GB1009197A - Stable water-in-oil emulsion - Google Patents

Stable water-in-oil emulsion

Info

Publication number
GB1009197A
GB1009197A GB33400/62A GB3340062A GB1009197A GB 1009197 A GB1009197 A GB 1009197A GB 33400/62 A GB33400/62 A GB 33400/62A GB 3340062 A GB3340062 A GB 3340062A GB 1009197 A GB1009197 A GB 1009197A
Authority
GB
United Kingdom
Prior art keywords
oil
alkyl
ammonia
oils
emulsion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB33400/62A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lubrizol Corp
Original Assignee
Lubrizol Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lubrizol Corp filed Critical Lubrizol Corp
Publication of GB1009197A publication Critical patent/GB1009197A/en
Expired legal-status Critical Current

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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/353—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C55/00—Saturated compounds having more than one carboxyl group bound to acyclic carbon atoms
    • C07C55/02—Dicarboxylic acids
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    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
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    • C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
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    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/041—Triaryl phosphates
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    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/042—Metal salts thereof
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    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
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    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
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    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06—Organic compounds derived from inorganic acids or metal salts
    • C10M2227/061—Esters derived from boron
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    • C10M2227/06—Organic compounds derived from inorganic acids or metal salts
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    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
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    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/044—Siloxanes with specific structure containing silicon-to-hydrogen bonds
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    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/05—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon
    • C—CHEMISTRY; METALLURGY
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    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/02—Groups 1 or 11
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    • C10N2010/04—Groups 2 or 12
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/08—Groups 4 or 14
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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    • C10N2010/16—Groups 8, 9, or 10
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    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/08—Hydraulic fluids, e.g. brake-fluids
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    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01—Emulsions, colloids, or micelles
    • C—CHEMISTRY; METALLURGY
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    • C10N2070/00—Specific manufacturing methods for lubricant compositions
    • C10N2070/02—Concentrating of additives

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Lubricants (AREA)

Abstract

A stable water-in-oil emulsion suitable for use as a lubricant and hydraulic fluid comprises 1-80 parts by weight of water and 20-99 parts of oil, and 0.2-10 parts per 100 parts of emulsion of a substantially saturated (i.e. no more than 5% unsaturated bonds) hydrocarbon-substituted succinic acid derivative having at least 50 aliphatic carbon atoms in the substituent, said derivative being (I) an alkali or alkaline earth metal salt, (II) an ester of a hydroxy-alkyl amine, (III) an ester of a partially acylated polyhydroxy alcohol, or (IV) an amide, imide, aminidine or salt, of ammonia, a hydroxyalkylamine or an alkylene amine, such derivatives being extensively exemplified. The oil may be a mineral oil, or a mixture of different oils such as mineral oil, vegetable oil, animal oil, silicon-containing oils, polyolefin oils, and polyester oils. Many other additives may optionally be present, these being described under the following categories: (a) emulsion stabilizers, e.g. phosphatides such as soyabean lecithin, mono-aryl and alkyl ethers of aliphatic glycols and polyglycols, fatty acid esters of such ethers, and Na, K and NH4 mahogany and synthetic sulphonates; (b) extreme pressure agents, e.g. Pb, Ni or Group II metal phosphorodithioates, chlorinated waxes, sulphurized or phosphosulphurized fatty acid esters such as sperm oil, di- and tri-hydrocarbon phosphites and phosphates, di-hydrocarbon polysulphides, and Zn, Pb, Sr, Ni, Cd and Pd dithiocarbamates; (c) rust-inhibiting agents, e.g. salts of aromatic acids with aliphatic amines (the acids including p-amino and o-chloro benzoic acids), free aliphatic amines including tertiary-alkyl primary amines and hydroxy alkyl amines, and nitrous acid salts of long-chain aliphatic amines; (d) supplemental emulsifiers, e.g. Na, NH4, Ba and Ca mahogany and synthetic sulphonates including basic sulphonates, potassium stearate, and calcium oleate; (e) foam-inhibitors, e.g. di-alkyl siloxane polymers and alkyl methacrylate polymers; (f) freezing-point depressants, e.g. polyhydric alcohols such as glycerol, and "Cellosolves" (Trade Mark); (g) bactericides, e.g. nitro - bromo - alkanes, nitro - hydroxyalkanes, andboric acid esters; and (h) oxidation inhibitors e.g. hindered phenols. Additived (a)-(h) are also extensively exemplieied. In the examples, which include emulsion concentrates, other additives used which do not fall into any of the above categories are N-tertnonyl acrylamide, N-methyl-N-carboxymethyl oleamide, tetrapropylene succinic acid, the adduct of zinc diamyl dithiophosphinate with a mixed C11- 14 tert. alkyl primary amine, and free NaOH and Ca(OH)2.ALSO:In preparative examples, polyisobutylene succinic anhydride is reacted with each of the following: (i) diethanolamine, (ii) triethanolamine, (iii) tetraethylene pentamine, (iv) ammonia, (v) ammonia, followed by five equivalents of ethylene oxide, (vi) sorbitan monooleate, (vii) polyoxyethylene sorbitan monooleate, and (viii) chlorosulphonic acid (HCl being evolved), followed by NaOH; and polyisobutylene succinic acid is also reacted with ammonia.
GB33400/62A 1961-08-30 1962-08-30 Stable water-in-oil emulsion Expired GB1009197A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US13486061A 1961-08-30 1961-08-30
US18894762A 1962-04-20 1962-04-20
US280453A US3255108A (en) 1961-08-30 1963-05-14 Water-in-oil emulsions containing succinic esters

Publications (1)

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GB1009197A true GB1009197A (en) 1965-11-10

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GB33400/62A Expired GB1009197A (en) 1961-08-30 1962-08-30 Stable water-in-oil emulsion
GB20156/56A Expired GB1059847A (en) 1961-08-30 1964-05-14 Stable water-in-oil emulsion

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Application Number Title Priority Date Filing Date
GB20156/56A Expired GB1059847A (en) 1961-08-30 1964-05-14 Stable water-in-oil emulsion

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US (1) US3255108A (en)
DE (2) DE1270723B (en)
GB (2) GB1009197A (en)

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US4770803A (en) * 1986-07-03 1988-09-13 The Lubrizol Corporation Aqueous compositions containing carboxylic salts
US4828633A (en) 1987-12-23 1989-05-09 The Lubrizol Corporation Salt compositions for explosives
US4840687A (en) * 1986-11-14 1989-06-20 The Lubrizol Corporation Explosive compositions
US4844756A (en) * 1985-12-06 1989-07-04 The Lubrizol Corporation Water-in-oil emulsions
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EP0407124A1 (en) * 1989-07-07 1991-01-09 Tonen Corporation Lubricating oil composition
US5047175A (en) 1987-12-23 1991-09-10 The Lubrizol Corporation Salt composition and explosives using same
US5129972A (en) 1987-12-23 1992-07-14 The Lubrizol Corporation Emulsifiers and explosive emulsions containing same
US5527491A (en) 1986-11-14 1996-06-18 The Lubrizol Corporation Emulsifiers and explosive emulsions containing same
USRE36479E (en) * 1986-07-03 2000-01-04 The Lubrizol Corporation Aqueous compositions containing nitrogen-containing salts
GB2408748A (en) * 2004-02-05 2005-06-08 Niche Products Ltd Hydraulic fluids
RU2652714C1 (en) * 2017-07-17 2018-04-28 Общество с ограниченной ответственностью "РудХим" Universal emulsifier of inverted emulsions
CN109328226A (en) * 2016-06-17 2019-02-12 道达尔销售服务公司 Lubricant polymer

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US3939088A (en) * 1974-03-25 1976-02-17 Chevron Research Company Fire-resistant hydraulic fluid
US4045363A (en) * 1975-11-07 1977-08-30 The Elco Corporation Invert emulsions of improved extreme pressure properties
US4094800A (en) * 1976-07-14 1978-06-13 Standard Oil Company (Indiana) Anti-wear lubricating oil compositions
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US4575526A (en) * 1982-08-09 1986-03-11 The Lubrizol Corporation Hydrocarbyl substituted carboxylic acylaging agent derivative containing combinations, and fuels containing same
US4564460A (en) * 1982-08-09 1986-01-14 The Lubrizol Corporation Hydrocarbyl-substituted carboxylic acylating agent derivative containing combinations, and fuels containing same
US4471091A (en) * 1982-08-09 1984-09-11 The Lubrizol Corporation Combinations of carboxylic acylating agents substituted with olefin polymers of high and low molecular weight mono-olefins, derivatives thereof, and fuels and lubricants containing same
US4596663A (en) * 1982-08-09 1986-06-24 The Lubrizol Corporation Carboxylic acylating agents substituted with olefin polymers of high molecular weight mono-olefins, derivatives thereof, and fuels and lubricants containing same
US4613342A (en) * 1982-08-09 1986-09-23 The Lubrizol Corporation Hydrocarbyl substituted carboxylic acylating agent derivative containing combinations, and fuels containing same
US4486573A (en) * 1982-08-09 1984-12-04 The Lubrizol Corporation Carboxylic acylating agents substituted with olefin polymers of high molecular weight mono-olefins, derivatives thereof, and fuels and lubricants containing same
US4489194A (en) * 1982-08-09 1984-12-18 The Lubrizol Corporation Carboxylic acylating agents substituted with olefin polymers of high/low molecular weight mono-olefins, derivatives thereof, and fuels and lubricants containing same
US4623684A (en) 1982-08-09 1986-11-18 The Lubrizol Corporation Hydrocarbyl substituted carboxylic acylating agent derivative containing combinations, and fuels containing same
US4559155A (en) * 1982-08-09 1985-12-17 The Lubrizol Corporation Hydrocarbyl substituted carboxylic acylating agent derivative containing combinations, and fuels containing same
US4539125A (en) * 1982-11-30 1985-09-03 Idemitsu Kosan Company Water-based metal-working fluid
GB8407300D0 (en) * 1984-03-21 1984-04-26 Ici Plc Surfactants
GB2156799B (en) * 1984-03-21 1987-12-16 Ici Plc Emulsion explosive
GB8410393D0 (en) * 1984-04-24 1984-05-31 Ici Plc Fluid compositions
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GB1059847A (en) 1967-02-22
US3255108A (en) 1966-06-07
DE1270723B (en) 1968-06-20

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