GB263200A - Improvements in the manufacture and production of vat dyestuffs of the benzanthrone series - Google Patents

Improvements in the manufacture and production of vat dyestuffs of the benzanthrone series

Info

Publication number
GB263200A
GB263200A GB32194/26A GB3219426A GB263200A GB 263200 A GB263200 A GB 263200A GB 32194/26 A GB32194/26 A GB 32194/26A GB 3219426 A GB3219426 A GB 3219426A GB 263200 A GB263200 A GB 263200A
Authority
GB
United Kingdom
Prior art keywords
benzanthrone
vat
dyestuff
thioethers
oxidized
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB32194/26A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Publication of GB263200A publication Critical patent/GB263200A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B3/00—Dyes with an anthracene nucleus condensed with one or more carbocyclic rings
    • C09B3/02—Benzathrones
    • C09B3/06—Preparation from starting materials already containing the benzanthrone nucleus

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Coloring (AREA)

Abstract

263,200. I. G. Farbenindustrie Akt.- Ges. Dec. 18, 1925, [Convention date]. Addition to 242,620. Benzanthrone dyes.-The process of the parent Specification, according to which vat-dyes are obtained by treating with alkaline condensing agents benzanthrone-Bz1-thioethers, is modified by replacing the latter by oxidation products of Bz1-benzanthrone-thioethers which have a free 2- position and a sulphoxide or sulphone character; dyestuff formation thereby occurs with greater facility. According to examples :-(1) Bz1- benzanthronylmethylsulphide is oxidized with ammonium persulphate in sulphuric acid solution and the products converted into a violet vat-dyestuff by treatment with caustic potash and alcohol on the water bath; (2) Bz1-Bz1<1>dibenzanthronylsulphide is oxidized in sulphuric acid with hydrogen peroxide and the product converted into isodibenzanthrone by treatment with caustic potash and alcohol at 90-100‹ C. ; (3) benzanthronylsulphide is treated with nitric and sulphuric acids; the dinitrobenzanthronylsulphone so obtained yields the diamino compound by reduction with sodium sulphide; the latter yields with alcoholic potash at 130-140‹ C. a dyestuff which dves cotton from the vat in violet-blue shades changed to marine-blue by chlorination.
GB32194/26A 1925-12-18 1926-12-20 Improvements in the manufacture and production of vat dyestuffs of the benzanthrone series Expired GB263200A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE263200X 1925-12-18

Publications (1)

Publication Number Publication Date
GB263200A true GB263200A (en) 1928-02-16

Family

ID=5983160

Family Applications (1)

Application Number Title Priority Date Filing Date
GB32194/26A Expired GB263200A (en) 1925-12-18 1926-12-20 Improvements in the manufacture and production of vat dyestuffs of the benzanthrone series

Country Status (1)

Country Link
GB (1) GB263200A (en)

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