GB1299076A - Catalyst - Google Patents

Catalyst

Info

Publication number
GB1299076A
GB1299076A GB08387/69A GB1838769A GB1299076A GB 1299076 A GB1299076 A GB 1299076A GB 08387/69 A GB08387/69 A GB 08387/69A GB 1838769 A GB1838769 A GB 1838769A GB 1299076 A GB1299076 A GB 1299076A
Authority
GB
United Kingdom
Prior art keywords
hydrogen
sulphur
hydrocarbon
thiophene
hydrocarbons
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB08387/69A
Inventor
John Joseph Phillipson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB08387/69A priority Critical patent/GB1299076A/en
Priority to BE748405D priority patent/BE748405A/xx
Priority to ZA702221A priority patent/ZA702221B/en
Priority to FR7012901A priority patent/FR2041159A1/fr
Priority to DE19702017329 priority patent/DE2017329A1/en
Priority to ZM34/70A priority patent/ZM3470A1/en
Publication of GB1299076A publication Critical patent/GB1299076A/en
Priority to US00347726A priority patent/US3846286A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

1299076 Hydrodesulphurizing hydrocarbons IMPERIAL CHEMICAL INDUSTRIES Ltd 16 March 1970 [10 April 1969] 18387/69 Heading C5E [Also in Division B1] A hydrocarbon feedstock containing sulphur derivatives of hydrocarbons is desulphurized by passing it together with hydrogen at 300- 450‹ C. over a catalyst formed by reducing and/or sulphiding a precursor composition comprising alumina, a Group VI metal oxide and a non-noble Group VIII metal oxide compressed together in cylindrical shapes having a density of under 1À2 g./c.c. and a mean vertical crushing strength of at least 280 p.s.i. (see Division B1). Specified feedstocks are naphthas of boiling range 30-220‹ C., heavy naphthas, kerosines and gas oils. The catalyst is also said to be suitable for the selective hydrogenation of acetylenes in olefines. In the examples: (i) vaporized n-heptane containing 100 p.p.m. w/v. sulphur as thiophene is treated together with hydrogen at a hydrogen to hydrocarbon mole ratio of 0À25, a liquid heptane space velocity of 0À75 hr.<SP>-1</SP> at 390‹ C. and atmospheric pressure; and (ii) a naphtha of boiling range 30-170‹ C. containing 100-110 p.p.m. w/v. sulphur as thiophene is treated at a H 2 /hydrocarbon ratio of 0À25, a liquid space velocity of 1 hr.<SP>-1</SP>, 370‹ C. and 450 p.s.i.g.
GB08387/69A 1969-04-10 1969-04-10 Catalyst Expired GB1299076A (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
GB08387/69A GB1299076A (en) 1969-04-10 1969-04-10 Catalyst
BE748405D BE748405A (en) 1969-04-10 1970-04-02
ZA702221A ZA702221B (en) 1969-04-10 1970-04-03 Catalyst
FR7012901A FR2041159A1 (en) 1969-04-10 1970-04-09
DE19702017329 DE2017329A1 (en) 1969-04-10 1970-04-10 Catalyst precursors, processes for their preparation and their use
ZM34/70A ZM3470A1 (en) 1969-04-10 1971-03-25 Catalyst
US00347726A US3846286A (en) 1969-04-10 1973-04-04 Hydrodesulfurization catalyst

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB08387/69A GB1299076A (en) 1969-04-10 1969-04-10 Catalyst

Publications (1)

Publication Number Publication Date
GB1299076A true GB1299076A (en) 1972-12-06

Family

ID=10111586

Family Applications (1)

Application Number Title Priority Date Filing Date
GB08387/69A Expired GB1299076A (en) 1969-04-10 1969-04-10 Catalyst

Country Status (6)

Country Link
BE (1) BE748405A (en)
DE (1) DE2017329A1 (en)
FR (1) FR2041159A1 (en)
GB (1) GB1299076A (en)
ZA (1) ZA702221B (en)
ZM (1) ZM3470A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2511202A1 (en) * 1974-03-25 1975-10-09 British Petroleum Co CATALYSTS FOR THE HYDRATING DESULFURIZATION OF HYDROCARBONS

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2511202A1 (en) * 1974-03-25 1975-10-09 British Petroleum Co CATALYSTS FOR THE HYDRATING DESULFURIZATION OF HYDROCARBONS

Also Published As

Publication number Publication date
ZA702221B (en) 1971-11-24
DE2017329A1 (en) 1970-10-08
FR2041159A1 (en) 1971-01-29
ZM3470A1 (en) 1971-11-22
BE748405A (en) 1970-10-02

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees