GB2619456A - Hard carbon negative electrode material, and preparation method therefor and use thereof - Google Patents
Hard carbon negative electrode material, and preparation method therefor and use thereof Download PDFInfo
- Publication number
- GB2619456A GB2619456A GB2314132.8A GB202314132A GB2619456A GB 2619456 A GB2619456 A GB 2619456A GB 202314132 A GB202314132 A GB 202314132A GB 2619456 A GB2619456 A GB 2619456A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hard carbon
- carbon anode
- anode material
- starch
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910021385 hard carbon Inorganic materials 0.000 title claims abstract description 90
- 239000007773 negative electrode material Substances 0.000 title abstract description 9
- 238000002360 preparation method Methods 0.000 title abstract description 5
- 239000011148 porous material Substances 0.000 claims abstract description 47
- 229920002472 Starch Polymers 0.000 claims abstract description 37
- 239000008107 starch Substances 0.000 claims abstract description 34
- 235000019698 starch Nutrition 0.000 claims abstract description 34
- 239000002994 raw material Substances 0.000 claims abstract description 18
- 229910001415 sodium ion Inorganic materials 0.000 claims abstract description 18
- 239000000758 substrate Substances 0.000 claims abstract description 3
- 239000010405 anode material Substances 0.000 claims description 63
- 229920000642 polymer Polymers 0.000 claims description 38
- 238000000034 method Methods 0.000 claims description 20
- 125000003118 aryl group Chemical group 0.000 claims description 19
- 238000007363 ring formation reaction Methods 0.000 claims description 19
- 239000002243 precursor Substances 0.000 claims description 18
- 239000011734 sodium Substances 0.000 claims description 15
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 13
- 238000003763 carbonization Methods 0.000 claims description 13
- 229910052708 sodium Inorganic materials 0.000 claims description 13
- 229920002261 Corn starch Polymers 0.000 claims description 11
- 239000008120 corn starch Substances 0.000 claims description 11
- 229920000945 Amylopectin Polymers 0.000 claims description 6
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 claims description 6
- 239000012798 spherical particle Substances 0.000 claims description 6
- 229920001592 potato starch Polymers 0.000 claims description 5
- 229920000856 Amylose Polymers 0.000 claims description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 3
- 229920003123 carboxymethyl cellulose sodium Polymers 0.000 claims description 3
- 229940063834 carboxymethylcellulose sodium Drugs 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 229940100445 wheat starch Drugs 0.000 claims description 3
- 244000017020 Ipomoea batatas Species 0.000 claims description 2
- 235000002678 Ipomoea batatas Nutrition 0.000 claims description 2
- 240000003183 Manihot esculenta Species 0.000 claims description 2
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 claims description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 2
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 239000011229 interlayer Substances 0.000 abstract description 12
- 238000009830 intercalation Methods 0.000 abstract description 5
- 230000002687 intercalation Effects 0.000 abstract description 5
- 238000009831 deintercalation Methods 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 238000010438 heat treatment Methods 0.000 description 25
- 238000005245 sintering Methods 0.000 description 24
- 239000000047 product Substances 0.000 description 20
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 18
- 229920001030 Polyethylene Glycol 4000 Polymers 0.000 description 18
- 238000004132 cross linking Methods 0.000 description 18
- 230000000052 comparative effect Effects 0.000 description 13
- 239000012299 nitrogen atmosphere Substances 0.000 description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 11
- 229910001873 dinitrogen Inorganic materials 0.000 description 11
- 238000001816 cooling Methods 0.000 description 9
- 229920000620 organic polymer Polymers 0.000 description 8
- 239000003575 carbonaceous material Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 6
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 239000011261 inert gas Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 229910001416 lithium ion Inorganic materials 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 4
- 229910052744 lithium Inorganic materials 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229940057838 polyethylene glycol 4000 Drugs 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 239000002028 Biomass Substances 0.000 description 3
- 229910052786 argon Inorganic materials 0.000 description 3
- 239000011889 copper foil Substances 0.000 description 3
- 238000004146 energy storage Methods 0.000 description 3
- 239000001307 helium Substances 0.000 description 3
- 229910052734 helium Inorganic materials 0.000 description 3
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000000197 pyrolysis Methods 0.000 description 3
- 230000008439 repair process Effects 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000006258 conductive agent Substances 0.000 description 2
- 230000001351 cycling effect Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 230000001788 irregular Effects 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-NJFSPNSNSA-N Carbon-14 Chemical compound [14C] OKTJSMMVPCPJKN-NJFSPNSNSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 241001625808 Trona Species 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
- 229910052808 lithium carbonate Inorganic materials 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000000844 transformation Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
- H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/05—Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/54—Reclaiming serviceable parts of waste accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/16—Pore diameter
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/021—Physical characteristics, e.g. porosity, surface area
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/027—Negative electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Carbon And Carbon Compounds (AREA)
- Battery Electrode And Active Subsutance (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111456775.6A CN114497545A (zh) | 2021-12-01 | 2021-12-01 | 一种硬碳负极材料及其制备方法与应用 |
| PCT/CN2022/116262 WO2023098191A1 (zh) | 2021-12-01 | 2022-08-31 | 一种硬碳负极材料及其制备方法与应用 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| GB202314132D0 GB202314132D0 (en) | 2023-11-01 |
| GB2619456A true GB2619456A (en) | 2023-12-06 |
Family
ID=81493002
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2314132.8A Pending GB2619456A (en) | 2021-12-01 | 2022-08-31 | Hard carbon negative electrode material, and preparation method therefor and use thereof |
Country Status (6)
| Country | Link |
|---|---|
| CN (1) | CN114497545A (de) |
| DE (1) | DE112022002661T5 (de) |
| ES (1) | ES2977437A2 (de) |
| GB (1) | GB2619456A (de) |
| HU (1) | HUP2400185A1 (de) |
| WO (1) | WO2023098191A1 (de) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114497545A (zh) * | 2021-12-01 | 2022-05-13 | 广东邦普循环科技有限公司 | 一种硬碳负极材料及其制备方法与应用 |
| CN115117339A (zh) * | 2022-07-08 | 2022-09-27 | 广东邦普循环科技有限公司 | 一种硬碳材料及其制备方法与应用 |
| CN115838165B (zh) * | 2022-12-29 | 2024-05-17 | 赣州立探新能源科技有限公司 | 硬炭负极材料及其制备方法、二次电池 |
| CN116062731A (zh) * | 2023-02-07 | 2023-05-05 | 湖北万润新能源科技股份有限公司 | 一种制备硬碳的方法 |
| CN116553524B (zh) * | 2023-07-04 | 2023-09-15 | 成都锂能科技有限公司 | 一种钠离子电池硬碳负极材料及其制备工艺、应用 |
| CN116789105A (zh) * | 2023-07-12 | 2023-09-22 | 江苏正力新能电池技术有限公司 | 一种硬碳负极材料、负极极片及二次电池 |
| CN117384323B (zh) * | 2023-12-12 | 2024-03-08 | 成都锂能科技有限公司 | 一种淀粉基前驱体材料及其制备方法、应用 |
| CN118553899A (zh) * | 2024-07-29 | 2024-08-27 | 国科炭美新材料(湖州)有限公司 | 一种沥青基硬碳复合材料及其制备方法和钠离子电池 |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20150333326A1 (en) * | 2014-05-13 | 2015-11-19 | Samsung Electronics Co., Ltd. | Negative electrode active material for non-lithium secondary battery, method of preparing the same, negative electrode for non-lithium secondary battery including the same, and non-lithium secondary battery including the negative electrode |
| CN105098186A (zh) * | 2014-11-11 | 2015-11-25 | 中国科学院物理研究所 | 一种热解无定型碳材料及其制备方法和用途 |
| CN107425215A (zh) * | 2016-05-23 | 2017-12-01 | 宁波杉杉新材料科技有限公司 | 一种淀粉基复合硬碳负极材料的制备方法及用途 |
| CN110877908A (zh) * | 2018-09-06 | 2020-03-13 | 天津大学 | 一种玉米淀粉热解硬碳电极材料的制备方法 |
| CN111244407A (zh) * | 2018-11-28 | 2020-06-05 | 上海杉杉科技有限公司 | 硬碳/石墨复合负极材料、锂离子电池及其制备方法和应用 |
| CN113206246A (zh) * | 2021-04-27 | 2021-08-03 | 天津理工大学 | 钠离子电池生物质硬碳负极材料及其制备方法 |
| CN114497545A (zh) * | 2021-12-01 | 2022-05-13 | 广东邦普循环科技有限公司 | 一种硬碳负极材料及其制备方法与应用 |
-
2021
- 2021-12-01 CN CN202111456775.6A patent/CN114497545A/zh active Pending
-
2022
- 2022-08-31 WO PCT/CN2022/116262 patent/WO2023098191A1/zh active Application Filing
- 2022-08-31 DE DE112022002661.8T patent/DE112022002661T5/de active Pending
- 2022-08-31 HU HU2400185A patent/HUP2400185A1/hu unknown
- 2022-08-31 GB GB2314132.8A patent/GB2619456A/en active Pending
- 2022-08-31 ES ES202390210A patent/ES2977437A2/es active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20150333326A1 (en) * | 2014-05-13 | 2015-11-19 | Samsung Electronics Co., Ltd. | Negative electrode active material for non-lithium secondary battery, method of preparing the same, negative electrode for non-lithium secondary battery including the same, and non-lithium secondary battery including the negative electrode |
| CN105098186A (zh) * | 2014-11-11 | 2015-11-25 | 中国科学院物理研究所 | 一种热解无定型碳材料及其制备方法和用途 |
| CN107425215A (zh) * | 2016-05-23 | 2017-12-01 | 宁波杉杉新材料科技有限公司 | 一种淀粉基复合硬碳负极材料的制备方法及用途 |
| CN110877908A (zh) * | 2018-09-06 | 2020-03-13 | 天津大学 | 一种玉米淀粉热解硬碳电极材料的制备方法 |
| CN111244407A (zh) * | 2018-11-28 | 2020-06-05 | 上海杉杉科技有限公司 | 硬碳/石墨复合负极材料、锂离子电池及其制备方法和应用 |
| CN113206246A (zh) * | 2021-04-27 | 2021-08-03 | 天津理工大学 | 钠离子电池生物质硬碳负极材料及其制备方法 |
| CN114497545A (zh) * | 2021-12-01 | 2022-05-13 | 广东邦普循环科技有限公司 | 一种硬碳负极材料及其制备方法与应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| HUP2400185A1 (hu) | 2024-06-28 |
| CN114497545A (zh) | 2022-05-13 |
| GB202314132D0 (en) | 2023-11-01 |
| ES2977437A2 (es) | 2024-08-23 |
| DE112022002661T5 (de) | 2024-03-07 |
| WO2023098191A1 (zh) | 2023-06-08 |
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