GB1011662A - Improvements in the sizing of synthetic polymeric filaments - Google Patents

Improvements in the sizing of synthetic polymeric filaments

Info

Publication number
GB1011662A
GB1011662A GB1729362A GB1729362A GB1011662A GB 1011662 A GB1011662 A GB 1011662A GB 1729362 A GB1729362 A GB 1729362A GB 1729362 A GB1729362 A GB 1729362A GB 1011662 A GB1011662 A GB 1011662A
Authority
GB
United Kingdom
Prior art keywords
copolymer
acid
ester
acrylic acid
filaments
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1729362A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Farbwerke Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG, Farbwerke Hoechst AG filed Critical Hoechst AG
Publication of GB1011662A publication Critical patent/GB1011662A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02J—FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
    • D02J1/00—Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
    • D02J1/22—Stretching or tensioning, shrinking or relaxing, e.g. by use of overfeed and underfeed apparatus, or preventing stretch
    • D02J1/221—Preliminary treatments
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02J—FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
    • D02J1/00—Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
    • D02J1/22—Stretching or tensioning, shrinking or relaxing, e.g. by use of overfeed and underfeed apparatus, or preventing stretch
    • D02J1/228—Stretching in two or more steps, with or without intermediate steps
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • D06M15/233—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated aromatic, e.g. styrene
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

Sizes applied to synthetic polymeric filaments in the form of aqueous dispersions comprise: (a) a mixture of a vinyl chloride/butylacrylate copolymer and a vinylidene chloride/acrylonitrile/vinyl acetate copolymer, (b) a vinyl chloride / isooctylacrylate / methyl acrylamide copolymer, (c) a vinyl chloride/butylacrylate/vinylacetate copolymer and as thickener polyvinylacetate, (d) a vinyl chloride/butylacrylate/acrylic acid copolymer adjusted in pH value with triethanolamine and as thickener polyvinyl alcohol, (e) a vinyl chloride/isooctylacrylate/maleic acid butyl semi-ester copolymer, (f) a vinyl chloride/crotanic acid octyl ester/acrylic acid butyl ester/crotanic acid copolymer adjusted in pH value with triethanolamine, (g) an acrylamide / vinyl acetate / vinyl chloride/butylacrylate copolymer, (h) an acrylic acid butyl ester/vinyl acetate/acrylic acid/styrene copolymer adjusted in a pH value with triethanolamine, (i) a vinyl propionate/propyl acrylate/maleic acid diethyl ester/crotonic acid copolymer adjusted in pH value with triethanolamine, (j) a methyl acrylate/acrylic acid copolymer or (k) a methylacrylate/ethylacrylate/crotonic acid copolymer.ALSO:Endless filaments made from synthetic polymeric materials, e.g. polyamides, polyesters, polyurethanes, polycarbonates, polyolefins, polyvinylalcohol, copolymers or co-condensates or block polymers or block condensates, are sized by treating them with an aqueous dispersion of a film-forming water-insoluble polymer or copolymer made from vinyl chloride, acrylonitrile, methacrylic acid amide, acrylic acid amide, a methacrylic acid ester, an acrylic acid ester, a crotonic acid ester, styrene, vinylidene chloride, a maleic acid ester or a vinyl ester, which in the case of a copolymer may also contain up to a total of 3% by weight of one or more of methacrylic acid, acrylic acid, crotonic acid, a maleic acid semi-ester or maleic acid, and then drying them before they reach the draw-off device. The sizing compositions may also contain ammonia, triethanol amine and heat stabilizers, e.g. organo-tin compounds, organolead compounds and amines. The sizing composition may be applied to the freshly spun filaments before they are drawn or it may be applied after predrawing before afterdrawing, between after-drawing and shrinking or after drawing and shrinking before being spooled on a bobbin. The filaments may be passed tangentially over an applicator roll covered with a textile, plastic or ceramic material which rotates either in the same or in the opposite direction of filament passage and which is immersed in the sizing composition in a pan. Alternatively the filaments may be passed at first over a roller immersed in the sizing composition and then tangentially below a roller which presses against a second roller which rotates in the sizing composition. Grooved rollers may be used. Static charging when the filaments are passed over guide rollers may be prevented by wetting the filaments after sizing and drying with water containing a small quantity of a surface-active agent, e.g. polyethenoxylated fatty acids, fatty alcohols, amines or amides. The filaments may subsequently be made into fabrics and coated with polyvinyl chloride, polyurethanes, polychlorobutadiene, polyisoprene, polybutadiene or natural rubber.ALSO:Endless filaments made from synthetic polymeric materials, e.g. polyamides, poleysters, polyurethanes, polycarbonates, polyolefins, polyvinyl alcohol, copolymers or co-condensates or block polymers or block condensates, which have been sized with polymers or copolymers made from vinyl chloride, acrylonitrile, methacrylic acid amide, acrylic acid amide, methacrylic acid esters, acrylic acid esters, crotonic acid esters, styrene, vinylidene chloride, maleic acid esters or vinyl esters which in the case of copolymers may also contain up to a total of 3% by weight of one or more of methacrylic acid, acrylic acid, crotonic acid, a maleic acid semi-ester or maleic acid, are made into fabrics and coated with polyvinyl chloride, polyurethanes, polychlorobutadiene, polyisoprene, polybutadiene or natural rubber.
GB1729362A 1961-05-04 1962-05-04 Improvements in the sizing of synthetic polymeric filaments Expired GB1011662A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEF33840A DE1274060B (en) 1961-05-04 1961-05-04 Method for sizing threads

Publications (1)

Publication Number Publication Date
GB1011662A true GB1011662A (en) 1965-12-01

Family

ID=7095282

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1729362A Expired GB1011662A (en) 1961-05-04 1962-05-04 Improvements in the sizing of synthetic polymeric filaments

Country Status (6)

Country Link
AT (1) AT247830B (en)
BE (1) BE617263A (en)
CH (1) CH416540A (en)
DE (1) DE1274060B (en)
GB (1) GB1011662A (en)
NL (1) NL277915A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014192968A1 (en) * 2013-05-31 2014-12-04 Henkel Ag & Co Kgaa Water-dispersed resin composition

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108330687B (en) * 2018-01-29 2020-09-18 西安工程大学 Hot-melt textile size preparation method based on bulk polymerization method

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE13533C (en) * m. mengers in Berlin Innovations in the dyeing of cotton and the associated machines
DE653108C (en) * 1937-11-15 Zell J Krueckels Kom Ges Masch Chain sizing machine for sizing artificial silk warps
GB210266A (en) * 1923-01-11 1924-01-31 Henry Dreyfus Improvements in or relating to the manufacture or treatment of threads of artificialfilaments
DE560795C (en) * 1931-06-20 1932-10-07 Algemeene Kunstzijde Unie N V Device for drying sized yarn bundles, especially made of rayon, during rewinding
DE669020C (en) * 1936-12-04 1938-12-15 Colsman Geb Method and device for sizing textile threads before crepe turning, in particular artificial silk
FR855419A (en) * 1938-05-27 1940-05-10 Ig Farbenindustrie Ag Textile materials provided with a finish and method for producing such materials
US2730790A (en) * 1949-12-01 1956-01-17 Monsanto Chemicals Treatment of textile fibers
NL197987A (en) * 1954-06-14
FR1127289A (en) * 1954-07-09 1956-12-12 Hoechst Ag Process for preparing semi-finished products in the manufacture of hats of wool and hair
GB785673A (en) * 1955-06-29 1957-10-30 Mohasco Ind Inc Improvements in soil resistant pile fabrics and method of making them
FR1151071A (en) * 1956-05-30 1958-01-23 Permanent weighing process using polyvinyl acetate copolymers in aqueous suspension

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014192968A1 (en) * 2013-05-31 2014-12-04 Henkel Ag & Co Kgaa Water-dispersed resin composition
JP2014234560A (en) * 2013-05-31 2014-12-15 ヘンケルジャパン株式会社 Water dispersion type resin composition

Also Published As

Publication number Publication date
NL277915A (en)
AT247830B (en) 1966-06-27
CH416540A (en) 1966-07-15
BE617263A (en)
DE1274060B (en) 1968-08-01

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