GB1142703A - Improvements in and relating to cellulosic textile materials - Google Patents
Improvements in and relating to cellulosic textile materialsInfo
- Publication number
- GB1142703A GB1142703A GB19023/66A GB1902366A GB1142703A GB 1142703 A GB1142703 A GB 1142703A GB 19023/66 A GB19023/66 A GB 19023/66A GB 1902366 A GB1902366 A GB 1902366A GB 1142703 A GB1142703 A GB 1142703A
- Authority
- GB
- United Kingdom
- Prior art keywords
- fibres
- catalyst
- cellulosic
- agent
- yarns
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/12—Aldehydes; Ketones
- D06M13/127—Mono-aldehydes, e.g. formaldehyde; Monoketones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/12—Aldehydes; Ketones
- D06M13/123—Polyaldehydes; Polyketones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/137—Acetals, e.g. formals, or ketals
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/272—Unsaturated compounds containing sulfur atoms
- D06M13/278—Vinylsulfonium compounds; Vinylsulfone or vinylsulfoxide compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/285—Phosphines; Phosphine oxides; Phosphine sulfides; Phosphinic or phosphinous acids or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/395—Isocyanates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/423—Amino-aldehyde resins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/16—Processes for the non-uniform application of treating agents, e.g. one-sided treatment; Differential treatment
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
1,142,703. Treating cellulosic materials. RADUNER & CO. A-G. 29 April, 1966 [10 May, 1965; 21 Jan., 1966], No. 19023/66. Heading DIP. A cellulosic textile fibre is crease-proofed and its abrasion resistance is improved by reacting it with a compound capable of forming intermolecular bands between hydroxy groups in a manner such that the fibre exhibits a higher degree of intermolecular bonding between the cellulosic hydroxy groups towards the centre of the diameter of the fibre throughout its length than is exhibited in the peripheral portions of the fibre. This may be effected by impregnating cellulosic fibres, yarns, or fabric, with a cross-linking agent and a catalyst and before completion of the washfast fixation of the cross linking agent on the cellulosic fibres reducing the effective amount of catalyst in the peripheral portions of the fibres by neutralisation e.g. in the case of acid catalysts by treatment with gaseous ammonia or by applying the neutralising agent in a liquid which may or may not be miscible with the impregnation medium used for the catalyst and crosslinking agent or as a foam, by dissolving the catalyst and/or crosslinking agent off the surface of the fibres, by buffering, by insolubilisation in the case of metal salt catalysts either the cation or anion of the catalyst molecule being rendered inactive by the formation of an insoluble salt, or by increasing the number of hydroxy groups at the surface of the fibres by applying a distillable hydroxy group containing compound to the fibres after or simultaneously with the application of the cross-linking agent and catalyst the compounds accumulating at the surface of the fibres upon drying. Suitable neutralising agents in the case of acid catalysts are ammonia, octadecyl amine, morpholine and soda ash and in the case of alkaline catalysts sulphur dioxide and organic and inorganic acids. The solvent from which the crosslinking agent is applied to the fibres or dissolved therefrom may be a compound having a swelling effect on cellulose even in the absence of water, e.g. dimethyl sulphoxide, dimethyl formamide and dimethylsulphone, so that upon heating the swelling agent becomes concentrated on the surface and crosslinking is effected with the surface of the fibres in the swollen state. The crosslinking agent may be a condensation product of formaldehyde, glyoxal or acrolein with urea, a cyclic alkylene urea, a urein, a triazone or a ketone, formaldehyde, glyoxal, acrolein, acetaldehyde or an aldehyde producing compound, an epoxide, diepoxide or isocyanate, divinyl sulphone or sulphoxide, epichlorohydrin, di-chloro-1, 3-propanol or a sulphonium or phosphonium compound. After impregnation with the crosslinking agent and catalyst and drying fibres may be converted to yarns, yarns to fabrics and fabrics to garments or mechanical treatments, e.g. embossing or compressive shrinking, applied and the material then heated to effect crosslinking, the catalyst deactivation being carried out during or after drying or prior to or during curing. Fibres, yarns or fabrics comprising cotton, linen, jute, hemp, viscose rayon including polynosic fibres, or partially esterified or etherified cellulose fibres alone or in admixture with polyamide, polyurethane, polyester, acrylic or polyolefin fibres may be treated. The treating compositions may also contain a polyethylene softener.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH771865A CH448960A (en) | 1965-05-10 | 1965-05-10 | Process for the finishing of textile material containing cellulose fibers |
AT57766A AT270576B (en) | 1965-05-10 | 1966-01-21 | Textile material consisting at least partially of cellulose fibers with improved mechanical properties and a method for producing the same |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1142703A true GB1142703A (en) | 1969-02-12 |
Family
ID=25593206
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB19023/66A Expired GB1142703A (en) | 1965-05-10 | 1966-04-29 | Improvements in and relating to cellulosic textile materials |
Country Status (11)
Country | Link |
---|---|
US (1) | US3528762A (en) |
BE (1) | BE680793A (en) |
CH (1) | CH448960A (en) |
DE (1) | DE1619149A1 (en) |
DK (1) | DK124619B (en) |
FI (1) | FI47499C (en) |
FR (1) | FR1478856A (en) |
GB (1) | GB1142703A (en) |
IL (1) | IL25713A (en) |
NL (1) | NL6606365A (en) |
SE (1) | SE353110B (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4851291A (en) * | 1986-06-19 | 1989-07-25 | The United States Of America As Represented By The Secretary Of Agriculture | Temperature adaptable textile fibers and method of preparing same |
IL82915A (en) * | 1986-06-27 | 1991-05-12 | Buckeye Cellulose Corp | Individualized,crosslinked fibers and their production |
CA1340299C (en) * | 1986-06-27 | 1999-01-05 | Jeffrey Tood Cook | Process for marking individualized crosslinked fibers and fibers thereof |
CA1340434C (en) * | 1986-06-27 | 1999-03-16 | Carlisle Mitchell Herron | Process for making individualized crosslinked fibers having reduced residuals and fibers thereof |
IL82913A (en) * | 1986-06-27 | 1990-11-05 | Buckeye Cellulose Corp | Twisted,stiffened cellulosic fibers and absorbent structures made therefrom |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE508097A (en) * | ||||
US2864723A (en) * | 1956-08-23 | 1958-12-16 | American Cyanamid Co | Acid resistant cellulosic material and process for producing same |
US3309165A (en) * | 1964-03-20 | 1967-03-14 | Morris R Rogers | Process of improving the tensile strength and increasing resistance to microbiological deterioration of cellulose textile containing cured aminoplast resin by steaming |
US3402988A (en) * | 1965-04-02 | 1968-09-24 | Agriculture Usa | Chemical deactivation of catalyst at both faces of a cellulosic fabric impregnated with a resin-catalyst system to improve abrasion resistance of fabric after curing |
US3434794A (en) * | 1965-11-18 | 1969-03-25 | Cotton Producers Inst | Delayed cure of cellulosic articles |
-
1965
- 1965-05-10 CH CH771865A patent/CH448960A/en unknown
-
1966
- 1966-04-29 GB GB19023/66A patent/GB1142703A/en not_active Expired
- 1966-05-03 US US554926A patent/US3528762A/en not_active Expired - Lifetime
- 1966-05-05 FR FR60397A patent/FR1478856A/en not_active Expired
- 1966-05-05 IL IL25713A patent/IL25713A/en unknown
- 1966-05-07 DE DE19661619149 patent/DE1619149A1/en active Pending
- 1966-05-09 DK DK235566AA patent/DK124619B/en unknown
- 1966-05-10 SE SE06427/66A patent/SE353110B/xx unknown
- 1966-05-10 NL NL6606365A patent/NL6606365A/xx unknown
- 1966-05-10 BE BE680793D patent/BE680793A/xx unknown
- 1966-05-10 FI FI661238A patent/FI47499C/en active
Also Published As
Publication number | Publication date |
---|---|
FR1478856A (en) | 1967-04-28 |
FI47499B (en) | 1973-08-31 |
SE353110B (en) | 1973-01-22 |
DK124619B (en) | 1972-11-06 |
FI47499C (en) | 1973-12-10 |
US3528762A (en) | 1970-09-15 |
NL6606365A (en) | 1966-11-11 |
IL25713A (en) | 1969-11-12 |
CH448960A (en) | 1968-04-11 |
BE680793A (en) | 1966-11-10 |
CH771865A4 (en) | 1967-09-15 |
DE1619149A1 (en) | 1969-10-02 |
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