GB1403329A - Vapour-phase alkylation in presence of crystalline alumino silicate catalyst - Google Patents

Vapour-phase alkylation in presence of crystalline alumino silicate catalyst

Info

Publication number
GB1403329A
GB1403329A GB1226073A GB1226073A GB1403329A GB 1403329 A GB1403329 A GB 1403329A GB 1226073 A GB1226073 A GB 1226073A GB 1226073 A GB1226073 A GB 1226073A GB 1403329 A GB1403329 A GB 1403329A
Authority
GB
United Kingdom
Prior art keywords
benzene
toluene
methanol
alkylating agent
vapour
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1226073A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of GB1403329A publication Critical patent/GB1403329A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/867—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an aldehyde or a ketone
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3408—Regenerating or reactivating of aluminosilicate molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
GB1226073A 1972-04-28 1973-03-14 Vapour-phase alkylation in presence of crystalline alumino silicate catalyst Expired GB1403329A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US24836572A 1972-04-28 1972-04-28
US25277672A 1972-05-12 1972-05-12

Publications (1)

Publication Number Publication Date
GB1403329A true GB1403329A (en) 1975-08-28

Family

ID=26939306

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1226073A Expired GB1403329A (en) 1972-04-28 1973-03-14 Vapour-phase alkylation in presence of crystalline alumino silicate catalyst

Country Status (7)

Country Link
JP (1) JPS5644050B2 (sl)
CA (1) CA1000745A (sl)
DE (1) DE2321399C2 (sl)
FR (1) FR2181940B1 (sl)
GB (1) GB1403329A (sl)
IT (1) IT982848B (sl)
NL (1) NL7305993A (sl)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0005315A2 (en) * 1978-05-08 1979-11-14 Imperial Chemical Industries Plc Production of xylene hydrocarbons
EP0029652A1 (en) * 1979-11-20 1981-06-03 Mobil Oil Corporation Preparation of 2-phenylalkanes
WO1997003933A1 (en) * 1995-07-19 1997-02-06 Amoco Corporation Conversion of aromatics and olefins
WO2019190774A1 (en) * 2018-03-30 2019-10-03 Exxonmobil Chemical Patents Inc. Process for co-production of mixed xylenes and high octane c9+ aromatics

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3751504A (en) * 1972-05-12 1973-08-07 Mobil Oil Corp Vapor-phase alkylation in presence of crystalline aluminosilicate catalyst with separate transalkylation
NZ178543A (en) 1974-09-23 1978-04-03 Mobil Oil Corp Conversion catalyst, crystalline alumin osilicate zeolite containing phosphorus
US4016218A (en) * 1975-05-29 1977-04-05 Mobil Oil Corporation Alkylation in presence of thermally modified crystalline aluminosilicate catalyst
NZ183608A (en) * 1976-03-31 1978-12-18 Mobil Oil Corp Aluminosilicate zeolite catalyst for selectine production of para-diakyl substituted benzenes
DE2622318C2 (de) * 1976-05-19 1986-01-02 Mobil Oil Corp., New York, N.Y. Verfahren zur Alkylierung oder Transalkylierung von aromatischen Kohlenwasserstoffen
US4107224A (en) * 1977-02-11 1978-08-15 Mobil Oil Corporation Manufacture of ethyl benzene
CA1135286A (en) * 1978-12-14 1982-11-09 Mobil Oil Corporation Alkylation of aromatic hydrocarbons
US4393262A (en) * 1978-12-14 1983-07-12 Mobil Oil Corporation Production of isopropylbenzene
US4329533A (en) * 1980-05-05 1982-05-11 Mobil Oil Corporation Shape selective reactions with zeolite catalysts modified with group IA metals
JPS5939836A (ja) * 1982-08-27 1984-03-05 Toyo Soda Mfg Co Ltd １，２，４，５−テトラアルキルベンゼンの製造方法
JPS59128210A (ja) * 1982-12-30 1984-07-24 Asahi Chem Ind Co Ltd 結晶性アルミノシリケ−ト、その製造方法及びそのアルミノシリケ−トから成るモノアルキルベンゼンのアルキル化用触媒
US6670517B1 (en) * 2000-08-24 2003-12-30 Exxon Mobil Chemical Patents Inc. Process for alkylating aromatics
IT1392325B1 (it) * 2008-09-11 2012-02-28 Polimeri Europa Spa Processo per l'alchilazione di benzene con isopropanolo o miscele di isopropanolo e propilene
JP6696512B2 (ja) 2015-12-15 2020-05-20 コニカミノルタ株式会社 有機エレクトロルミネッセンス素子、有機エレクトロルミネッセンス素子の製造方法、及び有機エレクトロルミネッセンス素子材料

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2351897A (en) * 1944-06-20 Typewriter-calculating machine
US2904607A (en) * 1957-01-29 1959-09-15 Exxon Research Engineering Co Alkylation of aromatics
GB1161974A (en) * 1967-04-14 1969-08-20 Mobil Oil Corp Synthetic Crystalline Aluminosilicate and method of preparing the same
US3631120A (en) * 1969-06-13 1971-12-28 Exxon Research Engineering Co Alkylation of aromatic hydrocarbons

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0005315A2 (en) * 1978-05-08 1979-11-14 Imperial Chemical Industries Plc Production of xylene hydrocarbons
EP0005315A3 (en) * 1978-05-08 1979-11-28 Imperial Chemical Industries Limited Process for the alkylation of aromatic hydrocarbons
EP0029652A1 (en) * 1979-11-20 1981-06-03 Mobil Oil Corporation Preparation of 2-phenylalkanes
US4301317A (en) 1979-11-20 1981-11-17 Mobil Oil Corporation Preparation of 2-phenylalkanes
WO1997003933A1 (en) * 1995-07-19 1997-02-06 Amoco Corporation Conversion of aromatics and olefins
NL1003627C2 (nl) * 1995-07-19 1997-03-21 Amoco Corp Conversie van aromaten en olefinen.
US5792894A (en) * 1995-07-19 1998-08-11 Amoco Corporation Conversion of aromatic and olefins
WO2019190774A1 (en) * 2018-03-30 2019-10-03 Exxonmobil Chemical Patents Inc. Process for co-production of mixed xylenes and high octane c9+ aromatics
CN111954652A (zh) * 2018-03-30 2020-11-17 埃克森美孚化学专利公司 混合二甲苯和高辛烷值c9+芳族化合物的共同制备方法
US11053176B2 (en) 2018-03-30 2021-07-06 Exxonmobil Chemical Patents Inc. Process for co-production of mixed xylenes and high octane C9+ aromatics
CN111954652B (zh) * 2018-03-30 2022-11-08 埃克森美孚化学专利公司 混合二甲苯和高辛烷值c9+芳族化合物的共同制备方法

Also Published As

Publication number Publication date
DE2321399A1 (de) 1973-11-15
JPS4920124A (sl) 1974-02-22
FR2181940A1 (sl) 1973-12-07
JPS5644050B2 (sl) 1981-10-16
CA1000745A (en) 1976-11-30
DE2321399C2 (de) 1982-09-16
FR2181940B1 (sl) 1977-02-04
IT982848B (it) 1974-10-21
NL7305993A (sl) 1973-10-30

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Legal Events

Date Code Title Description
PS Patent sealed
PE20 Patent expired after termination of 20 years

Effective date: 19930313