GB1154517A - Preparation of Vinyl Acetate from Acetic Acid and Ethylene - Google Patents

Preparation of Vinyl Acetate from Acetic Acid and Ethylene

Info

Publication number
GB1154517A
GB1154517A GB2823967A GB2823967A GB1154517A GB 1154517 A GB1154517 A GB 1154517A GB 2823967 A GB2823967 A GB 2823967A GB 2823967 A GB2823967 A GB 2823967A GB 1154517 A GB1154517 A GB 1154517A
Authority
GB
United Kingdom
Prior art keywords
ethylene
preparation
vinyl acetate
june
prepared
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2823967A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Stamicarbon BV
Original Assignee
Stamicarbon BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Stamicarbon BV filed Critical Stamicarbon BV
Publication of GB1154517A publication Critical patent/GB1154517A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

1,154,517. Unsaturated esters. STAMICARBON N.V. 19 June, 1967 [21 June, 1966; 12 May, 1967], No. 28239/67. Heading C2C. Unsaturated esters are prepared from an olefine and a saturated carboxylic acid by passing a gaseous mixture thereof with oxygen at an elevated temperature over a catalyst comprising a carrier and metallic palladium and one or more of the metals platinum, rhodium or ruthenium in a weight ratio of palladium to the other metal of between 300 : 1 to 3 : 1. Ethylene, propylene, isobutene and butadiene and formic, acetic, propionic, n- and iso-butyric acids are mentioned and the catalysts are prepared by impregnating the conventional carrier with metallic salts, drying, hydrolysing and reducing for instance with a hydrazine-hydrate solution. The preparation of vinyl acetate is described.
GB2823967A 1966-06-21 1967-06-19 Preparation of Vinyl Acetate from Acetic Acid and Ethylene Expired GB1154517A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL6608559A NL6608559A (en) 1966-06-21 1966-06-21
NL6706640A NL6706640A (en) 1966-06-21 1967-05-12

Publications (1)

Publication Number Publication Date
GB1154517A true GB1154517A (en) 1969-06-11

Family

ID=26644052

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2823967A Expired GB1154517A (en) 1966-06-21 1967-06-19 Preparation of Vinyl Acetate from Acetic Acid and Ethylene

Country Status (9)

Country Link
AT (1) AT278731B (en)
BE (1) BE700148A (en)
CH (1) CH487829A (en)
DE (1) DE1643077B2 (en)
ES (1) ES342070A1 (en)
GB (1) GB1154517A (en)
NL (2) NL6608559A (en)
NO (1) NO121605B (en)
SE (1) SE307939B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5347046A (en) * 1993-05-25 1994-09-13 Engelhard Corporation Catalyst and process for using same for the preparation of unsaturated carboxylic acid esters
US5576457A (en) * 1995-05-23 1996-11-19 Hoechst Celanese Corporation Catalyst and procedure for preparation of vinyl acetate

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5347046A (en) * 1993-05-25 1994-09-13 Engelhard Corporation Catalyst and process for using same for the preparation of unsaturated carboxylic acid esters
US5576457A (en) * 1995-05-23 1996-11-19 Hoechst Celanese Corporation Catalyst and procedure for preparation of vinyl acetate

Also Published As

Publication number Publication date
CH487829A (en) 1970-03-31
DE1643077B2 (en) 1976-08-19
AT278731B (en) 1970-02-10
SE307939B (en) 1969-01-27
NL6706640A (en) 1968-11-13
NO121605B (en) 1971-03-22
DE1643077A1 (en) 1971-05-13
NL6608559A (en) 1967-12-22
BE700148A (en) 1967-12-19
ES342070A1 (en) 1968-10-16

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