GB1382667A - Process for the hydrogenation of aromatic hydrocarbons - Google Patents

Process for the hydrogenation of aromatic hydrocarbons

Info

Publication number
GB1382667A
GB1382667A GB1337472A GB1337472A GB1382667A GB 1382667 A GB1382667 A GB 1382667A GB 1337472 A GB1337472 A GB 1337472A GB 1337472 A GB1337472 A GB 1337472A GB 1382667 A GB1382667 A GB 1382667A
Authority
GB
United Kingdom
Prior art keywords
catalyst
fluorine
sulphide
aromatic hydrocarbons
atoms
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1337472A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Priority to GB1337472A priority Critical patent/GB1382667A/en
Priority to CA160,064A priority patent/CA987619A/en
Priority to BE1004885A priority patent/BE796666A/en
Priority to JP48031492A priority patent/JPS5742674B2/ja
Priority to FR7309851A priority patent/FR2176907B1/fr
Priority to ZA731946A priority patent/ZA731946B/en
Priority to AU53513/73A priority patent/AU476357B2/en
Priority to NL7303857A priority patent/NL7303857A/xx
Priority to DE2313905A priority patent/DE2313905C2/en
Priority to IT7321873A priority patent/IT981500B/en
Publication of GB1382667A publication Critical patent/GB1382667A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/44—Hydrogenation of the aromatic hydrocarbons
    • C10G45/46—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used
    • C10G45/48—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/50—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum or tungsten metal, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B01J27/047—Sulfides with chromium, molybdenum, tungsten or polonium
    • B01J27/049—Sulfides with chromium, molybdenum, tungsten or polonium with iron group metals or platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/22—Halogenating
    • B01J37/26—Fluorinating
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/10—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of aromatic six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/04—Sulfides
    • C07C2527/047—Sulfides with chromium, molybdenum, tungsten or polonium
    • C07C2527/049—Sulfides with chromium, molybdenum, tungsten or polonium with iron group metals or platinum group metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring

Abstract

1382667 Hydrogenating aromatic hydrocarbons SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ NV 22 March 1972 13374/72 Heading C5E Aromatic hydrocarbons are hydrogenated over a supported catalyst comprising (a) nickel sulphide and/or cobalt sulphide, (b) molybdenum sulphide and/or tungsten sulphide and (c) fluorine. Substantially all the fluorine is incorporated by in situ fluoriding i.e. addition of fluorine compound (e.g. orthofluorotoluene and difluoromethane) to the gas and/or liquid stream passing over the catalyst. Nitrogen may be incorporated into the catalyst by addition to the stream of a nitrogen compound (many listed). A small amount of fluorine compound may be continuously added to the feed after the catalyst has reached its required fluorine content. The catalyst may comprise 0À025 to 0À5 g. atoms of Ni and/or Co and from 0À02 to 0À3 g. atoms of Mo and/or W per 100 g. carrier (e.g. SiO 2 , Al 2 O 3 , MgO, B 2 O 3 , Th 2 O 3 ). Crude benzene and petroleum distillates (final b.p.=375‹ C.) may be hydrogenated, the latter after hydrogenation being suitable for use as aromaticsfree solvents, illuminating oils, jet fuels and diesel fuels.
GB1337472A 1972-03-22 1972-03-22 Process for the hydrogenation of aromatic hydrocarbons Expired GB1382667A (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
GB1337472A GB1382667A (en) 1972-03-22 1972-03-22 Process for the hydrogenation of aromatic hydrocarbons
CA160,064A CA987619A (en) 1972-03-22 1972-12-28 Process for the hydrogenation of aromatic hydrocarbons
BE1004885A BE796666A (en) 1972-03-22 1973-03-13 PROCESS FOR HYDROGENING HYDROGEN AROMATIC CARBONS
JP48031492A JPS5742674B2 (en) 1972-03-22 1973-03-20
FR7309851A FR2176907B1 (en) 1972-03-22 1973-03-20
ZA731946A ZA731946B (en) 1972-03-22 1973-03-20 Process for the hydrogenation of aromatic hydrocarbons
AU53513/73A AU476357B2 (en) 1972-03-22 1973-03-20 Process forthe hydrogenation of aromatic hydrocarbons
NL7303857A NL7303857A (en) 1972-03-22 1973-03-20
DE2313905A DE2313905C2 (en) 1972-03-22 1973-03-20 Process for the hydrogenation of aromatic hydrocarbons
IT7321873A IT981500B (en) 1972-03-22 1973-03-20 PROCESS FOR THE HYDROGENATION OF AROMATIC HYDROCARBONS

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1337472A GB1382667A (en) 1972-03-22 1972-03-22 Process for the hydrogenation of aromatic hydrocarbons

Publications (1)

Publication Number Publication Date
GB1382667A true GB1382667A (en) 1975-02-05

Family

ID=10021813

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1337472A Expired GB1382667A (en) 1972-03-22 1972-03-22 Process for the hydrogenation of aromatic hydrocarbons

Country Status (9)

Country Link
JP (1) JPS5742674B2 (en)
BE (1) BE796666A (en)
CA (1) CA987619A (en)
DE (1) DE2313905C2 (en)
FR (1) FR2176907B1 (en)
GB (1) GB1382667A (en)
IT (1) IT981500B (en)
NL (1) NL7303857A (en)
ZA (1) ZA731946B (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL172756C (en) * 1972-11-09 1983-10-17 Shell Int Research PROCESS FOR PREPARING A TECHNICAL WHITE OIL.
US4181601A (en) * 1977-06-17 1980-01-01 The Lummus Company Feed hydrotreating for improved thermal cracking
US5290429A (en) * 1990-05-25 1994-03-01 Union Oil Company Of California Catalytic aromatic saturation in the presence of halide
JP2011083701A (en) * 2009-10-15 2011-04-28 Jx Nippon Oil & Energy Corp Hydrogenation catalyst exhibiting excellent anti-poison property to impurity in hydrogen source and method for producing the catalyst

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB747663A (en) * 1952-11-27 1956-04-11 British Petroleum Co Improvements relating to catalysts
GB750430A (en) * 1953-07-21 1956-06-13 British Petroleum Co Improvements relating to the catalytic desulphurisation of hydrocarbons
US2760907A (en) * 1953-09-01 1956-08-28 Union Oil Co Hydrocarbon conversion process and catalyst
US3078238A (en) * 1959-07-24 1963-02-19 Gulf Research Development Co Hydrogenation catalyst and method of preparation
NL6501529A (en) * 1965-02-08 1966-08-09
US3461181A (en) * 1966-01-27 1969-08-12 Toray Industries Process for hydrogenation

Also Published As

Publication number Publication date
AU5351373A (en) 1974-09-26
JPS5742674B2 (en) 1982-09-09
NL7303857A (en) 1973-09-25
BE796666A (en) 1973-09-13
DE2313905C2 (en) 1983-09-15
CA987619A (en) 1976-04-20
JPS497307A (en) 1974-01-23
IT981500B (en) 1974-10-10
FR2176907A1 (en) 1973-11-02
ZA731946B (en) 1974-01-30
DE2313905A1 (en) 1973-10-31
FR2176907B1 (en) 1976-04-09

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee