GB1069220A - Improvements in or relating to the production of oxide layers on silicon bodies - Google Patents
Improvements in or relating to the production of oxide layers on silicon bodiesInfo
- Publication number
- GB1069220A GB1069220A GB30508/65A GB3050865A GB1069220A GB 1069220 A GB1069220 A GB 1069220A GB 30508/65 A GB30508/65 A GB 30508/65A GB 3050865 A GB3050865 A GB 3050865A GB 1069220 A GB1069220 A GB 1069220A
- Authority
- GB
- United Kingdom
- Prior art keywords
- plate
- cover
- gas
- bodies
- rinsing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title 1
- 229910052710 silicon Inorganic materials 0.000 title 1
- 239000010703 silicon Substances 0.000 title 1
- 239000007789 gas Substances 0.000 abstract 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 3
- 239000010410 layer Substances 0.000 abstract 2
- 230000003647 oxidation Effects 0.000 abstract 2
- 238000007254 oxidation reaction Methods 0.000 abstract 2
- 230000001590 oxidative effect Effects 0.000 abstract 2
- 239000000376 reactant Substances 0.000 abstract 2
- 235000012239 silicon dioxide Nutrition 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- -1 HCL Chemical class 0.000 abstract 1
- 229910003910 SiCl4 Inorganic materials 0.000 abstract 1
- 229910003822 SiHCl3 Inorganic materials 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- 238000005530 etching Methods 0.000 abstract 1
- 229910002804 graphite Inorganic materials 0.000 abstract 1
- 239000010439 graphite Substances 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002366 halogen compounds Chemical class 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 229910000039 hydrogen halide Inorganic materials 0.000 abstract 1
- 239000012433 hydrogen halide Substances 0.000 abstract 1
- 239000011261 inert gas Substances 0.000 abstract 1
- 229910003465 moissanite Inorganic materials 0.000 abstract 1
- 229910021421 monocrystalline silicon Inorganic materials 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- 239000010453 quartz Substances 0.000 abstract 1
- 229910010271 silicon carbide Inorganic materials 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 abstract 1
- 125000006850 spacer group Chemical group 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 239000002344 surface layer Substances 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02225—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer
- H01L21/02227—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a process other than a deposition process
- H01L21/0223—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a process other than a deposition process formation by oxidation, e.g. oxidation of the substrate
- H01L21/02233—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a process other than a deposition process formation by oxidation, e.g. oxidation of the substrate of the semiconductor substrate or a semiconductor layer
- H01L21/02236—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a process other than a deposition process formation by oxidation, e.g. oxidation of the substrate of the semiconductor substrate or a semiconductor layer group IV semiconductor
- H01L21/02238—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a process other than a deposition process formation by oxidation, e.g. oxidation of the substrate of the semiconductor substrate or a semiconductor layer group IV semiconductor silicon in uncombined form, i.e. pure silicon
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02225—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer
- H01L21/02227—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a process other than a deposition process
- H01L21/02255—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a process other than a deposition process formation by thermal treatment
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02296—Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer
- H01L21/02299—Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer pre-treatment
- H01L21/02312—Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer pre-treatment treatment by exposure to a gas or vapour
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/302—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
- H01L21/306—Chemical or electrical treatment, e.g. electrolytic etching
- H01L21/3065—Plasma etching; Reactive-ion etching
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Microelectronics & Electronic Packaging (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Power Engineering (AREA)
- Plasma & Fusion (AREA)
- Drying Of Semiconductors (AREA)
- Silicon Compounds (AREA)
- Carbon And Carbon Compounds (AREA)
- Cleaning Or Drying Semiconductors (AREA)
Abstract
A layer of SiO2 is produced on the surface of a monocrystalline Si body by first subjecting the body to the action of a gaseous reactant to remove a surface layer of Si, then rinsing with an inert gas, and oxidizing the Si surface with O2 or H2O vapour. The gaseous reactant may be a halogen or a hydrogen halide, e.g. HCL, and may be diluted with H2 or Ar. The removal of the Si layer may be effected by a transport reaction between the Si surface and the adjacent surface of a parallel cover-plate spaced at a distance of 0.1-1 mm. away and maintained at a temperature 15-30 DEG C. lower than the Si body. In this case, a halogen compound of Si, e.g. SiCl4 or SiHCl3 may be used, preferably mixed with H2 in the ratio 0.01 : 1 to 0.05 : 1; it decomposes in the hot parts of the vessel to deposit Si and form HCl, which then acts as the transport gas. The cover-plate may be made of Si, or quartz, SiC, or graphite, which may be coated with Si. It may rest on the Si body, be separated by a spacer, or be arranged freely, and is preferably removed before oxidation. A plurality of Si bodies may be treated by using a single cover-plate with slots between the bodies, or by stacking the bodies vertically so that each acts as a cover-plate for the next. The inert rinsing gas may be N2, H2 or a rare gas, e.g. Ar. The water vapour oxidant may be carried by H2 or a rare gas. The temperature of the Si body may be 1100-1250 DEG C. during etching, 1150-1200 DEG C. during rinsing, and 900-1150 DEG C. during oxidation. A continuous flow or closed system may be used.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DES92134A DE1287411B (en) | 1964-07-20 | 1964-07-20 | A method of forming an oxide layer on the surface of a silicon crystal for semiconductor devices |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1069220A true GB1069220A (en) | 1967-05-17 |
Family
ID=7517013
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB30508/65A Expired GB1069220A (en) | 1964-07-20 | 1965-07-19 | Improvements in or relating to the production of oxide layers on silicon bodies |
Country Status (4)
Country | Link |
---|---|
CH (1) | CH467346A (en) |
DE (1) | DE1287411B (en) |
GB (1) | GB1069220A (en) |
NL (1) | NL6509178A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1085562A2 (en) * | 1999-09-17 | 2001-03-21 | Applied Materials, Inc. | Apparatus and method for surface finishing a silicon film |
-
1964
- 1964-07-20 DE DES92134A patent/DE1287411B/en active Pending
-
1965
- 1965-07-15 NL NL6509178A patent/NL6509178A/xx unknown
- 1965-07-16 CH CH999565A patent/CH467346A/en unknown
- 1965-07-19 GB GB30508/65A patent/GB1069220A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1085562A2 (en) * | 1999-09-17 | 2001-03-21 | Applied Materials, Inc. | Apparatus and method for surface finishing a silicon film |
EP1085562A3 (en) * | 1999-09-17 | 2004-06-09 | Applied Materials, Inc. | Apparatus and method for surface finishing a silicon film |
EP1603154A2 (en) * | 1999-09-17 | 2005-12-07 | Applied Materials, Inc. | Apparatus and method for surface finishing a silicon film |
EP1603154A3 (en) * | 1999-09-17 | 2010-09-29 | Applied Materials, Inc. | Apparatus and method for surface finishing a silicon film |
Also Published As
Publication number | Publication date |
---|---|
NL6509178A (en) | 1966-01-21 |
CH467346A (en) | 1969-01-15 |
DE1287411B (en) | 1969-01-16 |
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