GB1188777A - Process for the Manufacture of Carboxylic Acids and Unsaturated Esters of Carboxylic Acids - Google Patents
Process for the Manufacture of Carboxylic Acids and Unsaturated Esters of Carboxylic AcidsInfo
- Publication number
- GB1188777A GB1188777A GB1816068A GB1816068A GB1188777A GB 1188777 A GB1188777 A GB 1188777A GB 1816068 A GB1816068 A GB 1816068A GB 1816068 A GB1816068 A GB 1816068A GB 1188777 A GB1188777 A GB 1188777A
- Authority
- GB
- United Kingdom
- Prior art keywords
- carboxylic acids
- april
- manufacture
- palladium
- aldehyde
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001735 carboxylic acids Chemical class 0.000 title abstract 3
- 150000002148 esters Chemical class 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 3
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 abstract 2
- -1 PdO Chemical class 0.000 abstract 2
- 150000001299 aldehydes Chemical class 0.000 abstract 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 150000002941 palladium compounds Chemical class 0.000 abstract 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 abstract 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052737 gold Inorganic materials 0.000 abstract 1
- 239000010931 gold Substances 0.000 abstract 1
- 230000007062 hydrolysis Effects 0.000 abstract 1
- 238000006460 hydrolysis reaction Methods 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/007—Esters of unsaturated alcohols having the esterified hydroxy group bound to an acyclic carbon atom
- C07C69/01—Vinyl esters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/52—Gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/58—Platinum group metals with alkali- or alkaline earth metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B35/00—Reactions without formation or introduction of functional groups containing hetero atoms, involving a change in the type of bonding between two carbon atoms already directly linked
- C07B35/04—Dehydrogenation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEK62042A DE1286021B (de) | 1967-04-18 | 1967-04-18 | Verfahren zur Herstellung von Estern von Carbonsaeuren mit ungesaettigten Alkoholen |
| DE1967K0062126 DE1301306C2 (de) | 1967-04-18 | 1967-04-26 | Verfahren zur herstellung von carbonsaeurevinylestern |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1188777A true GB1188777A (en) | 1970-04-22 |
Family
ID=25984369
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1816068A Expired GB1188777A (en) | 1967-04-18 | 1968-04-17 | Process for the Manufacture of Carboxylic Acids and Unsaturated Esters of Carboxylic Acids |
Country Status (10)
| Country | Link |
|---|---|
| JP (1) | JPS5034532B1 (enrdf_load_stackoverflow) |
| AT (1) | AT280980B (enrdf_load_stackoverflow) |
| BE (1) | BE713883A (enrdf_load_stackoverflow) |
| CH (1) | CH511790A (enrdf_load_stackoverflow) |
| DE (2) | DE1286021B (enrdf_load_stackoverflow) |
| ES (1) | ES352804A1 (enrdf_load_stackoverflow) |
| FR (1) | FR1560863A (enrdf_load_stackoverflow) |
| GB (1) | GB1188777A (enrdf_load_stackoverflow) |
| NL (1) | NL6805406A (enrdf_load_stackoverflow) |
| SE (1) | SE355351B (enrdf_load_stackoverflow) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5336802A (en) * | 1991-12-05 | 1994-08-09 | Quantum Chemical Corporation | Pretreatment of palladium-gold catalysts useful in vinyl acetate synthesis |
| WO1999062632A1 (en) * | 1998-06-02 | 1999-12-09 | Celanese International Corporation | Vinyl acetate catalyst comprising metallic palladium and gold prepared with potassium aurate |
| WO1999062633A1 (en) * | 1998-06-02 | 1999-12-09 | Celanese International Corporation | Vinyl acetate catalyst prepared with potassium aurate and comprising metallic palladium and gold on a carrier precoated with copper |
| WO1999062634A1 (en) * | 1998-06-02 | 1999-12-09 | Celanese International Corporation | Vinyl acetate catalyst comprising metallic palladium, copper and gold and preparation thereof |
| US9334226B2 (en) | 2012-09-19 | 2016-05-10 | Clariant International Ltd. | Copper-promoted shell catalyst for producing alkenyl carboxylic acid esters |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5249198A (en) * | 1975-10-16 | 1977-04-19 | Kawaguchi Shiko Kikai Kk | Binding method |
| US5612889A (en) | 1994-10-04 | 1997-03-18 | Pitney Bowes Inc. | Mail processing system with unique mailpiece authorization assigned in advance of mailpieces entering carrier service mail processing stream |
| DE102007025358A1 (de) * | 2007-05-31 | 2009-01-08 | Süd-Chemie AG | Verfahren zur Herstellung eines mit Pd und/oder Au beladenen Schalenkatalysators |
| DE102007025223A1 (de) | 2007-05-31 | 2008-12-04 | Süd-Chemie AG | Zirkoniumoxid-dotierter VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
| DE102007025443A1 (de) | 2007-05-31 | 2008-12-04 | Süd-Chemie AG | Pd/Au-Schalenkatalysator enthaltend HfO2, Verfahren zu dessen Herstellung sowie dessen Verwendung |
| DE102007025224A1 (de) * | 2007-05-31 | 2008-12-11 | Süd-Chemie AG | Verfahren zur Herstellung eines Schalenkatalysators |
| DE102007025362A1 (de) | 2007-05-31 | 2008-12-11 | Süd-Chemie AG | Dotierter Pd/Au-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
| DE102007025442B4 (de) | 2007-05-31 | 2023-03-02 | Clariant International Ltd. | Verwendung einer Vorrichtung zur Herstellung eines Schalenkatalysators und Schalenkatalysator |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL276196A (enrdf_load_stackoverflow) * | 1961-03-25 | 1900-01-01 | ||
| FR1422241A (fr) * | 1964-11-09 | 1965-12-24 | Rhone Poulenc Sa | Procédé de préparation d'acétate de vinyle |
-
1967
- 1967-04-18 DE DEK62042A patent/DE1286021B/de active Pending
- 1967-04-26 DE DE1967K0062126 patent/DE1301306C2/de not_active Expired
-
1968
- 1968-04-11 CH CH543768A patent/CH511790A/de not_active IP Right Cessation
- 1968-04-16 SE SE504968A patent/SE355351B/xx unknown
- 1968-04-16 ES ES352804A patent/ES352804A1/es not_active Expired
- 1968-04-17 AT AT373668A patent/AT280980B/de active
- 1968-04-17 GB GB1816068A patent/GB1188777A/en not_active Expired
- 1968-04-17 NL NL6805406A patent/NL6805406A/xx unknown
- 1968-04-18 BE BE713883D patent/BE713883A/xx unknown
- 1968-04-18 JP JP2610568A patent/JPS5034532B1/ja active Pending
- 1968-04-18 FR FR1560863D patent/FR1560863A/fr not_active Expired
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5336802A (en) * | 1991-12-05 | 1994-08-09 | Quantum Chemical Corporation | Pretreatment of palladium-gold catalysts useful in vinyl acetate synthesis |
| WO1999062632A1 (en) * | 1998-06-02 | 1999-12-09 | Celanese International Corporation | Vinyl acetate catalyst comprising metallic palladium and gold prepared with potassium aurate |
| WO1999062633A1 (en) * | 1998-06-02 | 1999-12-09 | Celanese International Corporation | Vinyl acetate catalyst prepared with potassium aurate and comprising metallic palladium and gold on a carrier precoated with copper |
| WO1999062634A1 (en) * | 1998-06-02 | 1999-12-09 | Celanese International Corporation | Vinyl acetate catalyst comprising metallic palladium, copper and gold and preparation thereof |
| US6015769A (en) * | 1998-06-02 | 2000-01-18 | Celanese International Corporation | Vinyl acetate catalyst comprising metallic palladium, gold and copper supported on a carrier and prepared with potassium aurate |
| US6017847A (en) * | 1998-06-02 | 2000-01-25 | Celanese International Corporation | Vinyl acetate catalyst prepared with potassium aurate and comprising metallic palladium and gold on a carrier precoated with copper |
| US6350900B1 (en) | 1998-06-02 | 2002-02-26 | Celanese International Corporation | Vinyl acetate catalyst comprising metallic palladium and gold prepared with potassium aurate |
| JP2002516747A (ja) * | 1998-06-02 | 2002-06-11 | セラニーズ・インターナショナル・コーポレーション | 金属パラジウム及び金を含んでなる金酸カリウムで調製された酢酸ビニル触媒 |
| AU753815B2 (en) * | 1998-06-02 | 2002-10-31 | Celanese International Corporation | Vinyl acetate catalyst comprising metallic palladium and gold prepared with potassium aurate |
| RU2216401C2 (ru) * | 1998-06-02 | 2003-11-20 | Селаниз Интернэшнл Корпорейшн | Способ получения катализатора (варианты) и способ получения винилацетата с использованием полученного катализатора (варианты) |
| KR100589992B1 (ko) * | 1998-06-02 | 2006-06-15 | 셀라니즈 인터내셔날 코포레이션 | 금속 팔라듐, 구리 및 금을 포함하는 비닐 아세테이트촉매 및 이의 제조방법 |
| US9334226B2 (en) | 2012-09-19 | 2016-05-10 | Clariant International Ltd. | Copper-promoted shell catalyst for producing alkenyl carboxylic acid esters |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1301306B (de) | 1969-08-21 |
| BE713883A (enrdf_load_stackoverflow) | 1968-10-18 |
| SE355351B (enrdf_load_stackoverflow) | 1973-04-16 |
| JPS5034532B1 (enrdf_load_stackoverflow) | 1975-11-10 |
| DE1301306C2 (de) | 1976-10-28 |
| CH511790A (de) | 1971-08-31 |
| FR1560863A (enrdf_load_stackoverflow) | 1969-03-21 |
| NL6805406A (enrdf_load_stackoverflow) | 1968-10-21 |
| ES352804A1 (es) | 1969-10-01 |
| DE1286021B (de) | 1969-01-02 |
| AT280980B (de) | 1970-05-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |