KR910011715A - 벤젠 또는 치환된 벤젠을 알킬화시키거나 알킬화 벤젠을 트랜스알킬화시키는 방법 및 이를 위한 촉매 조성물 - Google Patents

벤젠 또는 치환된 벤젠을 알킬화시키거나 알킬화 벤젠을 트랜스알킬화시키는 방법 및 이를 위한 촉매 조성물 Download PDF

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KR910011715A
KR910011715A KR1019900021123A KR900021123A KR910011715A KR 910011715 A KR910011715 A KR 910011715A KR 1019900021123 A KR1019900021123 A KR 1019900021123A KR 900021123 A KR900021123 A KR 900021123A KR 910011715 A KR910011715 A KR 910011715A
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benzene
catalyst
silica
crystal structure
ray diffraction
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KR1019900021123A
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KR100206050B1 (ko
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존리 구오-슈
엠. 가르세스 쥬안
에르. 마이마 감트
요트. 엠. 판 데어 알스트 마토이스
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리챠드 지. 워터맨
더 다우 케미칼 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
    • C07C37/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms by addition reactions, i.e. reactions involving at least one carbon-to-carbon unsaturated bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/126—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of more than one hydrocarbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Heat Treatment Of Sheet Steel (AREA)
  • Separation Of Gases By Adsorption (AREA)

Abstract

내용 없음

Description

벤젠 또는 치환된 벤젠을 알킬화시키거나 알킬화 벤젠을 트랜스알킬화시키는 방법 및 이를 위한 촉매 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (12)

  1. 벤젠 또는 치환된 벤젠을 실리카/알루미나 몰비가 30 : 1이상이고 X-선 회절법에 의해 대칭수가 1 이상인 것으로 측정되는 결정구조를 갖는 산성 모오데나이트 제올라이트 및 내부 실리카 결합제를 포함하는 촉매의 존재하에 알킬화 벤젠 또는 알킬화 치환된 벤젠이 생성되고 촉매는 필수적으로 사용한지 500시간 이상후에 탈환성화를 나타내지 않도록 하는 반응조건하에서 탄소수 2 내지 18의 알킬화제를 접촉시킴을 특징으로 하여, 벤젠 또는 치환된 벤젠을 알킬화시키거나, 알킬화 벤젠을 트랜스알킬화시키는 방법.
  2. 제1항에 있어서, 알킬화제가 프로필렌 또는 에틸렌인 방법.
  3. 제1항에 있어서, 촉매의 실리카/알루미나 몰비가 40 : 1 내지 300 : 1인 방법.
  4. 제1항에 있어서, 온도가 100 내지 250℃범위인 방법.
  5. 벤젠과 디알킬화 벤젠의 혼합물을 실리카/알루미나 몰비가 30 : 1 이상이고 X-선 회절법에 의해 대칭수가 1이상인 것으로 측정되는 결정구조를 갖는 산성 모오데나이트 제올라이트 및 내부 실리카 결합제를 포함하는 촉매의 존재하에 필수적으로 무색 알킬화 벤젠이 생성되고 촉매는 필수적으로 사용한지 500시간 이상후에 탈활성화를 나타내지 않도록 하는 반응조건하에서 접촉시킴을 특징으로 하여 트랜스알킬화시킴으로써 큐멘 및 에틸벤젠을 포함하는 알킬화 벤젠을 제조하는 방법.
  6. 제5항에 있어서, 촉매의 실리카/알루미나 몰비가 40 : 1 내지 300 : 1인 방법.
  7. 제5항에 있어서, 촉매 복합체가 내부 실리카 결합체인 방법.
  8. 제5항에 있어서, 온도가 100 내지 250℃ 범위인 방법.
  9. 벤젠과 디이소프로필벤젠 및 프로필렌을 실리카/알루미나 몰비가 30 : 1 이상이고 X-선 회절법에 의해 대칭지수가 1이상인 것으로 측정되는 결정구조를 갖는 산성 모오데나이트 제올라이트 및 내부 실리카 결합제를 포함하는 촉매의 존재하에 필수적으로 무색 큐멘이 생성되고 촉매는 사용한지 500시간 이상후에 탈활성화되지 않도록 하는 반응조건하에서 접촉시킴을 특징으로 하여 알킬화/트랜스알킬화시킴으로써, 큐멘을 제조하는 방법.
  10. 벤젠과 디에틸벤젠 및 에틸렌을 실리카/알루미나 몰비가 30 : 1 이상이고 X-선 회절법에 의해 대칭지수가 1 이상인 것으로 측정되는 결정구조를 갖는 산성 모오데나이트 제올라이트 및 내부 실리카 결합제를 포함하는 촉매의 존재하에 필수적으로 무색 에틸벤젠이 생성되고 촉매는 사용한지 500시간 이상후에 탈활성화 되지 않도록 하는 반응조건하에서 접촉시킴을 특징으로 하여, 알킬화/트랜스알킬화시킴으로써, 에틸벤젠을 제조하는 방법.
  11. 제1항에 있어서, 치환된 벤젠이 페놀 또는 아닐린인 방법.
  12. 실리카/알루미나 몰비가 30 : 1 이상이고, X-선 회절법에 의해 대칭지수가 1이상인 것으로 측정되는 결정구조를 갖는 산성 모오데나이트 제올라이트와 불활성 실리카 결합제를 포함함을 특징으로 하는 촉매 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900021123A 1989-12-22 1990-12-20 벤젠 또는 치환된 벤젠을 알킬화시키거나 알킬화 벤젠을 트랜스알킬화시키는 방법 KR100206050B1 (ko)

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US45567789A 1989-12-22 1989-12-22
US455677 1989-12-22

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EP (1) EP0433932B1 (ko)
JP (1) JPH06239771A (ko)
KR (1) KR100206050B1 (ko)
CN (1) CN1031989C (ko)
AT (1) ATE137483T1 (ko)
AU (1) AU651565B2 (ko)
CA (1) CA2033021C (ko)
DE (1) DE69026802T2 (ko)
ES (1) ES2085878T3 (ko)
FI (1) FI906369A (ko)
IL (1) IL96758A0 (ko)
NO (1) NO175249C (ko)
NZ (1) NZ236508A (ko)

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ES2121776T3 (es) * 1991-03-21 1998-12-16 Solutia Europ Nv Sa Procedimiento catalitico mejorado para la alquilacion selectiva de hidrocarburos aromaticos.
BR9107311A (pt) * 1991-06-21 1995-04-25 Dow Chemical Co Processo para alquilar benzeno ou benzeno substituído.
EP0528096B1 (en) * 1991-08-21 1998-05-27 Solutia Europe N.V./S.A. Catalytic process for the selective alkylation of polycyclic aromatic compounds
US5756873A (en) * 1992-08-05 1998-05-26 Exxon Chemical Patents Inc. Design for aromatics alkylation
CN1055876C (zh) * 1996-01-25 2000-08-30 中国石油化工总公司 用于制备烷基苯的烷基化催化剂
US5955642A (en) * 1996-10-30 1999-09-21 Fina Technology, Inc. Gas phase alkylation-liquid transalkylation process
FR2761905B1 (fr) * 1997-04-09 1999-05-14 Inst Francais Du Petrole Catalyseur a base de mordenite desaluminee contenant au moins un metal des groupes vi, vii et viii, et son utilisation en dismutation et/ou transalkylation d'hydrocarbures aromatiques
FR2761904B1 (fr) * 1997-04-09 1999-05-14 Inst Francais Du Petrole Catalyseur a base de mordenite desaluminee et son utilisation en dismutation et/ou transalkylation d'hydrocarbures aromatiques
CN100532506C (zh) * 2001-11-16 2009-08-26 弗纳技术股份有限公司 载于二氧化硅上的烷基化催化剂
US6964935B2 (en) 2004-03-12 2005-11-15 Chevron Oronite Company Llc. Mordenite zeolite alkylation catalysts
CN102909052B (zh) * 2011-08-01 2014-12-10 中国石油化工股份有限公司 含丝光沸石的催化剂及其制备方法和应用
BR102014002154A2 (pt) * 2014-01-28 2015-10-27 Whirlpool Sa processo de produção de composto alquilaromático, processo de transalquilação de polialquilaromáticos para produção seletiva de composto monoalquilaromático, e, processo de alquilação e transalquilação de compostos aromáticos e/ou poliaromáticos
CN108530246B (zh) * 2017-03-03 2021-03-30 中国石油化工股份有限公司 苯和丙烯生产正丙苯的方法
CN114426451A (zh) * 2020-09-24 2022-05-03 中国石油化工股份有限公司 一种多取代异丙苯烷基转移制备异丙苯的方法及其所得异丙苯

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DE2112223B2 (de) * 1970-03-16 1973-12-20 Universal Oil Products Co., Des Plaines, Ill. (V.St.A.) Verfahren zur Herstellung von synthetischem Mordenit und dessen Verwendung
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FR2638157B1 (fr) * 1988-10-26 1991-04-19 Inst Francais Du Petrole Procede de production d'alkylbenzenes utilisant un catalyseur a base de mordenite modifiee

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NO175249B (no) 1994-06-13
FI906369A0 (fi) 1990-12-21
CA2033021A1 (en) 1991-06-23
JPH06239771A (ja) 1994-08-30
FI906369A (fi) 1991-06-23
CN1052655A (zh) 1991-07-03
ATE137483T1 (de) 1996-05-15
AU651565B2 (en) 1994-07-28
NO905568D0 (no) 1990-12-21
NO905568L (no) 1991-06-24
AU6843790A (en) 1991-06-27
EP0433932A1 (en) 1991-06-26
CN1031989C (zh) 1996-06-12
DE69026802D1 (de) 1996-06-05
ES2085878T3 (es) 1996-06-16
NO175249C (no) 1994-09-21
CA2033021C (en) 2001-05-01
DE69026802T2 (de) 1996-11-21
KR100206050B1 (ko) 1999-07-01
IL96758A0 (en) 1991-09-16
EP0433932B1 (en) 1996-05-01
NZ236508A (en) 1992-05-26

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