GB1497691A - Finely-divided polymeric solids having physical propertie - Google Patents
Finely-divided polymeric solids having physical propertieInfo
- Publication number
- GB1497691A GB1497691A GB17485/75A GB1748575A GB1497691A GB 1497691 A GB1497691 A GB 1497691A GB 17485/75 A GB17485/75 A GB 17485/75A GB 1748575 A GB1748575 A GB 1748575A GB 1497691 A GB1497691 A GB 1497691A
- Authority
- GB
- United Kingdom
- Prior art keywords
- htoc
- reacted
- product
- propylene oxide
- maleic anhydride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000007787 solid Substances 0.000 title abstract 3
- 230000000704 physical effect Effects 0.000 title 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 abstract 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 abstract 9
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 8
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 abstract 7
- 239000000047 product Substances 0.000 abstract 7
- 239000000203 mixture Substances 0.000 abstract 4
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 abstract 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 abstract 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 abstract 2
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 abstract 2
- FGLBSLMDCBOPQK-UHFFFAOYSA-N 2-nitropropane Chemical compound CC(C)[N+]([O-])=O FGLBSLMDCBOPQK-UHFFFAOYSA-N 0.000 abstract 2
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 abstract 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 abstract 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 abstract 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 abstract 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 abstract 2
- -1 alkyl mercaptan Chemical compound 0.000 abstract 2
- 125000002947 alkylene group Chemical group 0.000 abstract 2
- 239000007795 chemical reaction product Substances 0.000 abstract 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- 150000002894 organic compounds Chemical class 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 abstract 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 abstract 1
- GNSFRPWPOGYVLO-UHFFFAOYSA-N 3-hydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCO GNSFRPWPOGYVLO-UHFFFAOYSA-N 0.000 abstract 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 abstract 1
- 239000004342 Benzoyl peroxide Substances 0.000 abstract 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 abstract 1
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 abstract 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 abstract 1
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 229960003328 benzoyl peroxide Drugs 0.000 abstract 1
- 235000019400 benzoyl peroxide Nutrition 0.000 abstract 1
- 229920001400 block copolymer Polymers 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000012986 chain transfer agent Substances 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 abstract 1
- 229960001760 dimethyl sulfoxide Drugs 0.000 abstract 1
- 125000003700 epoxy group Chemical group 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- QQBPIHBUCMDKFG-UHFFFAOYSA-N phenazopyridine hydrochloride Chemical compound Cl.NC1=NC(N)=CC=C1N=NC1=CC=CC=C1 QQBPIHBUCMDKFG-UHFFFAOYSA-N 0.000 abstract 1
- 229920001281 polyalkylene Polymers 0.000 abstract 1
- 229920000570 polyether Polymers 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F246/00—Copolymers in which the nature of only the monomers in minority is defined
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Polymerisation Methods In General (AREA)
- Polyurethanes Or Polyureas (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/465,234 US3931092A (en) | 1974-04-29 | 1974-04-29 | Finely-divided polymeric solids having improved physical properties |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1497691A true GB1497691A (en) | 1978-01-12 |
Family
ID=23846972
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB17485/75A Expired GB1497691A (en) | 1974-04-29 | 1975-04-28 | Finely-divided polymeric solids having physical propertie |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US3931092A (https=) |
| JP (2) | JPS5246272B2 (https=) |
| BE (1) | BE828524A (https=) |
| CA (1) | CA1075396A (https=) |
| DE (1) | DE2519139C3 (https=) |
| FR (1) | FR2268830B1 (https=) |
| GB (1) | GB1497691A (https=) |
| IT (1) | IT1035486B (https=) |
| NL (1) | NL7504874A (https=) |
| SE (1) | SE7504925L (https=) |
| ZA (1) | ZA752715B (https=) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2161170A (en) * | 1984-07-06 | 1986-01-08 | Ricoh Kk | Production of polymer particles |
Families Citing this family (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4014846A (en) * | 1974-04-29 | 1977-03-29 | Basf Wyandotte Corporation | Low-viscous, stable polymer dispersions and polyurethanes prepared therefrom |
| CA1074049A (en) * | 1974-11-13 | 1980-03-18 | Russell Van Cleve | Polymer/polyols and polyurethane derivatives thereof |
| JPS52129752A (en) * | 1976-04-23 | 1977-10-31 | Nippon Oil Co Ltd | Novel composition |
| US4226756A (en) * | 1976-07-06 | 1980-10-07 | Union Carbide Corporation | Mixtures of extenders and polyols or polymer/polyols useful in polyurethane production |
| CA1106989A (en) * | 1976-09-10 | 1981-08-11 | John T. Patton, Jr. | Emulsion polymerization of ethylenically unsaturated monomers in hydroxy-terminated organic compounds |
| US4140667A (en) * | 1977-03-31 | 1979-02-20 | Olin Corporation | Graft copolymers from vinyl monomers and unsaturated polyols containing alkenyl aryl constituents and polyurethanes prepared therefrom |
| US4174152A (en) * | 1978-02-13 | 1979-11-13 | American Cyanamid Company | Electrochromic devices with polymeric electrolytes |
| US4312973A (en) * | 1978-08-10 | 1982-01-26 | Union Carbide Corporation | Polyurethane elastomers prepared from polyol or polymer/polyol-chain extender mixtures |
| US4233425A (en) * | 1978-11-15 | 1980-11-11 | The Dow Chemical Company | Addition polymerizable polyethers having pendant ethylenically unsaturated urethane groups |
| US4214055A (en) | 1978-11-17 | 1980-07-22 | Union Carbide Corporation | High resilience flame-retardant polyurethane foams based on polymer/polyol compositions |
| US4242476A (en) * | 1978-11-17 | 1980-12-30 | Union Carbide Corporation | Polymer/polyol compositions containing vinylidene chloride |
| JPS5844711B2 (ja) * | 1979-07-04 | 1983-10-05 | 日東電工株式会社 | 水溶性感圧接着剤組成物 |
| US4327005A (en) * | 1980-08-18 | 1982-04-27 | Basf Wyandotte Corporation | Process for the preparation of stabilized polymer dispersions in polyol at low temperature |
| US4359571A (en) * | 1981-09-02 | 1982-11-16 | Basf Wyandotte Corporation | Process for preparing graft polymer dispersions and polyurethanes prepared therefrom |
| USRE33291E (en) * | 1982-04-01 | 1990-08-07 | Basf Corporation | Process for the preparation of white graft polymer dispersions and flame-retardant polyurethane foams |
| US4690956A (en) | 1982-04-01 | 1987-09-01 | Basf Corporation | Process for the preparation of graft polymer dispersions and flame-retardant polyurethane foams |
| US4550194A (en) * | 1982-04-01 | 1985-10-29 | Basf Wyandotte Corporation | Process for the preparation of polyether-ester polyols |
| US4435592A (en) | 1982-09-29 | 1984-03-06 | Basf Wyandotte Corporation | Process for the preparation of polyether-ester polyols |
| US4503207A (en) * | 1983-07-05 | 1985-03-05 | Basf Wyandotte Corporation | Process for the preparation of acrylamide graft polymer dispersions |
| US4555527A (en) * | 1983-07-05 | 1985-11-26 | Basf Wyandotte Corporation | Process for the preparation of acrylamide graft polymer dispersions |
| US4568705A (en) * | 1984-05-17 | 1986-02-04 | Basf Wyandotte Corporation | Graft polymer dispersion in a mixture of low molecular weight polyols and polyether polyols and polyurethane foams prepared therefrom |
| US4522976A (en) * | 1984-05-17 | 1985-06-11 | Basf Wyandotte Corporation | Graft polymer dispersion in a mixture of low molecular weight polyols and polyether polyols and polyurethane foams prepared therefrom |
| US4652589A (en) * | 1985-02-08 | 1987-03-24 | Union Carbide Corporation | Polymer/polyols having improved combustion resistance and intrinsic viscosity, methods of making same and polyurethanes prepared therefrom |
| DE3685370D1 (en) * | 1985-05-30 | 1992-06-25 | Mita Industrial Co Ltd | Elektrophotographischer toner. |
| JPH0684495B2 (ja) * | 1986-06-03 | 1994-10-26 | 旭硝子株式会社 | 表面改質剤 |
| US4997857A (en) * | 1986-09-30 | 1991-03-05 | Arco Chemical Technology, Inc. | Stabilizers for polymer/polyols |
| US5196476A (en) * | 1990-06-12 | 1993-03-23 | Arco Chemical Technology, L.P. | Polymer/polyol and preformed stabilizer systems |
| KR960011890B1 (ko) * | 1991-10-14 | 1996-09-04 | 미쓰이도오아쓰가가쿠 가부시키가이샤 | 폴리머 폴리올과 그의 제조방법 |
| US5237024A (en) * | 1992-06-11 | 1993-08-17 | Monsanto Company | Preparing monoalkenyl aromatic monomer-maleic half ester copolymer |
| US5412048A (en) * | 1993-07-26 | 1995-05-02 | General Electric Company | Process for producing cross-linked monodispersed polymeric particles |
| US5656678A (en) * | 1996-05-14 | 1997-08-12 | Hickory Springs Manufacturing Company | Method and apparatus for the production of polyurethane foam using variable capacity trough |
| US6172164B1 (en) | 1999-04-01 | 2001-01-09 | Basf Corporation | Process for making graft polyols using t-amyl peroxy free radical initiator |
| EP1622960A4 (en) * | 2003-04-23 | 2008-04-23 | Stepan Co | LIQUID CURING AGENT FOR OPEN COIL FOAMS |
| US7759423B2 (en) * | 2004-08-02 | 2010-07-20 | Bayer Materialscience Llc | Polymer polyols with ultra-high solids contents |
| US7179882B2 (en) * | 2004-08-02 | 2007-02-20 | Bayer Materialscience Llc | Low viscosity polymer polyols |
| WO2007047661A2 (en) * | 2005-10-18 | 2007-04-26 | Stepan Company | Prepolymer containing a liquid hardness agent for open cell foams |
| US7776969B2 (en) | 2006-12-04 | 2010-08-17 | Bayer Materialscience Llc | Allophanate-modified stabilizers and the polymer polyols prepared from these stabilizers |
| US20090163613A1 (en) | 2007-12-20 | 2009-06-25 | Guelcher Scott A | Polymer polyols with improved properties and a process for their production |
| WO2011075343A1 (en) | 2009-12-17 | 2011-06-23 | Dow Global Technologies Inc. | Ethylene oxide capping of secondary hydroxyl polyols |
| KR101951495B1 (ko) | 2011-06-30 | 2019-02-22 | 다우 글로벌 테크놀로지스 엘엘씨 | 코팅, 접착제, 실란트 및 탄성중합체 응용을 위한 실란 종결된 중합체 |
| US8946313B2 (en) | 2011-12-16 | 2015-02-03 | Bayer Materialscience Llc | Hybrid PHD/PMPO polyols for polyurethane foam applications |
| US9163099B2 (en) | 2013-03-08 | 2015-10-20 | Bayer Materialscience Llc | Polybutadiene modified polymer polyols, foams prepared from polybutadiene modified polymer polyols, and processes for the production thereof |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2851379A (en) * | 1953-11-18 | 1958-09-09 | Distillers Co Yeast Ltd | Process of impregnating material with a resinous bonding composition |
| US3089863A (en) * | 1956-06-29 | 1963-05-14 | Devoe & Raynolds Co Inc | Process for preparation of a polyester resin of pentaerythritol, a dicarboxylic acid anhydride, and a monoepoxide |
| US3222421A (en) * | 1961-12-01 | 1965-12-07 | American Cyanamid Co | Polyester resinous compositions |
| GB1314974A (en) * | 1969-06-19 | 1973-04-26 | Bp Chem Int Ltd | Polyester moulding compositions |
| US3718714A (en) * | 1970-09-16 | 1973-02-27 | Union Carbide Corp | Unsaturated polyester compositions |
| JPS5246272A (en) * | 1975-10-08 | 1977-04-12 | Matsushita Electric Ind Co Ltd | Balanced weight of rotary machines |
-
1974
- 1974-04-29 US US05/465,234 patent/US3931092A/en not_active Expired - Lifetime
-
1975
- 1975-04-24 NL NL7504874A patent/NL7504874A/xx not_active Application Discontinuation
- 1975-04-28 GB GB17485/75A patent/GB1497691A/en not_active Expired
- 1975-04-28 ZA ZA00752715A patent/ZA752715B/xx unknown
- 1975-04-28 IT IT49329/75A patent/IT1035486B/it active
- 1975-04-28 SE SE7504925A patent/SE7504925L/xx unknown
- 1975-04-28 CA CA225,856A patent/CA1075396A/en not_active Expired
- 1975-04-29 BE BE155892A patent/BE828524A/xx not_active IP Right Cessation
- 1975-04-29 FR FR7513381A patent/FR2268830B1/fr not_active Expired
- 1975-04-29 DE DE2519139A patent/DE2519139C3/de not_active Expired
- 1975-04-30 JP JP50051627A patent/JPS5246272B2/ja not_active Expired
-
1977
- 1977-04-04 JP JP3768477A patent/JPS5388894A/ja active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2161170A (en) * | 1984-07-06 | 1986-01-08 | Ricoh Kk | Production of polymer particles |
Also Published As
| Publication number | Publication date |
|---|---|
| IT1035486B (it) | 1979-10-20 |
| JPS50149778A (https=) | 1975-12-01 |
| FR2268830B1 (https=) | 1981-03-27 |
| DE2519139C3 (de) | 1981-04-16 |
| ZA752715B (en) | 1976-04-28 |
| FR2268830A1 (https=) | 1975-11-21 |
| BE828524A (fr) | 1975-08-18 |
| JPS5246272B2 (https=) | 1977-11-22 |
| US3931092A (en) | 1976-01-06 |
| SE7504925L (sv) | 1975-10-30 |
| DE2519139B2 (de) | 1980-07-31 |
| DE2519139A1 (de) | 1975-10-30 |
| NL7504874A (nl) | 1975-10-31 |
| CA1075396A (en) | 1980-04-08 |
| AU8047675A (en) | 1976-10-28 |
| JPS5388894A (en) | 1978-08-04 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |