GB1007723A - Polymer compositions - Google Patents

Polymer compositions

Info

Publication number
GB1007723A
GB1007723A GB1616563A GB1616563A GB1007723A GB 1007723 A GB1007723 A GB 1007723A GB 1616563 A GB1616563 A GB 1616563A GB 1616563 A GB1616563 A GB 1616563A GB 1007723 A GB1007723 A GB 1007723A
Authority
GB
United Kingdom
Prior art keywords
ethyl acrylate
polymer
mixture
group
acrylate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1616563A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rohm and Haas Co
Original Assignee
Rohm and Haas Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US169957A external-priority patent/US3198759A/en
Priority claimed from US191637A external-priority patent/US3258438A/en
Application filed by Rohm and Haas Co filed Critical Rohm and Haas Co
Publication of GB1007723A publication Critical patent/GB1007723A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/46—Polyesters chemically modified by esterification
    • C08G63/48—Polyesters chemically modified by esterification by unsaturated higher fatty oils or their acids; by resin acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/06—Organic solvent
    • C08F2/08—Organic solvent with the aid of dispersing agents for the polymer
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Paints Or Removers (AREA)

Abstract

A non-aqueous graft polymer composition is obtained by polymerizing a mono-ehtylenically unsaturated monomer charge containing at least one compound containing a <FORM:1007723/C3/1> group in a liquid hydrocarbon medium which (1) is composed of one or more aliphatic hydrocarbons and not more than 49% by weight of non-aliphatic hydrocarbons and (2) has dissolved therein at least 1% by weight of a mixture of (a) a drying oil-modified fusible thermoplastic polyester condensate or such a condensate further modified by copolymerization with at least one monoethylenically unsaturated polar monomer having a <FORM:1007723/C3/2> group and a carboxyl, alcoholic hydroxyl, amine or amide group and (b) an acrylic ester polymer containing at least 50% by weight of acrylate and/or methacrylate units. The polymerization results in polymer particles stably disposed in the hydrocarbon medium and having particle sizes ranging from about 0.1 to 2 microns. The polymer may contain as much as 50% of the alkyd(acrylic polymer mixture. The acrylic ester polymer may also contain units from at least one polar monomer as defined above, may be grafted on. Preferably the mixture of (a) and (b) is prepared by polymerization of at least one polar monomer in a medium containing a mixture of a drying oil-modified fusible thermoplastic polyester and an acrylic ester polymer. The oil modified polyester condensates are prepared by conventional methods. The monomer charges used in the examples are ethyl acrylate and methyl methacrylate (Example 1), n-butyl methacrylate, ethyl acrylate and methyl methacrylate (Example 2), methyl acrylate (Example 3), acrylonitrile, ethyl acrylate (Example 4), ethyl acrylate, styrene methyl methacrylate (Example 5), vinylidene chloride, ethyl acrylate (Example 7), vinyl toluene, methyl methacrylate, ethyl acrylate (Example 8).ALSO:A non-aqueous graft polymer composition which is used as a coating for wood, glass paper cardboard, leather, aluminium, steel, ceramic, concrete, bricks, plaster, asphalt, vinyl resin tiles, linoleum, asbestos, cement siding and shingles, textile fabrics is obtained by polymerizing a monoethylenically unsaturated monomer charge containing at least one compound containing a CH2=C< group in a liquid hydrocarbon medium which (1) is composed of one or more aliphatic hydrocarbons and not more than 49% by wt. of non-aliphatic hydrocarbons and (2) has dissolved therein at least 1% by wt. of a mixture of (a) a drying oil-modified fusible thermoplastic polyester condensate or such a condensate further modified by copolymerization with at least one monoethylenically unsaturated polar monomer having a CH2=C< group and a carboxyl, alcoholic hydroxy, amine or amide group and (b) an acrylic ester polymer containing at least 50% by weight of acrylate and/or methacrylate units. The polymerization results in polymer particles stably dispersed in the hydrocarbon medium and having particle sizes ranging from about 0,1 to 2 microns. The minimum film-forming temperature of the composition may vary from about -40 DEG C. to 150 DEG C. The coating may be applied by brushing, spraying or rolling and may be air-dried or baked.
GB1616563A 1962-01-30 1963-04-24 Polymer compositions Expired GB1007723A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US169957A US3198759A (en) 1962-01-30 1962-01-30 Addition polymer compositions and methods of producing them
US191637A US3258438A (en) 1962-05-01 1962-05-01 Addition polymer compositions and methods of producing them

Publications (1)

Publication Number Publication Date
GB1007723A true GB1007723A (en) 1965-10-22

Family

ID=26865535

Family Applications (2)

Application Number Title Priority Date Filing Date
GB214563A Expired GB1002493A (en) 1962-01-30 1963-01-17 A method of preparing polymer dispersions and method of coating or impregnating substrates therewith
GB1616563A Expired GB1007723A (en) 1962-01-30 1963-04-24 Polymer compositions

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB214563A Expired GB1002493A (en) 1962-01-30 1963-01-17 A method of preparing polymer dispersions and method of coating or impregnating substrates therewith

Country Status (1)

Country Link
GB (2) GB1002493A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4983716A (en) * 1990-01-16 1991-01-08 The Sherwin-Williams Company Non-aqueous dispersions
DE102008040464A1 (en) 2008-07-16 2010-01-21 Evonik Degussa Gmbh Coupled polyester-acrylate graft polymers
DE102009055009A1 (en) 2009-12-18 2011-06-22 Evonik Degussa GmbH, 45128 Process for the preparation of poly (meth) acrylate graft polylactone polymers

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT384430B (en) * 1985-11-27 1987-11-10 Vianova Kunstharz Ag METHOD FOR PRODUCING COPOLYMERISATS

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4983716A (en) * 1990-01-16 1991-01-08 The Sherwin-Williams Company Non-aqueous dispersions
DE102008040464A1 (en) 2008-07-16 2010-01-21 Evonik Degussa Gmbh Coupled polyester-acrylate graft polymers
DE102009055009A1 (en) 2009-12-18 2011-06-22 Evonik Degussa GmbH, 45128 Process for the preparation of poly (meth) acrylate graft polylactone polymers
WO2011073006A1 (en) 2009-12-18 2011-06-23 Evonik Degussa Gmbh Method for producing poly(methyl) acrylate graft polylactone polymers

Also Published As

Publication number Publication date
GB1002493A (en) 1965-08-25

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