GB1102693A - Fluorinated organic compounds - Google Patents

Fluorinated organic compounds

Info

Publication number
GB1102693A
GB1102693A GB4508167A GB4508167A GB1102693A GB 1102693 A GB1102693 A GB 1102693A GB 4508167 A GB4508167 A GB 4508167A GB 4508167 A GB4508167 A GB 4508167A GB 1102693 A GB1102693 A GB 1102693A
Authority
GB
United Kingdom
Prior art keywords
prepared
formula
phenone
organic compounds
grignard reagent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4508167A
Inventor
John Colin Tatlow
Paul Leslie Coe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MacDermid Europe Ltd
Original Assignee
W Canning PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by W Canning PLC filed Critical W Canning PLC
Publication of GB1102693A publication Critical patent/GB1102693A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00—Electroplating: Baths therefor
    • C25D3/02—Electroplating: Baths therefor from solutions
    • C25D3/04—Electroplating: Baths therefor from solutions of chromium
    • C25D3/10—Electroplating: Baths therefor from solutions of chromium characterised by the organic bath constituents used
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/18—Preparation of halogenated hydrocarbons by replacement by halogens of oxygen atoms of carbonyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C25/00—Compounds containing at least one halogen atom bound to a six-membered aromatic ring
    • C07C25/02—Monocyclic aromatic halogenated hydrocarbons
    • C07C25/13—Monocyclic aromatic halogenated hydrocarbons containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01—Sulfonic acids
    • C07C309/28—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C309/39—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing halogen atoms bound to the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/78—Halides of sulfonic acids
    • C07C309/86—Halides of sulfonic acids having halosulfonyl groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/01—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and halogen atoms, or nitro or nitroso groups bound to the same carbon skeleton
    • C07C323/09—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and halogen atoms, or nitro or nitroso groups bound to the same carbon skeleton having sulfur atoms of thio groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/004—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with organometalhalides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
    • C07C45/292—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups with chromium derivatives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/52—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition by dehydration and rearrangement involving two hydroxy groups in the same molecule
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/80—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • C07C47/14—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen containing halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/04—Saturated compounds containing keto groups bound to acyclic carbon atoms
    • C07C49/16—Saturated compounds containing keto groups bound to acyclic carbon atoms containing halogen
    • C07C49/167—Saturated compounds containing keto groups bound to acyclic carbon atoms containing halogen containing only fluorine as halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/76—Ketones containing a keto group bound to a six-membered aromatic ring
    • C07C49/80—Ketones containing a keto group bound to a six-membered aromatic ring containing halogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention comprises fluorinated aromatic compounds of the general formula Z(CF2)m-C6F5 in which Z is H, F or Cl and m is an integer from 3 to 14. The compounds may be prepared by reacting sulphur tetrachloride with a phenone of formula Z(CF2)m-1-CO-C6F5. The phenone used as starting material may be prepared by the oxidation of the corresponding carbinol which in turn may be prepared by the action of a pentafluorophenyl Grignard reagent with an aldehyde of formula Z(CF2)m-1-CHO. Alternatively, the starting phenone may be prepared by the reaction of a pentafluorophenyl Grignard reagent and the corresponding acid chloride which may be made by reacting an acid of formula Z(CF2)m-1COOH and phosphorus pentachloride. Examples are given of the preparation of perfluorobutylbenzene.
GB4508167A 1964-03-03 1964-03-03 Fluorinated organic compounds Expired GB1102693A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB887364A GB1102692A (en) 1964-03-03 1964-03-03 Fluorinated aromatic compounds

Publications (1)

Publication Number Publication Date
GB1102693A true GB1102693A (en) 1968-02-07

Family

ID=9860927

Family Applications (2)

Application Number Title Priority Date Filing Date
GB887364A Expired GB1102692A (en) 1964-03-03 1964-03-03 Fluorinated aromatic compounds
GB4508167A Expired GB1102693A (en) 1964-03-03 1964-03-03 Fluorinated organic compounds

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB887364A Expired GB1102692A (en) 1964-03-03 1964-03-03 Fluorinated aromatic compounds

Country Status (1)

Country Link
GB (2) GB1102692A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2250515B (en) * 1990-11-27 1994-09-28 Rhone Poulenc Chemicals Controlling acid misting during electrolytic recovery of metals

Also Published As

Publication number Publication date
GB1102692A (en) 1968-02-07

Similar Documents

Publication Publication Date Title
SE8901532D0 (en) acetophenone
KR890015962A (en) Method for preparing ferric chloride from dilute hydrochloric acid
GB1077834A (en) Unsaturated aldehydes
GB1102693A (en) Fluorinated organic compounds
DK140254B (en) Process for the preparation of perchloromethyl mercaptan by chlorination of carbon disulfide in the presence of iodine.
GB1026290A (en) Aromatic fluorine compounds
GB1092141A (en) Fluorine-containing carboxylic acids and the manufacture thereof
GB982588A (en) Highly chlorinated aryl sulphides and processes for their manufacture
GB1051647A (en)
GB1082869A (en) Process for the manufacture of 2,2,3-trichlorobutane
GB1132141A (en) Fluorinated diols
CH412833A (en) Process for the production of 1,2-dichloroethane by oxychlorination of ethylene
GB994573A (en) Novel betalyxopyranosyl halides and a process for their preparation
GB1090222A (en) Process for the preparation of 1,2-dichlorotetrafluoro-cyclopentenone-3
JPS523014A (en) Preparation of chlorinated aldehyde
GB907267A (en) Photographic materials and method of developing the same
GB1269196A (en) Organic hpyochlorites
CH444830A (en) Process for the production of chlorine from gaseous or aqueous hydrochloric acid by oxidation with nitric acid
GB971591A (en) Process for the manufacture of pseudocumene-5-carboxylic acid
AT274758B (en) Process for the production of 1,2-dichloroethane by adding chlorine to ethylene
ES351101A1 (en) Process for the manufacture of nitrosyl chloride
GB1060156A (en) Process for the production of 3-alkylphenols
GB1100261A (en) Improvements in the manufacture of highly fluorinated aromatic compounds
GB1552368A (en) Preparation of olefinic compounds by disproportionation
GB1012840A (en) 2,3 - dichloro - pyrazine