GB1008115A - Improvements in or relating to peroxide initiator compositions - Google Patents

Improvements in or relating to peroxide initiator compositions

Info

Publication number
GB1008115A
GB1008115A GB28991/63A GB2899163A GB1008115A GB 1008115 A GB1008115 A GB 1008115A GB 28991/63 A GB28991/63 A GB 28991/63A GB 2899163 A GB2899163 A GB 2899163A GB 1008115 A GB1008115 A GB 1008115A
Authority
GB
United Kingdom
Prior art keywords
life
hour half
peroxide
type
relating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB28991/63A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dart Industries Inc
Original Assignee
Rexall Drug and Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rexall Drug and Chemical Co filed Critical Rexall Drug and Chemical Co
Publication of GB1008115A publication Critical patent/GB1008115A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Ethylene is polymerized, e.g. at 15000 to 60000 p.s.i., with a peroxide initiator composition comprising at least 3 peroxides selected from at least two of the following three types: Type 1, having a 10-hour half-life at 110 DEG to 175 DEG F.; Type II, having a 10-hour half-life at 175 DEG to 250 DEG F.; and Type III, having a 10-hour half-life at 250 DEG to 320 DEG F. In examples the initiator composition comprises lauroyl peroxide and/or tertiary butyl peroxyisobutyrate, tertiary butyl peracetate and ditertiary butyl peroxide. Comonomers and/or chain transfer agents may be present and a continuous flow tubular reactor may be used. Specification 471,590 is referred to.
GB28991/63A 1962-07-20 1963-07-22 Improvements in or relating to peroxide initiator compositions Expired GB1008115A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US21135562A 1962-07-20 1962-07-20
BE640899 1963-12-06

Publications (1)

Publication Number Publication Date
GB1008115A true GB1008115A (en) 1965-10-27

Family

ID=25655602

Family Applications (1)

Application Number Title Priority Date Filing Date
GB28991/63A Expired GB1008115A (en) 1962-07-20 1963-07-22 Improvements in or relating to peroxide initiator compositions

Country Status (5)

Country Link
BE (1) BE640899A (en)
DE (1) DE1520655B1 (en)
FR (1) FR1383259A (en)
GB (1) GB1008115A (en)
NL (1) NL292959A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1948005A1 (en) * 1969-09-23 1971-04-08 Basf Ag Process for the production of homo- or copolymers of ethylene
DE2643882A1 (en) * 1975-10-01 1977-04-14 Princeton Polymer Lab POLYAETHYLENE WAXES

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB870043A (en) * 1959-04-20 1961-06-07 Union Carbide Corp Improvements in and relating to polymerisation

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1948005A1 (en) * 1969-09-23 1971-04-08 Basf Ag Process for the production of homo- or copolymers of ethylene
US3714135A (en) * 1969-09-23 1973-01-30 Basf Ag Production of homopolymers or copolymers of ethylene
DE2643882A1 (en) * 1975-10-01 1977-04-14 Princeton Polymer Lab POLYAETHYLENE WAXES

Also Published As

Publication number Publication date
NL292959A (en)
FR1383259A (en) 1964-12-24
BE640899A (en) 1964-04-01
DE1520655B1 (en) 1970-02-12

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