GB1002493A - A method of preparing polymer dispersions and method of coating or impregnating substrates therewith - Google Patents

A method of preparing polymer dispersions and method of coating or impregnating substrates therewith

Info

Publication number
GB1002493A
GB1002493A GB214563A GB214563A GB1002493A GB 1002493 A GB1002493 A GB 1002493A GB 214563 A GB214563 A GB 214563A GB 214563 A GB214563 A GB 214563A GB 1002493 A GB1002493 A GB 1002493A
Authority
GB
United Kingdom
Prior art keywords
ethyl acrylate
methyl methacrylate
oil
acrylic acid
dispersion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB214563A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rohm and Haas Co
Original Assignee
Rohm and Haas Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US169957A external-priority patent/US3198759A/en
Priority claimed from US191637A external-priority patent/US3258438A/en
Application filed by Rohm and Haas Co filed Critical Rohm and Haas Co
Publication of GB1002493A publication Critical patent/GB1002493A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/46—Polyesters chemically modified by esterification
    • C08G63/48—Polyesters chemically modified by esterification by unsaturated higher fatty oils or their acids; by resin acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/06—Organic solvent
    • C08F2/08—Organic solvent with the aid of dispersing agents for the polymer
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Paints Or Removers (AREA)

Abstract

Non-aqueous polymer dispersions are made by polymerizing an ethylenic monomer charge in a hydrocarbon medium in which the resulting polymer is insoluble and which consists of at least 51% of aliphatic hydrocarbon, the medium having dissolved therein a drying oil-modified polyester. The Examples describe the polymerization of: (1) methyl methacrylate, ethyl acrylate and acrylic acid, (2) methyl methacrylate, ethyl acrylate and acrylonitrile, (3) methyl methacrylate, ethyl acrylate and methacrylamide, (4) methyl methacrylate, ethyl acrylate and isobutyl methacrylate, (5) ethyl acrylate, vinyl chloride and acrylic acid, (6) ethyl acrylate, styrene and acrylic acid, (7) vinyl acetate, (8) methyl methacrylate and ethyl acrylate, and (9) methyl methacrylate ethyl acrylate and acrylic acid, in hydrocarbon media containing polyesters modified by soyabean oil, linseed oil fatty acids, dehydrated castor oil and safflower oil. The polymer dispersions are used in coating a variety of substrates.ALSO:Surfaces of wood, metal, concrete, vinyl tiles, and other similar materials are coated by applying thereto non-aqueous polymer dispersions made by polymerizing a monomer charge in a hydrocarbon medium in which the resulting polymer is insoluble, and which contains dissolved therein a drying oil-modified polyester (see Division C3). The examples describe: (1) glass and metal coated with a dispersion of a methyl methacrylate/ethyl acrylate/acrylic acid copolymer containing a soyabean modified alkyd resin, (2) steel panels sprayed with, and copper wire dipped in, a dispersion of a methyl methacrylate / ethyl acrylate / acrylonitrile copolymer containing a dehydrated castor oil modified alkyd resin, (3) steel, aluminium, glass and wood brushed with a dispersion of a methyl methacrylate/ethyl acrylate/methacrylamide copolymer containing a linseed oil-modified alkyd resin, (4) maple and yellow pine brushed with two coats of a dispersion of a methyl methacrylate/ethyl acrylate/isobutyl methacrylate copolymer containing a safflower oil-modified alkyd resin, and (6) red cedar with a dispersion of an ethyl acrylate/styrene/acrylic acid copolymer containing a linseed oil-modified alkyd resin.
GB214563A 1962-01-30 1963-01-17 A method of preparing polymer dispersions and method of coating or impregnating substrates therewith Expired GB1002493A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US169957A US3198759A (en) 1962-01-30 1962-01-30 Addition polymer compositions and methods of producing them
US191637A US3258438A (en) 1962-05-01 1962-05-01 Addition polymer compositions and methods of producing them

Publications (1)

Publication Number Publication Date
GB1002493A true GB1002493A (en) 1965-08-25

Family

ID=26865535

Family Applications (2)

Application Number Title Priority Date Filing Date
GB214563A Expired GB1002493A (en) 1962-01-30 1963-01-17 A method of preparing polymer dispersions and method of coating or impregnating substrates therewith
GB1616563A Expired GB1007723A (en) 1962-01-30 1963-04-24 Polymer compositions

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB1616563A Expired GB1007723A (en) 1962-01-30 1963-04-24 Polymer compositions

Country Status (1)

Country Link
GB (2) GB1002493A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2590582A1 (en) * 1985-11-27 1987-05-29 Vianova Kunstharz Ag Process for the preparation of copolymers

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4983716A (en) * 1990-01-16 1991-01-08 The Sherwin-Williams Company Non-aqueous dispersions
DE102008040464A1 (en) 2008-07-16 2010-01-21 Evonik Degussa Gmbh Coupled polyester-acrylate graft polymers
DE102009055009A1 (en) 2009-12-18 2011-06-22 Evonik Degussa GmbH, 45128 Process for the preparation of poly (meth) acrylate graft polylactone polymers

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2590582A1 (en) * 1985-11-27 1987-05-29 Vianova Kunstharz Ag Process for the preparation of copolymers

Also Published As

Publication number Publication date
GB1007723A (en) 1965-10-22

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