, and potassium acetate or caustic soda; (2) 1-amino-2-methylanthraquinone with m-nitraniline, naphthalene, and potassium carbonate; (3) 1-amino-2-methylanthraquinone with b -naphthylamine, nitrobenzene, and potassium carbonate; (4) 4-p-toluido - 1 - amino - 2 - methylanthraquinone, nitrobenzene, aniline, and potassium acetate; (5) 1 : 5-diamino-2-methylanthraquinone, nitrobenzene, aniline, and potassium carbonate; (6) 3-amino-2-methylanthraquinone, nitrobenzene, aniline, and potassium carbonate; (7) 2-methylanthraquinone, nitrobenzene, aniline, and potassium carbonate. Examples are also given of the preparation of 1-aminoanthraquinone-2-aldehyde, 4-p-toluido-1-aminoanthraquinone-2-aldehyde, 1 : 5-diaminoanthraquinone-2-aldehyde, 3-aminoanthraquinone-2-aldehyde, and anthraquinone-2-aldehyde from these condensation products. Specifications 7194/01, 24883/10, and 8917/14 are referred to.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1028518A GB153055A (en) | 1918-06-21 | 1918-06-21 | Improvements in the manufacture of anthraquinone derivatives |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1028518A GB153055A (en) | 1918-06-21 | 1918-06-21 | Improvements in the manufacture of anthraquinone derivatives |
Publications (1)
Publication Number | Publication Date |
---|---|
GB153055A true GB153055A (en) | 1920-11-04 |
Family
ID=9965028
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1028518A Expired GB153055A (en) | 1918-06-21 | 1918-06-21 | Improvements in the manufacture of anthraquinone derivatives |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB153055A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0048886A1 (en) * | 1980-09-30 | 1982-04-07 | Siemens Aktiengesellschaft | Liquid-crystal composition containing a pleochroic anthraquinone dye, and process for the production of such a dye |
-
1918
- 1918-06-21 GB GB1028518A patent/GB153055A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0048886A1 (en) * | 1980-09-30 | 1982-04-07 | Siemens Aktiengesellschaft | Liquid-crystal composition containing a pleochroic anthraquinone dye, and process for the production of such a dye |
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