ES400439A1 - 1,4-bis-styryl-benzene-dioxyalkanoic acids,salts and esters - Google Patents

1,4-bis-styryl-benzene-dioxyalkanoic acids,salts and esters

Info

Publication number
ES400439A1
ES400439A1 ES400439A ES400439A ES400439A1 ES 400439 A1 ES400439 A1 ES 400439A1 ES 400439 A ES400439 A ES 400439A ES 400439 A ES400439 A ES 400439A ES 400439 A1 ES400439 A1 ES 400439A1
Authority
ES
Spain
Prior art keywords
carbon atoms
alkyl
formula
see formula
groups
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES400439A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
Ciba Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CH323571A external-priority patent/CH556888A/en
Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG
Publication of ES400439A1 publication Critical patent/ES400439A1/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/70—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form
    • C07C45/71—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form being hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/52—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings
    • C07C47/56—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings containing hydroxy groups
    • C07C47/565—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings containing hydroxy groups all hydroxy groups bound to the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/52—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings
    • C07C47/575—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings containing ether groups, groups, groups, or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C59/40—Unsaturated compounds
    • C07C59/58—Unsaturated compounds containing ether groups, groups, groups, or groups
    • C07C59/64—Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings
    • C07C59/66—Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings the non-carboxylic part of the ether containing six-membered aromatic rings
    • C07C59/68—Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings the non-carboxylic part of the ether containing six-membered aromatic rings the oxygen atom of the ether group being bound to a non-condensed six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C59/40—Unsaturated compounds
    • C07C59/58—Unsaturated compounds containing ether groups, groups, groups, or groups
    • C07C59/64—Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings
    • C07C59/66—Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings the non-carboxylic part of the ether containing six-membered aromatic rings
    • C07C59/68—Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings the non-carboxylic part of the ether containing six-membered aromatic rings the oxygen atom of the ether group being bound to a non-condensed six-membered aromatic ring
    • C07C59/70—Ethers of hydroxy-acetic acid, e.g. substitutes on the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C59/40—Unsaturated compounds
    • C07C59/74—Unsaturated compounds containing —CHO groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0041—Optical brightening agents, organic pigments
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/60—Optical bleaching or brightening
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/60—Optical bleaching or brightening
    • D06L4/65—Optical bleaching or brightening with mixtures of optical brighteners
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/913—Material designed to be responsive to temperature, light, moisture

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Detergent Compositions (AREA)

Abstract

Procedure for the preparation of new bis-stilbene compounds of the formula **(See formula)** in which R1 and R2 are the same or different and signify alkyl with 5 to 18 carbon atoms, substituted alkyl having a total of 2 to 20 carbon atoms or alkenyl with 3 to 4 carbon atoms; X1 and X2 are the same or different and signify hydrogen, alkoxy with 1 to 4 carbon atoms, halogen, alkenyl with 3 to 4 carbon atoms or alkyl with 1 to 4 carbon atoms; Y1 and Y2 are the same or different and signify hydrogen, halogen, alkenyl with 3 to 4 carbon atoms or alkyl with 1 to 4 carbon atoms; a represents hydrogen, halogen, alkoxy with 1 to 4 carbon atoms or alkyl with 1 to 4 carbon atoms; and the para positions are free of alkoxylic groups or respectively R1O- and R2O- groups, characterized by reacting around 1 molar equivalent of a compound of the formula **(See formula)** with approximately 1 molar equivalent of a compound of the formula **(See formula)** and about 1 molar equivalent of a compound of the formula **(See formula)** (In these formulas, X1, X2, Y1, Y2 and a have the same meaning as before; R'1 and R'2 have the meaning of R1 and respectively of R2, with the exception of alkyl groups containing modified carboxylic groups; and one of the symbols Z1 and Z2 means one group -CHO-, while the other means one of the groupings of the formulas **(See formula)** where R denotes an alkyl, aryl, cycloalkyl or aralkyl radical (with possible subsequent substitution), and by subsequently esterifying or amidating the carboxylic groups, in a known manner. (Machine-translation by Google Translate, not legally binding)
ES400439A 1971-03-05 1972-03-04 1,4-bis-styryl-benzene-dioxyalkanoic acids,salts and esters Expired ES400439A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH323571A CH556888A (en) 1971-03-05 1971-03-05 Bis-stilbene cpds - used as optical brightening agents
CH160872 1972-02-03

Publications (1)

Publication Number Publication Date
ES400439A1 true ES400439A1 (en) 1975-06-16

Family

ID=25688144

Family Applications (1)

Application Number Title Priority Date Filing Date
ES400439A Expired ES400439A1 (en) 1971-03-05 1972-03-04 1,4-bis-styryl-benzene-dioxyalkanoic acids,salts and esters

Country Status (11)

Country Link
US (1) US3843718A (en)
JP (1) JPS5638625B1 (en)
BE (1) BE780173A (en)
CA (1) CA994357A (en)
DD (1) DD99627A5 (en)
DE (1) DE2209128C3 (en)
ES (1) ES400439A1 (en)
FR (1) FR2128543B1 (en)
GB (1) GB1350883A (en)
IT (1) IT952084B (en)
NL (1) NL7202870A (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH554848A (en) * 1967-10-03 1974-10-15 Ciba Geigy Ag PROCESS FOR PRODUCING NEW STILBENE DERIVATIVES.
US4371475A (en) * 1977-05-04 1983-02-01 Showa Kagaku Kogyo Company, Ltd. 1,4-Bis-styryl-benzene derivatives and a process for the preparation of the same
DE2722151A1 (en) * 1977-05-16 1978-11-23 Max Planck Gesellschaft FOAMED PLASTIC BODY AND ITS USE
US4231957A (en) * 1977-11-04 1980-11-04 Ciba-Geigy Corporation Phosphonium compounds, a process for their preparation and a process for the preparation of asymmetrically substituted stilbene fluorescent brightening agents
US4339393A (en) * 1979-04-11 1982-07-13 Ciba-Geigy Corporation Distyrylbiphenyls
US4314820A (en) * 1979-04-11 1982-02-09 Ciba-Geigy Corporation Distyrylbenzene fluorescent brightening agents
ZA803880B (en) 1979-06-29 1982-02-24 Wellcome Found Pharmaceutical ethers,preparation,use and intermediates therefor and their preparation
ATE493688T1 (en) * 2007-05-25 2011-01-15 Agfa Graphics Nv FLAT PLATE PRECURSOR

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH500145A (en) * 1967-07-14 1970-12-15 Ciba Geigy Ag Process for the preparation of aromatic compounds containing ethylene double bonds
CH505036A (en) * 1968-12-23 1971-03-31 Ciba Geigy Ag Bis-stilbene derivs useful as optical - bleaches

Also Published As

Publication number Publication date
GB1350883A (en) 1974-04-24
FR2128543B1 (en) 1974-04-05
CA994357A (en) 1976-08-03
DD99627A5 (en) 1973-08-12
DE2209128B2 (en) 1981-01-08
JPS5638625B1 (en) 1981-09-08
FR2128543A1 (en) 1972-10-20
DE2209128A1 (en) 1972-09-14
NL7202870A (en) 1972-09-07
US3843718A (en) 1974-10-22
DE2209128C3 (en) 1981-10-22
IT952084B (en) 1973-07-20
BE780173A (en) 1972-09-04

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