GB1084549A - New compositions of matter having catalytic properties - Google Patents
New compositions of matter having catalytic propertiesInfo
- Publication number
- GB1084549A GB1084549A GB3477363A GB3477363A GB1084549A GB 1084549 A GB1084549 A GB 1084549A GB 3477363 A GB3477363 A GB 3477363A GB 3477363 A GB3477363 A GB 3477363A GB 1084549 A GB1084549 A GB 1084549A
- Authority
- GB
- United Kingdom
- Prior art keywords
- formates
- alkali
- preferred
- salts
- decan
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
- C07C69/04—Formic acid esters
- C07C69/06—Formic acid esters of monohydroxylic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Formate esters are made by reacting an hydroxy organic compound with CO in the presence of an alkali or alkaline earth metal salt on quaternary NH4 salt and an olefin oxide. Preferred salts are carbonates, formates, acetates and benzoates. C2- 8 olefine oxides are preferred. Preferred hydroxy compounds are C1- 4 monohydric alcohols. Examples describe the conversion of methanol, ethanol, n-propanol and decan-1-ol to methyl, ethyl, n-propyl and decan-1-ol formates respectively.ALSO:Quaternary ammonium, alkali or alkaline earth metal salts in combination with an olefin oxide are used to convert organic hydroxy compounds to the corresponding formate esters in the presence of CO. The salts may be formates, acetates, benzoates or p carbonates. An alkali metal carbonate may be produced in situ from CO2, alkoxide (ex. EtOH + Na).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3477363A GB1084549A (en) | 1963-09-03 | 1963-09-03 | New compositions of matter having catalytic properties |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3477363A GB1084549A (en) | 1963-09-03 | 1963-09-03 | New compositions of matter having catalytic properties |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1084549A true GB1084549A (en) | 1967-09-27 |
Family
ID=10369775
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3477363A Expired GB1084549A (en) | 1963-09-03 | 1963-09-03 | New compositions of matter having catalytic properties |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1084549A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0104875A1 (en) * | 1982-09-25 | 1984-04-04 | BP Chemicals Limited | Process for the production of formates |
| US4661624A (en) * | 1984-08-13 | 1987-04-28 | Chang Tsuan Y | Process for the production of methyl formate |
-
1963
- 1963-09-03 GB GB3477363A patent/GB1084549A/en not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0104875A1 (en) * | 1982-09-25 | 1984-04-04 | BP Chemicals Limited | Process for the production of formates |
| AU570220B2 (en) * | 1982-09-25 | 1988-03-10 | Bp Chemicals Limited | Preparation of alkyl formates |
| US4734525A (en) * | 1982-09-25 | 1988-03-29 | Bp Chemicals Limited | Process for the production of formates |
| US4661624A (en) * | 1984-08-13 | 1987-04-28 | Chang Tsuan Y | Process for the production of methyl formate |
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