GB2140837A - Sheet of material and method of making same - Google Patents
Sheet of material and method of making same Download PDFInfo
- Publication number
- GB2140837A GB2140837A GB08413841A GB8413841A GB2140837A GB 2140837 A GB2140837 A GB 2140837A GB 08413841 A GB08413841 A GB 08413841A GB 8413841 A GB8413841 A GB 8413841A GB 2140837 A GB2140837 A GB 2140837A
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- GB
- United Kingdom
- Prior art keywords
- sheet
- thermoplastic
- fiber
- mat
- fibers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/40—Shaping or impregnating by compression not applied
- B29C70/50—Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
- B29C70/504—Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC] using rollers or pressure bands
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
- D04H1/541—Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres
- D04H1/5418—Mixed fibres, e.g. at least two chemically different fibres or fibre blends
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B15/00—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00
- B29B15/08—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00 of reinforcements or fillers
- B29B15/10—Coating or impregnating independently of the moulding or shaping step
- B29B15/12—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
- B29C51/002—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor characterised by the choice of material
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
- D04H1/558—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving in combination with mechanical or physical treatments other than embossing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/32—Component parts, details or accessories; Auxiliary operations
- B29C43/44—Compression means for making articles of indefinite length
- B29C43/48—Endless belts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/10—Polymers of propylene
- B29K2023/12—PP, i.e. polypropylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
- B29K2105/08—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts of continuous length, e.g. cords, rovings, mats, fabrics, strands or yarns
- B29K2105/0854—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts of continuous length, e.g. cords, rovings, mats, fabrics, strands or yarns in the form of a non-woven mat
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/25—Solid
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Abstract
A sheet of material 30 having fibers 43 and a thermoplastic material 44 binding the fibers and the thermoplastic material together, as well as a method of making the same, is provided. The thermoplastic material 44 comprises fibers that were initially mixed with the other fibers 43 to provide a fiber textile-like mat 36 that was subject to heat and pressure to melt the thermoplastic fibers and densify the mat so that subsequent cooling of the thermoplastic material in the densified mat caused the cooled thermoplastic material to set and thus caused the cooled densified mat to be a substantially rigid sheet of material. <IMAGE>
Description
SPECIFICATION
Sheet of material and method of making same
This invention relates to an improved sheet of material having fiber means and thermoplastic means bonding the fiber means and the thermoplastic means together, as well as to a method of making such a sheet of material.
It is known in the art to provide a sheet of material having fiber means and thermoplastic means bonding the fiber means and the thermoplastic means together. For example, the thermoplastic means comprises a thermoplastic resin, such as polypropylene, and the fiber means comprises fibers of synthetic or natural origin, such as cellulose, fiberglass, etc., wherein the resulting sheet of material is densified under heat and pressure so as to be substantially flat while being adapted to be subsequently contoured or molded into a desired shape by heat and pressure.One such sheet of material is sold under the Trade name or Trademark "Azdel" by the Pittsburgh
Plate Glass Company of Pittsburgh, Pennsylvania, and another such material is known as "Masonite."
However, it is believed that neither of these two prior known sheets of material are formed by having the thermoplastic means thereof initially in fiber form as required by this invention.
It is also believed that the apparatus for producing the aforementioned prior known sheets of material each comprises an arrangement wherein the fiber means and thermoplastic means are carried between adjacent runs of two endless belts that pass through a first section of the apparatus wherein the thermoplastic means and fiber means are heated and compressed between the adjacent runs of the belts and then pass through another section of the apparatus where the densified material is cooled so as to set the melted thermoplastic means to produce the substantially rigid sheet of material that exits from between the two belts. However, it is not known how the heating section of such an arrangement is provided, or how the cooling section thereof is provided.
It is one feature of this invention to provide an improved sheet of material having fiber means and thermoplastic means bonding the fiber means and the thermoplastic means together.
In particular, it was found according to the teachings of this invention that the thermoplastic means can comprise fibers of thermoplastic material that can be mixed with the other fiber means to provide a fiber textile-like mat means that can be subject to heat and pressure to melt the thermoplastic fibers and densify the mat means so that upon subsequent cooling of the thermoplastic material in the mat means, the cooled thermoplastic material sets and this causes the cooled densified mat means to be a substantially rigid sheet of material that can be subsequently reheated and deformed under pressure to provide a contoured sheet of material that has many uses, such as being utilized to form various components of a transportation vehicle, as will be apparent hereinafter.
For example, it has been found according to the teachings of this invention that such fibers of thermoplastic materal can comprise waste fibers of polypropylene, and the other fiber means can comprise recycled textile fibers of synthetic or natural materiels or combinations thereof. When mixed in a prefered ratio of between 55% to 65% polypropylene fibers and the remaining percent being the recycled fibers, such fibers can be readily formed into a flat moldable textile-like mat means by conventional textile equipment, such as garnett machines or airlay machines.Such fiber textile-like mat means can be subsequently placed in a press with heated platens where the platens compress the mat means to the desired thickness while the polypropylene fibers thereof melt and flow throughout the resulting densified sheet of material to bind all of the other fibers together, so that when the densified sheet of material is subsequently cooled, the same can be removed from the press and can be cut into rectangular sizes or other shapes as required for further processing thereof into final contoured products.
Accordingly, one embodiment of this invention pro-provides a sheet of material having fiber means and thermoplastic means bonding the fiber means and the thermoplastic means together, the thermoplastic means comprising fibers of thermoplastic material that initially were mixed with the fiber means to provide a fiber textile-like mat means that was subject to heat and pressure to melt the thermoplastic fibers and densify the mat means, so that subsequent cooling of the thermoplastic material in the densified mat means caused the cooled thermoplastic material to set and thus caused the cooled densified mat means to be a substantially rigid sheet of material.
Accordingly, it is an object of this invention to provide an improved sheet of material having one or more of the novel features of this invention as set forth above of hereinafter shown or described.
Another object of this invention is to provide an improved method of making such a sheet of material, the method of this invention having one or more of the novel features of this invention as set forth above or hereinafter shown or described.
The features of the invention, and its technical advantages, can be seen from the following description of embodiments together with the claims and the accompanying drawings, in which:
Figure 1 is a schematic view illustrating the method and apparatus of this invention for forming the sheet of material of this invention, and for subsequently reforming that sheet of material into a contoured product;
Figure 2 is an enlarged fragmentary crosssectional view of the fiber textile-like mat means which is being formed in the method and apparatus of Fig. 1;
Figure 3 is a fragmentary cross-sectional view of the improved sheet of material which has been made by the method and apparatus of Fig. 1;;
Figure 4 is a perspective view of one example of a contoured product that can be formed from the sheet of material made by the method and apparatus of Fig. 1, the product of Fig. 4 comprising a door and quarter interior trim panel for a transportation vehicle made by a compression molding process;
Figure 5 is a perspective view of a transportation rear package tray made from the sheet of material of Fig. 3 by a compression or flow molding process;
Figure 6 is a perspective view of a rear hatch cover for a three-door transportation vehicle, the cover being made from the sheet of material of Fig. 3 by a compression or flow molding process;
Figure 7 is a perspective view of a transportation fender liner or splash shield made from the sheet of material of Fig. 3 by a compression molding process;;
Figure 8 is a perspective view of a transportation vehicle rear deck lid, lift gate, or hood liner panel made from the sheet of material of
Fig. 3 by a compression molding process;
Figure 9 is a perspective view of a transportation vehicle heater or air-contitioning duct work made from the sheet of material of Fig.
3 by a compression molding process;
Figure 10 is a perspective view of a transportation vehicle seat back foundation panel made from the sheet of material of Fig. 3 by a compression molding process;
Figure 11 is a perspective view of a transportation vehicle I.P. close-out cover made from the sheet of material of Fig. 3 by a compression or flow molding process;
Figure 12 is a perspective view of a transportation vehicle trunk liner made from the sheet of material of Fig. 3 by a compression molding process;
Figure 13 is a perspective view of a transportation vehicle wiring harness protective cover made from the sheet of material of Fig.
3 by a compression molding process;
Figure 14 is a perspective view of a transportation vehicle formed headliner foundation panel made from the sheet of material of Fig.
3 by a compression molding process;
Figure 15 is a perspective view of a transportation vehicle battery case made from the sheet of material of Fig. 3 by a flow molding process;
Figure 16 is a perspective view of a transportation vehicle electrical component cover made from the sheet of material of Fig. 3 by a flow molding process;
Figure 17 is a perspective view of a transportation vehicle blower housing made from the sheet of material of Fig. 3 by a compression or flow molding process;
Figure 18 is a perspective view of a transportation vehicle air cleaner cover made from the sheet material of Fig. 3 by a compression or flow molding process;
Figure 19 is a perspective view of a transportation vehicle fan shroud made from the sheet of material of Fig. 3 by a compression molding process;;
Figure 20 is a perspective view of a transportation vehicle belt or chain guard made from the sheet of material of Fig. 3 by a compression or flow molding process;
Figure 21 is a perspective and schematic view illustrating a compression or flow molding press apparatus for forming the sheets of material illustrated in Fig. 3 into various contoured products, such as the contoured products illustrated in Figs. 4-20; Figure 22 is an exploded perspective view illustrating the two die members of the press of Fig. 21;
Figure 23 is a schematic cross-sectional view of a method and apparatus for continuously forming the sheets of material of Fig. 3;
Figure 24 is a fragmentary enlarged crosssectional view of one of the roller means, and a center support therefor, of the apparatus of
Fig. 23;;
Figure 25 is a fragmentary schematic side view of another method and apparatus for forming the sheets of material of Fig. 3;
Figure 26 is a fragmentary enlarged side view of a portion of the apparatus of Fig. 25 with the die menbers thereof in one operating position thereof; and Figure 27 is a view similar to Fig. 26 and illustrates the die members of the apparatus of
Fig. 25 in another operating position thereof.
While the various features of this invention are hereinafter illustrated and described as being particularly adapted to provide a sheet of material for forming contoured products for a transportation vehicle, it is to be understood that the various features of this invention can be utilized singly or in any combination thereof to provide sheets of material for other products as desired.
Therefore, this invention is not to be limited to only the embodiments illustrated in the drawings, because the drawings are merely utilized to illustrate some of the wide variety of uses of this invention.
Also, while it is preferred to utilize recycled and/or waste fibers of either natural or synthetic materials to form the sheet of material of this invention as hereinafter set forth be cause of the lower cost of such fibers, it is to be understood that some or all of the various fibers utilized to form the sheet of material of this invention can be virgin if desired.
As illustrated in Fig. 1, the method and apparatus of this invention (for forming a substantially flat rigid sheet of material that is generally indicated by the reference numeral 30 in Fig. 3) is generally indicated by the reference numeral 31 in Fig. 1, and comprises a fiber textile-like mat forming section 32, a heat and pressure mat densifying section 33, and a forming press section 34.
While the fiber textile-like mat forming section 32 can comprise any suitable equipment for receiving a volume of blended fibers, as represented by the reference numeral 35 in Fig. 1, and for forming the same into a relatively thick fiber textile-like mat means 36, as illustrated in Figs. 1 and 2, the apparatus 32 can comprise conventional textile equipment, such as one or more garnetting machines or one or more airlay machines, whereby the blended fibers 35 are layered or folded into the relatively thick fiber textile-like mat means 36, which has a thickness represented by the reference numeral 37 in Fig. 2, such as between 12 to 18 inches thick. However, it is to be understood that the fiber textile-like mat means 36 could have a thickness greater than 18 inches, or could be less than 12 inches, as desired.
The method and apparatus 31 of Fig. 1 takes the fiber textile-like mat means 36, and by means of heat and pressure compresses and densifies the same in a manner hereinafter set forth to form the relatively flat sheet of material 30 of this invention (Figs. 1 and 3), which has a thickness represented by the reference numeral 38 on Fig. 3, such as between 0.08 of an inch and 0.15 of an inch thick.
The densifying apparatus 33 can comprise a conventional heated press means wherein the fiber mat 36 is heated and compressed between opposed platens of the press to form the mat means 36 into the densified sheet means 30 of Fig. 3 in a manner hereinafter set forth, the then permits the densified sheet means 30 to cool so that the same can be removed from the press in a substantially rigid sheet-like form.
However, if desired, the densifying section 33 can comprise the method and apparatus 39 (illustrated schematically in Figs. 23 and 24) which does not form any part of this invention, as the same comprises the sole invention of Thomas E. Lohr and is disclosed and claimed in the co-pending Allen Industries patent application, U.S. Serial No. 499,604, filed 31 May, 1983, G.B. No. 8413842.
Also, the densifying apparatus 33 of Fig. 1 of this invention can comprise the method and apparatus generally indicated by the reference numeral 40 in Figs. 25- 27. However, the particular method and apparatus 40 illustrated in Figs. 25-27 does not form any part of this invention, as the same comprises the sole invention of Edward G. Goldstone and is disclosed and claimed in the co-pending Allen
Industries patent application, U.S. Serial No.
499,608, filed 31 May, 1983, G.B. No.
8413839.
Therefore, while the methods and apparatus 39 and 40 do not form any part of this invention, the same will be hereinafter described in sufficient detail to understand the same so that a person desiring to practice the method and apparatus 31 of this invention as illustrated in Fig. 1 will understand how to utilize the apparatus and methods 39 and 40 for this purpose if desired.
In any event, it can be seen that the sheet of material 30 of this invention can be fed to a press forming section 34 to form a particular contoured product that is generally indicated by the reference numeral 41 in Fig. 1 and comprises a transportation vehicle trim panel that is best illustrated in Fig. 4. However, it is to be understood that the press section 34 can produce other contoured products, such as illustrated in Figs. 5-20, as will be described hereinafter, as well as entirely different products than products for the transportation vehicle field.
While any suitable press apparatus can be utilized for the forming press section 34 of the method and apparatus 31 of this invention, one typical arrangement is generally indicated by the reference numeral 42 in Figs. 21 and 22, and will be hereinafter described.
As previously stated, a plurality of fiber means 43 and fibers 44 of thermoplastic material are blended together in any suitable apparatus and are fed by the supply means 35 to the fiber textile mat making means 32 to produce the fiber textile-like mat means 36 having the thickness 37 previously described.
While the fibers 44 of thermoplastic material can comprise any suitable thermoplastic material, as will be apparent hereinafter, it has been found that the same can comprise polypropylene and can be either virgin or waste fibers, such as from carpeting and the like, or various combinations thereof, and can be blended with the fiber means 43, which can comprise either virgin fibers or recycled fibers of any suitable natural or synthetic material or combinations thereof, such as recycled textile fibers known as "shoddy". As previously stated, the fibers 44 of thermoplastic material can comprise any suitable percent of the total volume of fibers 44 and fiber means 43, and when the fibers 44 are polypropylene the same can comprise between 55% and 65% of the total volume.Also, when some of the fiber means 43 comprises fibers of fiberglass, the fiberglass can comprise up to a total of approximately 20% of the volume of fiber means 43.
In any event, the fiber textile-like mat means forming apparatus 32 causes the fiber means 43 and fibers 44 to be formed into the fiber textile-like mat means 36, which in the press 33 is formed into the sheet of material 30 by having the thermoplastic fibers 44 melted and densified with the fiber means 43 to produce the sheet 30 of the thickness 38 of approximately 0.08 of an inch to approximately 0.15 of an inch thick.
The thus formed sheets 30 can be trimmed and cut to size to form substantially rectangular panels that can be fed to the press forming section 34 to form a contoured shape therefrom for a particular product.
For example, reference is now made to
Figs. 21 and 22, wherein the press arrangement 42 comprises a stack 45 of sheets 30 which are each preheated in a heating oven 46 at a temperature which softens the sheets 30 but does not approach the melting point of the polypropylene thereof. For example, the oven 46 can heat the sheets 30 to approximately 425 F. As the heated sheets 30 are serially discharged from the oven, each sheet 30 is placed in a press 47 between the die faces 48 and 49 of a pair of cooperating dies 50 and 51 thereof which are closed to shape the sheet 30 therebetween in a conventional manner.
For example, when the press 47 is to be utilized in a compression molding operation, the press can exert pressures between 200 to 500 psi, and can have the dies 50 and 51 water cooled to a nominal temperature of approximately 100 F. to dissipate the residual heat from the hot plastic sheet 30 of this invention. Cooling time in the closed die or press 47 necessary to cool the thus formed thermoplastic sheet 30 can vary from approximately 10 seconds to approximately 25 seconds, at which time the completed part 41 is removed therefrom.
If desired, a trim operation can complete the molding phase of the part 41.
Should the press 47 be a flow molding press, the heated sheet 30 is compressed between the dies 50 and 51 under pressures of approximately 2,000 psi, so that the material of the sheet 30 flows to fill the mold cavity provided between the dies 50 and 51 and to thereby be shaped into the desired configuration for the final product 41. A cooling period of approximately 20 seconds to 30 seconds may be required before the part 41 can be removed from the dies 50 and 51; the dies 50 and 51 in the flow molding process are also water cooled to approximately 100 F.
dissipate the residual heat from the plastic sheet 30. With the flow molding process, and with proper die design, there should be little or possibly no flash to remove from the finished molded product 41.
Therefore, it can be seen that this invention is adapted to produce a substantially flat thermoplastic sheet 30 of a given density or densities with the capability of thereafter being subject to post compression molding in a set of matched metal dies, or to post flow molding under high pressure in a set of matched metal dies, to form a desired product.
While it has been found according to the teachings of this invention that the final product is particularly adapted for the transportation industry, it is to be understood that there are other products for which the sheet 30 can be contoured to form a desired final product.
Nevertheless, it can readily be seen in Fig.
4 that one such product that the method and apparatus 31 of this invention can produce from the sheet of material 30 of Fig. 3 is a transportation vehicle interior trim panel 41, and the same can be formed by a compression molding process as previously set forth.
Obviously, the trim panel 41 of Fig. 4 could be any formed foundation panel such as a door and quarter interior trim panel, as desired.
As illustrated in Fig. 5, the product formed from the sheet of material 30 of Fig. 3 can comprise a transportation rear package tray 52 that can be formed from the sheet 30 of
Fig. 3 by a compression or flow molding process as previously described.
As illustrated in Fig. 6, the sheet 30 of Fig.
3 can be formed by a compression or flow molding process as previously described into a rear hatch cover 53, such as for a threedoor transportation vehicle.
As illustrated in Fig. 7, the sheet of material 3Q of Fig. 3 can be formed by a compression molding process into a fender liner or splash sheild 54 for a transportation vehicle or the like.
As illustrated in Fig. 8, the sheet of material 30 of Fig. 3 can be formed by a compression molding process as previously described into a rear deck lid, lift gate, or hood inner panel 55 for a transportation vehicle or the like.
As illustrated in Fig. 9, the sheet of material 30 of Fig. 3 can be formed by a compression molding process as previously described into a heating or airconditioning duct work 56 for a transportation vehicle or the like.
As illustrated in Fig. 10, the sheet of material 30 of Fig. 3 can be formed by a compression molding process as previously described into a seat back foundation panel 57 for a transportation vehicle or the like.
As illustrated in Fig. 11, the sheet of material 30 of Fig. 3 can be formed by a compression or flow molding process as previously described into an l.P. close-out cover 58 for a transportation vehicle or the like.
As illustrated in Fig. 12, the sheet of material 30 of Fig. 3 can be formed by a compression molding process as previously described into a trunk liner 59 for a transportation vehicle or the like.
As illustrated in Fig. 13, the sheet of material 30 of Fig. 3 can be formed by a compression molding process as previously described into a wiring harness protective cover 60 for a transportation vehicle or the like.
As illustrated in Fig. 14, the sheet of material 30 of Fig. 3 can be formed by a compression molding process as previously described into a formed foundation panel 61 for a transportation vehicle or the like.
As illustrated in Fig. 15, the sheet of material 30 of Fig. 3 can be formed by a flow molding process as previously described into a battery case 62 for a transportation vehicle or the like.
As illustrated in Fig. 16, the sheet of material 30 of Fig. 3 can be formed by a flow molding process as previously described into an electrical component cover 63 for a transportation vehicle or the like.
As illustrated in Fig. 17, the sheet of material 30 of Fig. 3 can be formed by a compression or flow molding process into a blower housing 64 for a transportation vehicle or the like.
As illustrated in Fig. 18, the sheet of material 30 of Fig. 3 can be formed by a compression or flow molding process as previously described into an air cleaner cover 65 for a transportation vehicle or the like.
As illustrated in Fig. 19, the sheet of material 30 of Fig. 3 can be formed by a compression molding process as previously described into a fan shroud 66 for a transportation vehicle or the like.
As illustrated in Fig. 20, the sheet of material 30 of Fig. 3 can be formed by a compression or flow molding process as previously described into a belt or chain guard 67 for a transportation vehicle or the like.
Obviously, there are other products for a transportation vehicle that the sheet of material 30 can form by a compression or flow molding process as previously described, such as non-conductive housings, glove boxes, inner panels, etc.
Therefore, this invention is not to be limited to any particular formed product, as it is readily apparent that the press section 34 of the method and apparatus 31 of this invention can be utilized to form the sheet of material 30 into any desired contoured product in the manner previously set forth for the method and apparatus 42 of Figs. 21 and 22.
Thus, it can be seen that this invention not only provides an improved sheet of material having fiber means and thermoplastic means bonding the fiber means and thermoplastic means together, and a method of making the same, but also this invention provides an improved contoured sheet of such material, wherein the contoured sheet of material comprises a shaped product.
For example, the method of this invention is adapted to make a sheet of material 30 having fiber means 43 and thermoplastic means 44 bonding the fiber means 43 and thermoplastic means 44 together, the method comprising the steps of forming the thermoplastic means 44 to comprise fibers 44 of thermoplastic material, mixing the fibers 44 with the fiber means 43 with means 32 to provide a fiber textile-like mat means 36, applying heat and pressure to the mat means 36 with means 33 to melt the thermoplastic fibers 44 and densify the mat means 36, and then cooling the thermoplastic material 44 in the densified mat means 30 so that the cooled thermoplastic material 44 sets and causes the cooled densified mat means 30 to be a substantially rigid sheet of material 30.Such sheet of material 30 can then be heated and shaped between a pair of dies by means 34 to produce a contoured sheet of material that comprises a desired shaped product.
In one example of this invention, the sheet of material 30 was formed from approximately 60% fibers 44 of polypropylene, and approximately 40% textile fibers 43, with the resulting sheet 30 having a thickness of approximately 0.080 of an inch. Such sheet 30 had a flexural strength (ASTM D790) of approximately 6,619 psi and a tensile strength (ASTM D638) of approximately 4,621 psi with a stiffness at i of an inch of approximately 1.50 Ibs. and at + of an inch of approximately 3.00 Ibs., the sheet 30 having a specific gravity of approximately 0.94.
While the fibers 44 of thermoplastic material and the fiber means 43 can be of any suitable length, the same can be anywhere from approximately + inch to approximately 6 inches in length. However, it is to be understood that any desired length fiber means can be utilized.
As previously stated, the densifying apparatus 33 of the method and apparatus 31 of
Fig. 1 can comprise the method and apparatus 39 illustrated in Figs. 23 and 24; such method and apparatus 39 will now be described.
The method and apparatus 39 illustrated in
Figs. 23 and 24 comprises a frame means 68 which carries a chamber defining means 69 that has a heating section 70 and a cooling section 71 which are separated from each other by a wall means 72 through which a lower run 73 and an upper run 74 of a pair of continuous or endless belts 75 and 76 of metallic material can pass in parallel relation from left to right in Fig. 23, the left hand end of the heating chamber 70 also having a wall means 77 separating the chamber 70 from an infeed area 78, while the right hand end of the cooling chamber 71 has a wall means 79 that separates the cooling chamber 71 from an out feed area 80.
The belts 75 and 76 can each comprise a steel belt that is approximately 0.048 of an inch thick and approximately 70 inches wide, the belts 75 and 76 each having a length to accommodate the structure 69, as will be apparent hereinafter.
The upper belt 75 is fed around an in feed roller 81 and an out feed roller 82, while the lower belt 76 is disposed around an in feed roller 83 and an out feed roller 84, so that the runs 73 and 74 of the belts 75 and 76 are disposed substantially in parallel relation and respectively pass between an upper row 85 of a plurality of rollers 86, and a lower row 87 of a plurality of rollers 88, that tend to hold the belt runs 73 and 74 in parallel relation to each other and at a distance which will effectively and completely densify the fiber textile-like mat means 36 that is being fed in between the belts 75 and 76 by a feeding conveyor means that is generally indicated by the reference numeral 89 in Fig. 23.
While the chamber means 69 can have any suitable dimensions, it is believed that the same can have the heating section 70 thereof of approximately 50 feet in length, and the cooling section 71 of approximately 30 feet in length, whereby the number of rollers 86 and 88 could comprise approximately 900 rollers, each having an outside diameter of approximately 1.9 inches, a length of approximately 70 inches, and be spaced apart on approximately 2.4 inch centers.
In order to prevent deflection of the rollers 86 and 88, a central T-shaped support 90 can be disposed adjacent the medial portion of the upper row 85 of rollers 86, while a similar T-shaped support 91 will be disposed adjacent the medial portion of the lower set 87 of rollers 88, with approximately a 0.020 of an inch clearance therebetween to tend to prevent the respective rollers 86 and 88 from deflecting upwardly or downwardly under the pressure caused by compressing the mat means 36 between the runs 73 and 74 of the belts 75 and 76; such supports 90 and 91 are at least located in the heating section 70 of the apparatus 39.
Each roller 86 and 88 has its opposed ends respectively mounted in suitable bearing means 92 carried by the chamber defining means 69 of the frame means 68, as illustrated in Fig. 24.
The heating section 70 of the chamber defining means 69 can be heated with a gas fired heat exchanger blower system that is generally indicated by the reference numeral 93 in Fig. 23 and can be so arranged that the same will tend to preheat the upper run 94 of the upper belt 75 as well as the lower run 95 of the lower belt 76 as the same are brought back to the respective in feed rollers 81 and 83 from the cooling section 71; the upper run 94 of the upper belt 75 is supported by upper rollers 96, while the lower run 95 of the lower belt 76 is supported on lower rollers 97.
In this manner, the upper run 94 of the upper belt 75, and the lower run 95 of the lower belt 76, are suitably preheated so that by the time the same come together at the nip area 98 between the in feed rollers 81 and 83, as illustrated in Fig. 23, the belts 75 and 76 begin to melt the thermoplastic material in the fiber textile-like mat means 36 as the same is compressed between the in feed rollers 81 and 83; the runs 73 and 74 of the belts 75 and 76 maintain a compressive force against the fiber textile-like mat means 36 in the heating section 70 so as to insure that substantially all of the thermoplastic material thereof is melted and compressed with the remaining fiber means 43 to form the substantially flat sheet 30 in a continuous manner by the time the sheet 30 exits the heating chamber 70 through the divider wall means 72.
When the sheet means 30 and belt means 75 and 76 reach the cooling chamber 71, the lower run 73 of the upper belt 75, and. the upper run 74 of the lower belt 76, are respectively cooled by water spraying means 99 which are fed by a pump 100, the water being cooled by a chiller 101 in a manner conventional in the art.
The cooling chamber 71 has a suitable reservoir chamber 102 for receiving the water that has been utilized to chill the belts 75 and 76 so as to return to the pump 130 through a connecting pipe 103.
In this manner, the heating chamber 70 of the apparatus 39 can produce a temperature of approximately 420 F., which will be sufficient to cause the polypropylene fibers 44 to melt and fuse with the other fiber particles 43 into a homogeneous blended material or sheet 30, while the cooling section 71 can "chill" or reduce the temperature of the belts 75 and 76, as well as the material 30 therebetween, to approximately 1 30'F. maximum, so that the chilling "gels" the thermoplastic material of the sheet 30 to set the same and enable it to "release" from the steel belts 75 and 76 so as to pass out of the nip means 104 of the exit roller means 82 and 84 as illustrated in
Fig. 23 to be fed on a suitable conveyor means 105 to any desired area, such as to a suitable apparatus that will, by means of edge shears and the like, fix the finish width of the sheet, with the sheet subsequently being passed through squaring shears where it can be cut into the desired lengths.
Therefore, it can be seen that in the operation of the apparatus 39 illustrated in Fig.
23, the belts 75 and 76 can be driven continuously by the entrance rollers 81 and 83 and exit rollers 82 and 84, so that the runs 73 and 74 thereof move substantially in unison from left to right and carry the fiber textile-like mat means 36 therebetween, which is compressed by the entrance roller means 81 and 83 and backup rollers 86 and
88 in such a manner that in the heating section 70 of the apparatus 39, the fibers 44 of thermoplastic material are sufficiently melted, and the fiber mat 36 is sufficiently densified, so that the thickness thereof is reduced to the desired thickness for the resulting sheet 30, which will be chilled in the cooling section 71 to a temperature thereof that causes the thermoplastic material to set, and also permits the resulting sheet to release from the belts 75 and 76, so that the same can pass onto the conveyor means 105 for further processing thereof as previously set forth.
The other apparatus and method that can be utilized for the densifying apparatus 33 of the method and apparatus 31 of Fig. 1 is generally indicated by the reference numeral 40 in Figs. 25-27, and will now'be described.
As illustrated in Fig. 25, a conveyor means 110 is arranged in such a way that the upper run 111 thereof is adapted to have the fiber textile-like mat means 36 formed thereon by a pair of garnetting machines 112; the fiber mat means 36 is fed through a pair of rollers 113 into a compensating area 114 of the apparatus 40 for a purpose as will be apparent hereinafter.
The densifying area 115 includes a pair of presses that are generally indicated by the reference numerals 116 and 117 in Fig. 25, each having an upper platen 118 and a lower platen 119; the press 116 has the platens 118 and 119 thereof heated, whereas the press 117 has the platens 118 and 119 thereof cooled, such as by a refrigerated water or other suitable coolant being passed through the platens 118 and 119 thereof.
A pair of endless belts 120 and 122 are respectively guided by suitable roller means 123 and 124, so that a lower run 125 of the upper belt 120 joins in parallel relation with the upper run 126 of the lower belt 122 to convey the fiber textile-like mat means 36 through the presses 116 and 117, as illustrated in Figs. 25-27.
While the belts 120 and 122 can be formed of any suitable material, it is believed that the same can be formed of woven fiberglass which is impregnated with teflon so as to function in a manner now to be described.
Suitable drive mechanism and timing mechanism (not shown) are provided for intermittently moving the belts 120 and 122 in such a manner that the same are adapted to feed a certain amount of the fiber textile-like material 36 between the spaced apart platens 118 and 119 of the heated press 116 at the same time that a completed section of the densified mat means 30 is being indexed by the belts 120 and 122 between the open platens 11 8 and 11 9 of the cooling press means 117, as illustrated in Fig. 26.
At this time, movement of the belts 120 and 122 is stopped and the platens 118 and
119 of the heating press means 116 are brought toward each other in the manner illustrated in Fig. 27 to heat and densify the fiber textile-like mat means 36 disposed therebetween in the manner illustrated in Fig. 27, while the platens 118 and 11 9 of the press means 117 are likewise and simultaneously brought toward each other in the manner illustrated in Fig. 27 to chill the section of the densified mat means 36 that has been indexed therebetween, so that the cooled platens 11 8 and 119 will set the thermoplastic material thereof as well as permit the formed sheet means 30 to release from the belts 120 and 122 when the same is subsequently indexed out from between the runs 125 and 126 of the belts 120 and 122 to the right as illustrated in Fig. 25.At this time, suitable cutting apparatus as well as trimming apparatus 127 can be utilized to cut the formed sheet means 30 into individual sheets, as generally indicated by the reference numeral 128 in Fig. 25.
After a certain dwell time, such as 55 seconds, for having the platens 118 and 11 9 of the presses 116 and 117 closed, the upper platens 118 are moved away from the lower platens 119, as illustrated in Fig. 25, so that the belt means 120 and 122 can again index their respective runs 125 and 126 to the right in Fig. 25 to bring a sufficient quantity of undensified fiber textile-like mat means 36 between the platens 118 and 11 9 of the press 116, while the previously densified section of the fiber mat means 30 is indexed between the spaced apart platens 118 and 119 of the chilling press means 117. Such indexing time can be approximately 3 seconds.
Thus, it can be seen that during this intermittent operation of the presses 116 and 117, the garnetting machines 112 can continuously form the mat means 36, as the same will accumulate in the compensating area 114, so that there will be a sufficient quantity thereof to be indexed between the belts 120 and 122 when the same are indexed as previously set forth.
While the press 116 can be operated in any suitable manner, it is believed the same should exert pressures of approximately 200 tons, and should have the platens 118 and 119 thereof heated to approximately 450 F.
Also, the presses 116 and 11 7 should operate in unison, and each should have a press area of approximately 4 feet by 4 feet for performing the previously described operation.
In regards to the cooling press 117, it is believed that the same should have the platens 118 and 11 9 thereof water cooled, so that the same will cool the densified mat means 30 therebetween to approximately 1 30 F. maximum, whereby the molten thermoplastic material thereof will sufficiently gel and thereby set, so that the same will provide a substantially rigid sheet means 30 and also will readily release from the belts 120 and 122 when subsequently indexed therefrom.
Therefore, it can be seen that in the operation of the method and apparatus 40, the fiber textile-like mat means 36 is adapted to be indexed by the belts 120 and 122 between the open platens 11 8 and 119 of the press 116 while the upper platens 118 of both presses 116 and 117 are in the open condition as illustrated in Fig. 25 to position an undensified portion of the mat means 36 between the platens 118 and 119 of the press 116 while a previously densified portion of the mat means 30 in indexed between the platens 118 and 11 9 of the chilling press 117 as illustrated in Fig. 26.Thereafter, the movement of the belts 120 and 122 is terminated and the upper platens 118 of the presses 116 and 117 are brought toward the lower platens 119 thereof in the manner illustrated in Fig. 27, wherein the platens 118 and 11 9 of the press 11 6 sufficiently heat the thermoplastic material of the mat means 36 to melt the same as well as to densify the mat material 36 to form the same into the flat sheet-like form 30 as illustrated in Fig. 27.At this same time, the cooled platens 118 and 119 of the chilling press 11 7 sufficiently gel the previously molten thermoplastic material to cause the same to set and thereby from the densified section 30 therebetween into the substantially rigid sheet-like material 30, which will readily release from the belts 120 and 122 when the same is subsequently indexed therefrom to the right to the trimming apparatus 127 for the purpose previously set forth.
Therefore, it can be seen that this invention not only provides an improved sheet-like material and method of making the same, but also this invention provides an improved contoured sheet means made therefrom.
While the forms and methods of this invention now preferred have been illustrated and described as required, it is to be understood that other forms and method steps can be utilized and still fall within the scope of the
Claims (16)
1. A sheet of material having fiber means and thermoplastic means bonding said fiber means and said thermoplastic means together, the improvement characterized in that said thermoplastic means (44) comprises fibers (44) of thermoplastic material that initially were mixed with said fiber means (43) to provide a fiber textile-like mat means (36) that was subject to heat and pressure to melt said thermoplastic fibers (44) and densify said mat means (36) so that subsequent cooling of said thermoplastic material in said densified mat means caused said cooled thermoplastic material to set and thus caused said cooled densified mat means to be a substantially rigid sheet of material (30).
2. A sheet of material as set forth in claim 1, characterized in that said textile-like mat means (36) was between approximately 6 inches to approximately 18 inches in thickness, and said cooled densified mat means (30) is between approximately 0.08 of an inch to approximately 0.1 5 of an inch in thickness.
3. A sheet of material as set forth in claim
1, characterized in that said thermoplastic material comprises polypropylene.
4. A sheet of material as set forth in claim 3, characterized in that said fibers (44) of thermoplastic material comprises between approximately 55% to approximately 65% of the total volume (35) of said fibers (44) and said fiber means (43).
5. A sheet of material as set forth in claim 4, characterized in that said fiber means (43) comprises recycled textile fibers.
6. A sheet of material as set forth in claim 4, characterized in that said fiber means (43) comprises fibreglass fibers that make up approximately 20% of said total volume (35).
7. A sheet of material as set forth in claim 6, characterized in that said fiber means (43) comprises recycled textile fibers that make up the remainder of the volume of said fiber means (43).
8. A sheet of material as set forth in claim 1, characterized in that said cooled densified mat means (30) is substantially flat.
9. A contoured sheet of material having fiber means and thermoplastic means bonding said fiber means and said thermoplastic means together, said sheet of material initially having been in flat form and then having been contoured under heat and pressure; the improvement characterized in that said thermoplastic means (44) comprises fibers (44) of thermoplastic material that initially were mixed with said fiber means (43) to provide a fiber textile-like mat means (36) that was subject to heat and pressure to melt said thermoplastic fibers (44) and densify said mat means (36) so that upon subsequent cooling of said thermoplastic material in said densified mat means said cooled thermoplastic material sets and thus causes said cooled densified mat means to be a substantially rigid sheet of material (30).
10. A contoured sheet of material as set forth in claim 9, characterized in that said sheet of material defines a part (41) of a transportation vehicle structure.
11. A method of making a sheet of material having fiber means and thermoplastic means bonding said fiber means and said thermoplastic means together, the improvement characterized by the steps of forming said thermoplastic means to comprise fibers of thermoplastic material, mixing said fibers with said fiber means to provide a fiber textile-like mat means, applying heat and pressure to said mat means to melt said thermoplastic fibers and densify said mat means, and then cooling said thermoplastic material in said densified mat means so that said cooled thermoplastic material sets and thus causes said cooled densified mat means to be a substantially rigid sheet of material.
12. A method of making a sheet of material as set forth in claim 11, characterized in that said step of mixing comprises the step of forming said fiber textile-like mat means with a textile forming apparatus, such as a garnett apparatus or an airlay apparatus.
13. A method of making a sheet of material as set forth in claim 11, characterized by the step of subsequently contouring said sheet of material into a shaped product:
14. A method of making a sheet of material as set forth in claim 13, characterized in that said step of contouring comprises the step of again heating said sheet of material and shaping said heated sheet of material between a pair of dies.
15. A method of making a sheet of material having fiber means and thermoplastic means bonding said fiber means and said thermoplastic means together carried out substantially as herein described with reference to the accompanying drawings.
16. A sheet of material produced by the method claimed in any one of Claims 11 to 15.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US49960583A | 1983-05-31 | 1983-05-31 |
Publications (3)
Publication Number | Publication Date |
---|---|
GB8413841D0 GB8413841D0 (en) | 1984-07-04 |
GB2140837A true GB2140837A (en) | 1984-12-05 |
GB2140837B GB2140837B (en) | 1986-08-06 |
Family
ID=23985935
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB08413841A Expired GB2140837B (en) | 1983-05-31 | 1984-05-31 | Sheet of material and method of making same |
Country Status (3)
Country | Link |
---|---|
DE (1) | DE3420218A1 (en) |
GB (1) | GB2140837B (en) |
IT (1) | IT1174107B (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0133893A2 (en) * | 1983-07-02 | 1985-03-13 | Bayer Ag | Method of making fibre-reinforced moulded objects |
FR2663960A1 (en) * | 1990-07-02 | 1992-01-03 | Chomarat & Cie | TEXTILE STRUCTURE FOR REALIZING LAMINATED OR FLAT LAMINATED ARTICLES. |
GB2253420A (en) * | 1991-03-07 | 1992-09-09 | British Tech Group | Polymeric materials |
EP0522308A1 (en) * | 1991-07-10 | 1993-01-13 | Cotton Unlimited, Inc. | Method for making insulation |
EP0896079A1 (en) * | 1997-08-05 | 1999-02-10 | Araco Kabushiki Kaisha | Method of and apparatus for shaping fibrous elastic body |
ITUB20155400A1 (en) * | 2015-11-09 | 2017-05-09 | Sicam S R L Soc It Costruzioni Aeromeccaniche | OVEN FOR THE TEXTILE SECTOR |
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GB582006A (en) * | 1944-02-24 | 1946-11-01 | Celanese Corp | Improvements in or relating to the production of insulating materials |
GB618673A (en) * | 1944-04-14 | 1949-02-25 | Sylvania Ind Corp | Felt-like products and processes for producing the same |
GB701331A (en) * | 1951-06-20 | 1953-12-23 | American Felt Co | Storage batteries and separators therefor |
GB849833A (en) * | 1956-05-11 | 1960-09-28 | Saint Gobain | Improved mats, boards or shaped pieces made from glass fibre or other thermoplastic mineral materials |
GB1067576A (en) * | 1962-08-30 | 1967-05-03 | Du Pont | Improvements in or relating to the production of a non-woven self-bonded fabric |
GB1073182A (en) * | 1963-03-01 | 1967-06-21 | Ici Ltd | Improvements in or relating to bonded textile materials |
GB1228573A (en) * | 1967-08-11 | 1971-04-15 | ||
GB1493001A (en) * | 1974-01-15 | 1977-11-23 | Anic Spa | Production of composite structures |
-
1984
- 1984-05-29 IT IT21156/84A patent/IT1174107B/en active
- 1984-05-30 DE DE19843420218 patent/DE3420218A1/en not_active Withdrawn
- 1984-05-31 GB GB08413841A patent/GB2140837B/en not_active Expired
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB582006A (en) * | 1944-02-24 | 1946-11-01 | Celanese Corp | Improvements in or relating to the production of insulating materials |
GB618673A (en) * | 1944-04-14 | 1949-02-25 | Sylvania Ind Corp | Felt-like products and processes for producing the same |
GB701331A (en) * | 1951-06-20 | 1953-12-23 | American Felt Co | Storage batteries and separators therefor |
GB849833A (en) * | 1956-05-11 | 1960-09-28 | Saint Gobain | Improved mats, boards or shaped pieces made from glass fibre or other thermoplastic mineral materials |
GB1067576A (en) * | 1962-08-30 | 1967-05-03 | Du Pont | Improvements in or relating to the production of a non-woven self-bonded fabric |
GB1073182A (en) * | 1963-03-01 | 1967-06-21 | Ici Ltd | Improvements in or relating to bonded textile materials |
GB1228573A (en) * | 1967-08-11 | 1971-04-15 | ||
GB1493001A (en) * | 1974-01-15 | 1977-11-23 | Anic Spa | Production of composite structures |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0133893A2 (en) * | 1983-07-02 | 1985-03-13 | Bayer Ag | Method of making fibre-reinforced moulded objects |
EP0133893A3 (en) * | 1983-07-02 | 1987-05-20 | Bayer Ag | Method of making fibre-reinforced moulded objects |
FR2663960A1 (en) * | 1990-07-02 | 1992-01-03 | Chomarat & Cie | TEXTILE STRUCTURE FOR REALIZING LAMINATED OR FLAT LAMINATED ARTICLES. |
EP0465382A1 (en) * | 1990-07-02 | 1992-01-08 | ETABLISSEMENTS LES FILS D'AUGUSTE CHOMARAT & CIE. Société Anonyme | Textile sheet for making mouldable mat or moulded products |
GB2253420A (en) * | 1991-03-07 | 1992-09-09 | British Tech Group | Polymeric materials |
GB2253420B (en) * | 1991-03-07 | 1995-03-01 | British Tech Group | Polymeric materials |
EP0522308A1 (en) * | 1991-07-10 | 1993-01-13 | Cotton Unlimited, Inc. | Method for making insulation |
EP0896079A1 (en) * | 1997-08-05 | 1999-02-10 | Araco Kabushiki Kaisha | Method of and apparatus for shaping fibrous elastic body |
US6210147B1 (en) | 1997-08-05 | 2001-04-03 | Araco Kabushiki Kaisha | Method of and apparatus for shaping fibrous elastic body |
CN1089289C (en) * | 1997-08-05 | 2002-08-21 | 亚乐克株式会社 | Method of and apparatus for shaping fibrous elastic body |
ITUB20155400A1 (en) * | 2015-11-09 | 2017-05-09 | Sicam S R L Soc It Costruzioni Aeromeccaniche | OVEN FOR THE TEXTILE SECTOR |
EP3165662A1 (en) | 2015-11-09 | 2017-05-10 | SICAM S.r.l. | Oven for the textile sector |
Also Published As
Publication number | Publication date |
---|---|
GB8413841D0 (en) | 1984-07-04 |
DE3420218A1 (en) | 1984-12-06 |
IT8421156A1 (en) | 1985-11-29 |
IT8421156A0 (en) | 1984-05-29 |
IT1174107B (en) | 1987-07-01 |
GB2140837B (en) | 1986-08-06 |
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Legal Events
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PCNP | Patent ceased through non-payment of renewal fee |