GB1402304A - Process for stabilizing aqueous baths which contain organo- polysiloxane emulsions for the treatment of textile materials - Google Patents

Process for stabilizing aqueous baths which contain organo- polysiloxane emulsions for the treatment of textile materials

Info

Publication number
GB1402304A
GB1402304A GB3629372A GB3629372A GB1402304A GB 1402304 A GB1402304 A GB 1402304A GB 3629372 A GB3629372 A GB 3629372A GB 3629372 A GB3629372 A GB 3629372A GB 1402304 A GB1402304 A GB 1402304A
Authority
GB
United Kingdom
Prior art keywords
gpl
copolymer
cotton
emulsion
dmdheu
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3629372A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Publication of GB1402304A publication Critical patent/GB1402304A/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/6436Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04Polysiloxanes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/267Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof of unsaturated carboxylic esters having amino or quaternary ammonium groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/12Polysiloxanes containing silicon bound to hydrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/14Polysiloxanes containing silicon bound to oxygen-containing groups
    • C08G77/16Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/20Polysiloxanes containing silicon bound to unsaturated aliphatic groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/70Siloxanes defined by use of the MDTQ nomenclature

Abstract

1402304 Rendering fibrous materials hydrophobic FARBWERKE HOECHST AG 3 Aug 1972 [4 Aug 1971] 36293/72 Heading D1P [Also in Division C3] Fibrous materials are rendered hydrophobic by impregnating them with an aqueous emulsion of an organopolysiloxane stabilized by incorporating therein a copolymer of an unsaturated amide CH 2 = CR<SP>1</SP> . NR<SP>2</SP> . CO . R<SP>3</SP> and an unsaturated dicarboxylic ester R<SP>6</SP>OOC . CR<SP>4</SP> =CR<SP>5</SP> . COOR<SP>7</SP>, wherein R<SP>1</SP>, R<SP>4</SP> and R<SP>5</SP> are each H or SH 3 and R<SP>2</SP>, R<SP>3</SP>, R<SP>6</SP> and R<SP>7</SP> are each a C 1-4 alkyl radical, preferably in amount 0À1-5 gpl. In Examples baths are prepared containing (1) 60 gpl of a 33% emulsion of a methyl hydrogen polysiloxane containing 3% polyvinyl alcohol and 4% xylene, 120 gpl of 50% aqueous dimethylol dihydroxy ethyleneurea (DMDHEU), 6 gpl ZrCl 4 , 12 gpl Zn(NO 3 ) 2 (12%) and 0.5 gpl of a 9:1 copolymer of N-vinyl-N-methyl-acetamide and diethyl maleate, (2) 75 gpl of the silicone emulsion, 220 gpl of 50% UF resin, 8 gpl MgCl 2 , 4 gpl urea, 1 gpl acetic acid and 1 gpl of the copolymer and (3) 70 gpl of the silicone emulsion, 150 gpl of 50% DMDHEU, 10 gpl Zn(NO 3 ) 2 , 4 gpl urea, I gpl acetic acid and 0.75 gpl copolymer; they are used to impregnate a cotton poplin, a cotton pile fabric or a cotton/polyester anorak poplin.
GB3629372A 1971-08-04 1972-08-03 Process for stabilizing aqueous baths which contain organo- polysiloxane emulsions for the treatment of textile materials Expired GB1402304A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19712139026 DE2139026A1 (en) 1971-08-04 1971-08-04 METHOD AND MEANS FOR STABILIZING ORGANOPOLYSILOXANE EMULSIONS

Publications (1)

Publication Number Publication Date
GB1402304A true GB1402304A (en) 1975-08-06

Family

ID=5815766

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3629372A Expired GB1402304A (en) 1971-08-04 1972-08-03 Process for stabilizing aqueous baths which contain organo- polysiloxane emulsions for the treatment of textile materials

Country Status (7)

Country Link
BE (1) BE787250A (en)
CH (2) CH1147372A4 (en)
DE (1) DE2139026A1 (en)
FR (1) FR2148275B1 (en)
GB (1) GB1402304A (en)
IT (1) IT963675B (en)
NL (1) NL7210455A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1586694A3 (en) * 2004-04-16 2006-12-06 Kao Corporation Fiber treating composition

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3215936C2 (en) * 1982-04-29 1985-10-24 Chemische Fabrik Pfersee Gmbh, 8900 Augsburg Aqueous textile treatment liquor
JPS6094680A (en) * 1983-10-28 1985-05-27 東レ・ダウコーニング・シリコーン株式会社 Fiber treating agent

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1586694A3 (en) * 2004-04-16 2006-12-06 Kao Corporation Fiber treating composition

Also Published As

Publication number Publication date
FR2148275A1 (en) 1973-03-11
BE787250A (en) 1973-02-05
FR2148275B1 (en) 1976-08-13
CH553285A (en) 1974-08-30
IT963675B (en) 1974-01-21
CH1147372A4 (en) 1974-03-29
DE2139026A1 (en) 1973-02-15
NL7210455A (en) 1973-02-06

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees