GB919317A - Sizing solution for glass fibers - Google Patents

Sizing solution for glass fibers

Info

Publication number
GB919317A
GB919317A GB23758/60A GB2375860A GB919317A GB 919317 A GB919317 A GB 919317A GB 23758/60 A GB23758/60 A GB 23758/60A GB 2375860 A GB2375860 A GB 2375860A GB 919317 A GB919317 A GB 919317A
Authority
GB
United Kingdom
Prior art keywords
latex
silane
gamma
alkenyl
amino
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB23758/60A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PPG Industries Inc
Original Assignee
Pittsburgh Plate Glass Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pittsburgh Plate Glass Co filed Critical Pittsburgh Plate Glass Co
Publication of GB919317A publication Critical patent/GB919317A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B15/00—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00
    • B29B15/08—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00 of reinforcements or fillers
    • B29B15/10—Coating or impregnating independently of the moulding or shaping step
    • B29B15/12—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B15/00—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00
    • B29B15/08—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00 of reinforcements or fillers
    • B29B15/10—Coating or impregnating independently of the moulding or shaping step
    • B29B15/12—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length
    • B29B15/14—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length of filaments or wires
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06—Fibrous reinforcements only
    • B29C70/10—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
    • B29C70/16—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length
    • B29C70/20—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length oriented in a single direction, e.g. roofing or other parallel fibres
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • C03C25/26—Macromolecular compounds or prepolymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B1/00—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating
    • D06B1/10—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating by contact with a member carrying the treating material
    • D06B1/14—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating by contact with a member carrying the treating material with a roller
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
    • D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
    • D06M15/3568—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2709/00—Use of inorganic materials not provided for in groups B29K2703/00 - B29K2707/00, for preformed parts, e.g. for inserts
    • B29K2709/08—Glass

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Composite Materials (AREA)
  • Inorganic Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Surface Treatment Of Glass Fibres Or Filaments (AREA)

Abstract

An aqueous sizing solution for application to glass fibre filaments comprises a latex of a polymer of an ethylenic monomer as a binder, an alkenyl acyloxy silane as a coupling agent and a textile softener for the glass filaments, the alkenyl acyloxy silane being used in combination with gamma-amino-propyltriethoxy silane and, if desired, a water soluble melamineformaldehyde resin. Latex polymers specified are polyvinyl acetate, polymers of C1-C6 aliphatic acrylates and methacrylates, e.g. polymethyl methacrylate, copolymers of butadiene with styrene or acrylonitrile, polyvinyl chloride, polystyrene, vinyl chloride-vinyl acetate copolymers and polymers of chlorovinyl acetate, butadiene acrylonitrile and vinylidene chloride. As an alkenyl acyloxy silane there is specified vinyltriacetoxy silane. Textile softeners specified are amides of C4-C24 fatty acids, including acid solubilized polymers of the lower molecular weight unsaturated amides, and the alkyl imidazoline derivatives formed by reacting fatty acids with polyalkylene polyamines, e.g. the reaction product of stearic acid and tetraethylene pentamine. Also present in the size may be a wetting agent, such as cetylamine or stearylamine hydrochloride or acetate, dodecylamine, hexadecylamine, dodecylmethylamine and salts thereof, trimethyl stearyl or cetyl ammonium bromides and chlorides and polyoxyethylene sorbitan monostearate or trioleate and a plasticizer for the polymer, e.g. dibutyl, dioctyl and diisooctyl phthalates and tricresyl phosphate. Specification 919,318 is referred to.ALSO:Glass fibre strands are sized by applying thereto an aqueous sizing composition comprising an emulsion polymerization latex of an ethylenic monomer as a binder, an alkenyl acyloxy silane as a coupling agent, and a textile softener for the glass fibre filaments, the alkenyl acyloxy silane being used in combination with gamma-amino-propyltriethoxy silane and, if desired, with a water-soluble melamine-formaldehyde resin, and then drying the glass fibres so-treated. The examples describe the following compositions for application to glass fibres: (1) polyvinyl acetate latex with acetic acid-solubilized pelargonic amide, vinyl triacetoxysilane and gamma-amino-propyl triethoxysilane, (2) as in (1) but containing also a water-soluble melamine-formaldehyde resin, (3) butadiene-styrene copolymer latex with vinyl triacetoxysilane, gamma-amino-propyl-triethoxysilane and the methacrylic acid-solubilized tetraethylene pentamine amide of stearic acid, and (4) polymethyl methacrylate latex, vinyl triacetoxysilane, gamma-amino-propyl triethoxysilane and a solubilized fatty acid amide. Also present may be wetting agents, plasticizers and alternative latices and softeners (see Group IV(a)). Specification 919,318 is referred to.
GB23758/60A 1959-07-07 1960-07-07 Sizing solution for glass fibers Expired GB919317A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US82543259A 1959-07-07 1959-07-07

Publications (1)

Publication Number Publication Date
GB919317A true GB919317A (en) 1963-02-20

Family

ID=25243992

Family Applications (2)

Application Number Title Priority Date Filing Date
GB23758/60A Expired GB919317A (en) 1959-07-07 1960-07-07 Sizing solution for glass fibers
GB1791/61A Expired GB919318A (en) 1959-07-07 1960-07-07 Sizing solution for glass fibers

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB1791/61A Expired GB919318A (en) 1959-07-07 1960-07-07 Sizing solution for glass fibers

Country Status (5)

Country Link
BE (1) BE592716A (en)
DE (1) DE1154243B (en)
FR (1) FR1267996A (en)
GB (2) GB919317A (en)
NL (1) NL253518A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2287248A4 (en) * 2008-04-08 2011-10-19 Sumitomo Chemical Co Methacrylic resin composition for hot plate melt-bonding, use of the same for hot plate melt-bonding, and melt-bonding method

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2148458C2 (en) * 1971-09-28 1984-03-29 Wacker-Chemie GmbH, 8000 München Process for the preparation of polyvinyl ester dispersions with improved adhesion
DE2325575A1 (en) * 1973-05-19 1974-11-28 Bayer Ag METHOD OF AFTER-TREATMENT OF INORGANIC FIBERS
FR2421982A1 (en) 1978-04-03 1979-11-02 Saint Gobain SIZING COMPOSITION AND GLASS FIBERS TREATED WITH THIS COMPOSITION
CA1115876A (en) * 1978-08-14 1982-01-05 Chester S. Temple Storage stable polyolefin compatible size for fiber glass strands
US4358501A (en) 1978-08-14 1982-11-09 Ppg Industries, Inc. Storage stable polyolefin compatible size for fiber glass strands
US4248935A (en) 1978-08-21 1981-02-03 Ppg Industries, Inc. Storage stable polyolefin compatible non-crosslinking size for fiber glass strands
US4919739A (en) * 1986-11-07 1990-04-24 Basf Aktiengesellschaft Production of improved preimpregnated material comprising a particulate thermosetting resin suitable for use in the formation of a substantially void-free fiber-reinforced composite article
US4894105A (en) * 1986-11-07 1990-01-16 Basf Aktiengesellschaft Production of improved preimpregnated material comprising a particulate thermoplastic polymer suitable for use in the formation of substantially void-free fiber-reinforced composite article
US5128198A (en) * 1986-11-07 1992-07-07 Basf Aktiengesellschaft Production of improved preimpregnated material comprising a particulate thermoplastic polymer suitable for use in the formation of a substantially void-free fiber-reinforced composite article
US4943472A (en) * 1988-03-03 1990-07-24 Basf Aktiengesellschaft Improved preimpregnated material comprising a particulate thermosetting resin suitable for use in the formation of a substantially void-free fiber-reinforced composite article
CN117698233B (en) * 2023-12-27 2024-06-07 寿光市发达布业有限公司 Multi-layer composite glass fiber super-strong felt and preparation method thereof

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2723211A (en) * 1953-04-13 1955-11-08 Cowles Chem Co Stable silane triol composition and method of treating glass therewith
US2762717A (en) * 1955-04-18 1956-09-11 Dow Corning Vinyl silicon compound and method of application to glass fibers

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2287248A4 (en) * 2008-04-08 2011-10-19 Sumitomo Chemical Co Methacrylic resin composition for hot plate melt-bonding, use of the same for hot plate melt-bonding, and melt-bonding method

Also Published As

Publication number Publication date
GB919318A (en) 1963-02-20
NL253518A (en) 1964-03-26
FR1267996A (en) 1961-07-28
DE1154243B (en) 1963-09-12
BE592716A (en)

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