GB210890A - Manufacture of azo-dyestuffs and chromium compounds thereof - Google Patents

Manufacture of azo-dyestuffs and chromium compounds thereof

Info

Publication number
GB210890A
GB210890A GB3092322A GB3092322A GB210890A GB 210890 A GB210890 A GB 210890A GB 3092322 A GB3092322 A GB 3092322A GB 3092322 A GB3092322 A GB 3092322A GB 210890 A GB210890 A GB 210890A
Authority
GB
United Kingdom
Prior art keywords
naphthylamine
sulphonic acid
chromium
aminophenol
diazo
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3092322A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Gesellschaft fuer Chemische Industrie in Basel CIBA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gesellschaft fuer Chemische Industrie in Basel CIBA filed Critical Gesellschaft fuer Chemische Industrie in Basel CIBA
Priority to GB3092322A priority Critical patent/GB210890A/en
Publication of GB210890A publication Critical patent/GB210890A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B45/00Complex metal compounds of azo dyes
    • C09B45/02Preparation from dyes containing in o-position a hydroxy group and in o'-position hydroxy, alkoxy, carboxyl, amino or keto groups
    • C09B45/14Monoazo compounds
    • C09B45/16Monoazo compounds containing chromium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

o-Amino-o-oxyazo dyes are prepared by coupling an o-diazo-phenol not containing a nitro group, with a naphthylamine or a derivative or substitution product which is capable of orthocoupling and which contains no hydroxyl group or further amino group; the same products are obtained by converting the diazo components into O-acidyl derivatives, diazotizing and coupling, and then saponifying. The products dye wool in orange shades changed to green by after-chroming and to bluish-red to bordeaux by after-coppering; by treatment with agents yielding chromium the dyestuffs yield chromium compounds which dye wool in fast green tints. According to examples (1) 2-diazo-1-phenol-4-sulphonic acid is coupled with b -naphthylamine hydrochloride, and the double compound of the dyestuff with b -naphthylamine decomposed with caustic soda; the same dyestuff is obtained by coupling 2 - diazo - 1-phenol-p-toluenesulphonic-ester-4-sulphonic acid with b -naphthylamine and saponifying; it is converted into a chromium compound by boiling with chromium formate; (2) diazotized 4-chlor-2-aminophenol-5-sulphonic acid is coupled with 1-naphthylamine-4-sulphonic acid and the product boiled with hydrated chromium oxide, filtered and evaporated. Dyestuffs from the following pairs of compounds are also described:-4-chloro-2-aminophenol and 2-naphthylamine-6-sulphonic acid or 5 : 7-disulphonic acid; 4-chlor-2-aminophenol-5-sulphonic acid and b -naphthylamine or its o -methane-sulphonic acid; 4-methyl-2-aminophenol-5-sulphonic acid and b -naphthylamine.
GB3092322A 1922-11-11 1922-11-11 Manufacture of azo-dyestuffs and chromium compounds thereof Expired GB210890A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB3092322A GB210890A (en) 1922-11-11 1922-11-11 Manufacture of azo-dyestuffs and chromium compounds thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3092322A GB210890A (en) 1922-11-11 1922-11-11 Manufacture of azo-dyestuffs and chromium compounds thereof

Publications (1)

Publication Number Publication Date
GB210890A true GB210890A (en) 1924-02-11

Family

ID=10315193

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3092322A Expired GB210890A (en) 1922-11-11 1922-11-11 Manufacture of azo-dyestuffs and chromium compounds thereof

Country Status (1)

Country Link
GB (1) GB210890A (en)

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