GB1350883A - Bis-stilbene compounds - Google Patents

Bis-stilbene compounds

Info

Publication number
GB1350883A
GB1350883A GB1005572A GB1005572A GB1350883A GB 1350883 A GB1350883 A GB 1350883A GB 1005572 A GB1005572 A GB 1005572A GB 1005572 A GB1005572 A GB 1005572A GB 1350883 A GB1350883 A GB 1350883A
Authority
GB
United Kingdom
Prior art keywords
carbon atoms
alkyl
formulμ
groups
alkenyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1005572A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
Ciba Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CH323571A external-priority patent/CH556888A/en
Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG
Publication of GB1350883A publication Critical patent/GB1350883A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/70—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form
    • C07C45/71—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form being hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/52—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings
    • C07C47/56—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings containing hydroxy groups
    • C07C47/565—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings containing hydroxy groups all hydroxy groups bound to the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/52—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings
    • C07C47/575—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings containing ether groups, groups, groups, or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C59/40—Unsaturated compounds
    • C07C59/58—Unsaturated compounds containing ether groups, groups, groups, or groups
    • C07C59/64—Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings
    • C07C59/66—Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings the non-carboxylic part of the ether containing six-membered aromatic rings
    • C07C59/68—Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings the non-carboxylic part of the ether containing six-membered aromatic rings the oxygen atom of the ether group being bound to a non-condensed six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C59/40—Unsaturated compounds
    • C07C59/58—Unsaturated compounds containing ether groups, groups, groups, or groups
    • C07C59/64—Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings
    • C07C59/66—Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings the non-carboxylic part of the ether containing six-membered aromatic rings
    • C07C59/68—Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings the non-carboxylic part of the ether containing six-membered aromatic rings the oxygen atom of the ether group being bound to a non-condensed six-membered aromatic ring
    • C07C59/70—Ethers of hydroxy-acetic acid, e.g. substitutes on the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C59/40—Unsaturated compounds
    • C07C59/74—Unsaturated compounds containing —CHO groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0041—Optical brightening agents, organic pigments
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/60—Optical bleaching or brightening
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/60—Optical bleaching or brightening
    • D06L4/65—Optical bleaching or brightening with mixtures of optical brighteners
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/913—Material designed to be responsive to temperature, light, moisture

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Detergent Compositions (AREA)

Abstract

1350883 Bis-stilbenes CIBA-GEIGY AG 3 March 1972 [5 March 1971 3 Feb 1972] 10055/72 Addition to 1247934 Heading C2C [Also in Divisions C3 C5 and D1] Novel compounds of Formula I wherein R 1 and R 2 are identical or different and denote alkyl with 5 to 18 carbon atoms, substituted alkyl with a total of 2 to 20 carbon atoms, or alkenyl with 3 or 4 carbon atoms, X 1 and X 2 are identical or different and denote hydrogen, alkoxy with 1 to 4 carbon atoms, halogen, alkenyl with 3 or 4 carbon atoms or alkyl with 1 to 4 carbon atoms, Y 1 and Y 2 are identical or different and denote hydrogen, halogen, alkenyl with 3 or 4 carbon atoms or alkyl with 1 to 4 carbon atoms, a represents hydrogen, halogen, alkoxy with 1 to 4 carbon atoms or alkyl with 1 to 4 carbon atoms, with the proviso that the para-positions are free of alkoxy groups or R 1 O- and R 2 O- groups, are prepared by reacting about one mol. equivalent of a compound of Formula II with about one mol. equivalent of each of the compounds of Formulµ III and IV in which formulµ X 1 , X 2 , Y 1 , Y 2 are as defined above, R 1 <SP>1</SP>, and R 2 <SP>1</SP> are as defined under R 1 and R 2 above with the exception of alkyl groups containing modified carboxyl groups, and one of the symbols Z 1 and Z 2 denotes a -CHO group and the other denotes one of the group of the formulµ wherein R represents an optionally substituted alkyl radical, aryl radical, cycloalkyl radical or aralkyl radical, and subsequently esterifying or amidating the carboxyl groups in known manner. Aldehyde ethers of Formulµ III and IV in which Z 2 is CHO, are prepared by etherification of the corresponding hydroxy benzaldehydes.
GB1005572A 1971-03-05 1972-03-03 Bis-stilbene compounds Expired GB1350883A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH323571A CH556888A (en) 1971-03-05 1971-03-05 Bis-stilbene cpds - used as optical brightening agents
CH160872 1972-02-03

Publications (1)

Publication Number Publication Date
GB1350883A true GB1350883A (en) 1974-04-24

Family

ID=25688144

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1005572A Expired GB1350883A (en) 1971-03-05 1972-03-03 Bis-stilbene compounds

Country Status (11)

Country Link
US (1) US3843718A (en)
JP (1) JPS5638625B1 (en)
BE (1) BE780173A (en)
CA (1) CA994357A (en)
DD (1) DD99627A5 (en)
DE (1) DE2209128C3 (en)
ES (1) ES400439A1 (en)
FR (1) FR2128543B1 (en)
GB (1) GB1350883A (en)
IT (1) IT952084B (en)
NL (1) NL7202870A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4410537A (en) 1979-06-29 1983-10-18 Burroughts Wellcome Co. Pharmaceutical ethers

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH554848A (en) * 1967-10-03 1974-10-15 Ciba Geigy Ag PROCESS FOR PRODUCING NEW STILBENE DERIVATIVES.
US4371475A (en) * 1977-05-04 1983-02-01 Showa Kagaku Kogyo Company, Ltd. 1,4-Bis-styryl-benzene derivatives and a process for the preparation of the same
DE2722151A1 (en) * 1977-05-16 1978-11-23 Max Planck Gesellschaft FOAMED PLASTIC BODY AND ITS USE
US4231957A (en) * 1977-11-04 1980-11-04 Ciba-Geigy Corporation Phosphonium compounds, a process for their preparation and a process for the preparation of asymmetrically substituted stilbene fluorescent brightening agents
US4314820A (en) * 1979-04-11 1982-02-09 Ciba-Geigy Corporation Distyrylbenzene fluorescent brightening agents
US4339393A (en) * 1979-04-11 1982-07-13 Ciba-Geigy Corporation Distyrylbiphenyls
CN101681106B (en) * 2007-05-25 2013-11-20 爱克发印艺公司 A lithographic printing plate precursor

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH500145A (en) * 1967-07-14 1970-12-15 Ciba Geigy Ag Process for the preparation of aromatic compounds containing ethylene double bonds
CH505036A (en) * 1968-12-23 1971-03-31 Ciba Geigy Ag Bis-stilbene derivs useful as optical - bleaches

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4410537A (en) 1979-06-29 1983-10-18 Burroughts Wellcome Co. Pharmaceutical ethers

Also Published As

Publication number Publication date
FR2128543B1 (en) 1974-04-05
JPS5638625B1 (en) 1981-09-08
FR2128543A1 (en) 1972-10-20
CA994357A (en) 1976-08-03
DE2209128B2 (en) 1981-01-08
BE780173A (en) 1972-09-04
DE2209128A1 (en) 1972-09-14
IT952084B (en) 1973-07-20
DE2209128C3 (en) 1981-10-22
US3843718A (en) 1974-10-22
DD99627A5 (en) 1973-08-12
NL7202870A (en) 1972-09-07
ES400439A1 (en) 1975-06-16

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PE20 Patent expired after termination of 20 years