FR2761905B1 - Catalyseur a base de mordenite desaluminee contenant au moins un metal des groupes vi, vii et viii, et son utilisation en dismutation et/ou transalkylation d'hydrocarbures aromatiques - Google Patents

Catalyseur a base de mordenite desaluminee contenant au moins un metal des groupes vi, vii et viii, et son utilisation en dismutation et/ou transalkylation d'hydrocarbures aromatiques

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Publication number
FR2761905B1
FR2761905B1 FR9704451A FR9704451A FR2761905B1 FR 2761905 B1 FR2761905 B1 FR 2761905B1 FR 9704451 A FR9704451 A FR 9704451A FR 9704451 A FR9704451 A FR 9704451A FR 2761905 B1 FR2761905 B1 FR 2761905B1
Authority
FR
France
Prior art keywords
mordenity
dismutation
dealuminated
transalkylation
viii
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR9704451A
Other languages
English (en)
Other versions
FR2761905A1 (fr
Inventor
Elisabeth Merlen
Fabio Alario
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR9704451A priority Critical patent/FR2761905B1/fr
Priority to US09/056,741 priority patent/US6486372B1/en
Priority to KR1019980012376A priority patent/KR100565922B1/ko
Publication of FR2761905A1 publication Critical patent/FR2761905A1/fr
Application granted granted Critical
Publication of FR2761905B1 publication Critical patent/FR2761905B1/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/123—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of only one hydrocarbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/126—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of more than one hydrocarbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/10—Magnesium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/16—Clays or other mineral silicates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/08—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of gallium, indium or thallium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of germanium, tin or lead
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/32—Manganese, technetium or rhenium
    • C07C2523/36—Rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/755—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/14—Phosphorus; Compounds thereof
    • C07C2527/16—Phosphorus; Compounds thereof containing oxygen
    • C07C2527/167—Phosphates or other compounds comprising the anion (PnO3n+1)(n+2)-
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • C07C2529/20—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing iron group metals, noble metals or copper
    • C07C2529/22—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • C07C2529/20—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing iron group metals, noble metals or copper
    • C07C2529/24—Iron group metals or copper
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
FR9704451A 1997-04-09 1997-04-09 Catalyseur a base de mordenite desaluminee contenant au moins un metal des groupes vi, vii et viii, et son utilisation en dismutation et/ou transalkylation d'hydrocarbures aromatiques Expired - Fee Related FR2761905B1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
FR9704451A FR2761905B1 (fr) 1997-04-09 1997-04-09 Catalyseur a base de mordenite desaluminee contenant au moins un metal des groupes vi, vii et viii, et son utilisation en dismutation et/ou transalkylation d'hydrocarbures aromatiques
US09/056,741 US6486372B1 (en) 1997-04-09 1998-04-08 Catalyst based on dealuminated mordenite containing at least one metal from groups VI, VII or VIII, and its use for dismutation and/or transalkylation of aromatic hydrocarbons
KR1019980012376A KR100565922B1 (ko) 1997-04-09 1998-04-08 1종이상의 6,7및8족 금속을 함유하는 탈알루미늄화된 모오데나이트를 주성분으로 하는 촉매,및 그 촉매를 사용하여 방향족탄화수소를 불균화 및/또는 알킬교환방법

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9704451A FR2761905B1 (fr) 1997-04-09 1997-04-09 Catalyseur a base de mordenite desaluminee contenant au moins un metal des groupes vi, vii et viii, et son utilisation en dismutation et/ou transalkylation d'hydrocarbures aromatiques

Publications (2)

Publication Number Publication Date
FR2761905A1 FR2761905A1 (fr) 1998-10-16
FR2761905B1 true FR2761905B1 (fr) 1999-05-14

Family

ID=9505782

Family Applications (1)

Application Number Title Priority Date Filing Date
FR9704451A Expired - Fee Related FR2761905B1 (fr) 1997-04-09 1997-04-09 Catalyseur a base de mordenite desaluminee contenant au moins un metal des groupes vi, vii et viii, et son utilisation en dismutation et/ou transalkylation d'hydrocarbures aromatiques

Country Status (3)

Country Link
US (1) US6486372B1 (fr)
KR (1) KR100565922B1 (fr)
FR (1) FR2761905B1 (fr)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6867340B2 (en) 1998-12-24 2005-03-15 Sk Corporation Disproportionation/transalkylation of aromatic hydrocarbons
DE10006122A1 (de) * 2000-02-11 2001-08-16 Basf Ag Oxidisches Material und Verfahren zu dessen Herstellung
US6504076B1 (en) * 2001-05-18 2003-01-07 Fina Technology, Inc. Method of conversion of heavy aromatics
US6972348B2 (en) 2004-03-24 2005-12-06 Uop Llc Catalytic conversion of polycyclic aromatics into xylenes
US7273828B1 (en) 2004-05-27 2007-09-25 Uop Llc Catalyst treatment useful for aromatics conversion process
US7220885B2 (en) * 2004-05-27 2007-05-22 Uop Llc Catalyst treatment useful for aromatics conversion process
US7154014B1 (en) * 2004-09-22 2006-12-26 Uop Llc Alumina guard bed for aromatics transalkylation process
US7381674B1 (en) * 2006-07-28 2008-06-03 Uop Llc Iridium and germanium-containing catalysis and alkylaromatic transalkylation processes using such catalysts
US7378365B2 (en) * 2006-07-28 2008-05-27 Uop Llc Synergistic rhenium and germanium-containing catalysts potentiated with tin and alkylaromatic transalkylation processes using such catalysts
US7605295B1 (en) 2008-06-26 2009-10-20 Uop Llc Integrated process yielding xylenes from mixed aromatics
US7626064B1 (en) 2008-06-26 2009-12-01 Uop Llc Transalkylation process
EP2174713A1 (fr) * 2008-10-13 2010-04-14 BP Chemicals Limited Procédé de désaluminisation
EP2189215A1 (fr) 2008-11-19 2010-05-26 BP Chemicals Limited Procédé de carbonylation catalysé au mordenite supporté sur oxydes inorganiques
EP2198963A1 (fr) 2008-12-10 2010-06-23 BP Chemicals Limited Catalyseur de carbonylation comprenant une zéolithe mordénite et un liant
KR101660491B1 (ko) * 2010-04-09 2016-09-27 삼성전자주식회사 반도체 장치 및 그 제조 방법

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US3849340A (en) * 1971-11-10 1974-11-19 Universal Oil Prod Co Hydrocarbon conversion catalyst
DE2745983A1 (de) * 1976-10-15 1978-04-20 Inst Francais Du Petrol Verfahren zur herstellung eines katalysators zur umwandlung von kohlenwasserstoffen
FR2529100B1 (fr) * 1982-06-23 1986-10-03 Inst Francais Du Petrole Nouveau catalyseur a base de mordenite fortement desaluminee
FR2586674B1 (fr) * 1985-08-28 1988-07-15 Inst Francais Du Petrole Procede de dismutation et transalkylation d'hydrocarbures aromatiques en presence d'un catalyseur zeolithique
US4665272A (en) * 1985-09-03 1987-05-12 Uop Inc. Catalytic composition for the isomerization of paraffinic hydrocarbons
FR2593084B1 (fr) * 1986-01-22 1990-09-28 Inst Francais Du Petrole Catalyseur contenant une mordenite, sa preparation et son application a l'isomerisation de coupes riches en paraffines normales.
FR2620724B1 (fr) * 1987-09-17 1994-04-15 Institut Francais Petrole Procede de production d'oligomeres d'olefines, utilisant un catalyseur a base de mordenite modifiee
FR2622473B1 (fr) * 1987-11-03 1993-07-02 Inst Francais Du Petrole Catalyseur d'isomerisation des paraffines normales comprenant une mordenite et du titane
JPH06239771A (ja) * 1989-12-22 1994-08-30 Dow Chem Co:The ベンゼンもしくは置換ベンゼンのアルキル化またはアルキル化ベンゼンのトランスアルキル化の方法および触媒組成物
FR2691914B1 (fr) * 1992-06-03 1995-03-10 Inst Francais Du Petrole Catalyseur à base de zéolithe mordénite modifiée et son utilisation en isomérisation d'une coupe C8 aromatique.
JP3770564B2 (ja) * 1995-07-31 2006-04-26 東燃ゼネラル石油株式会社 芳香族炭化水素変換用触媒及び該変換用触媒を用いた 芳香族炭化水素の変換方法
JP3820685B2 (ja) * 1996-06-28 2006-09-13 東レ株式会社 アルキル芳香族炭化水素のトランスアルキル化反応用触媒組成物及びキシレンの製造方法
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KR100747685B1 (ko) * 2001-03-14 2007-08-09 차이나 페트로-케미칼 코포레이션 톨루엔 및 중방향족의 불균화 및 트렌스알킬화를 위한 방법 및 촉매

Also Published As

Publication number Publication date
FR2761905A1 (fr) 1998-10-16
US6486372B1 (en) 2002-11-26
KR19980081187A (ko) 1998-11-25
KR100565922B1 (ko) 2006-06-13

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