GB0400720D0 - Novel ferrocene-based phosphorus chiral phosphines - Google Patents

Novel ferrocene-based phosphorus chiral phosphines

Info

Publication number
GB0400720D0
GB0400720D0 GBGB0400720.9A GB0400720A GB0400720D0 GB 0400720 D0 GB0400720 D0 GB 0400720D0 GB 0400720 A GB0400720 A GB 0400720A GB 0400720 D0 GB0400720 D0 GB 0400720D0
Authority
GB
United Kingdom
Prior art keywords
chirality
ligands
based phosphorus
chiral phosphines
phosphorus chiral
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
GBGB0400720.9A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Stylacats Ltd
Original Assignee
Stylacats Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Stylacats Ltd filed Critical Stylacats Ltd
Priority to GBGB0400720.9A priority Critical patent/GB0400720D0/en
Publication of GB0400720D0 publication Critical patent/GB0400720D0/en
Priority to US10/586,204 priority patent/US20080281106A1/en
Priority to CNA2005800037217A priority patent/CN1914217A/zh
Priority to ES05701893T priority patent/ES2313282T3/es
Priority to AU2005205224A priority patent/AU2005205224B2/en
Priority to EP05701880A priority patent/EP1709054B1/en
Priority to JP2006548397A priority patent/JP2007517849A/ja
Priority to GB0500701A priority patent/GB2410950B/en
Priority to AU2005205229A priority patent/AU2005205229B2/en
Priority to GB0500704A priority patent/GB2410951B/en
Priority to CA002553608A priority patent/CA2553608A1/en
Priority to AT05701880T priority patent/ATE424404T1/de
Priority to ES05701880T priority patent/ES2323717T3/es
Priority to DE602005008917T priority patent/DE602005008917D1/de
Priority to AT05701893T priority patent/ATE404573T1/de
Priority to CA002553607A priority patent/CA2553607A1/en
Priority to JP2006548403A priority patent/JP2007517850A/ja
Priority to DE602005013062T priority patent/DE602005013062D1/de
Priority to US10/586,287 priority patent/US7994355B2/en
Priority to PCT/GB2005/000125 priority patent/WO2005068478A1/en
Priority to EP05701893A priority patent/EP1725570B1/en
Priority to PCT/GB2005/000112 priority patent/WO2005068477A1/en
Priority to CNA2005800037221A priority patent/CN1914218A/zh
Priority to GBGB0905212.7A priority patent/GB0905212D0/en
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B01J31/186—Mono- or diamide derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • B01J31/188—Amide derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/189—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms containing both nitrogen and phosphorus as complexing atoms, including e.g. phosphino moieties, in one at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1895—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing arsenic or antimony
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
    • B01J31/2447—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring
    • B01J31/2452—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring with more than one complexing phosphine-P atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
    • B01J31/2447—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring
    • B01J31/2452—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring with more than one complexing phosphine-P atom
    • B01J31/2457—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings, e.g. Xantphos
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2495—Ligands comprising a phosphine-P atom and one or more further complexing phosphorus atoms covered by groups B01J31/1845 - B01J31/1885, e.g. phosphine/phosphinate or phospholyl/phosphonate ligands
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/48—Phosphonous acids [RP(OH)2] including [RHP(=O)(OH)]; Thiophosphonous acids including [RP(SH)2], [RHP(=S)(SH)]; Derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0202—Polynuclearity
    • B01J2531/0205—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Biochemistry (AREA)
  • Molecular Biology (AREA)
  • General Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Led Devices (AREA)
  • Led Device Packages (AREA)
  • Control Of Eletrric Generators (AREA)
GBGB0400720.9A 2004-01-14 2004-01-14 Novel ferrocene-based phosphorus chiral phosphines Ceased GB0400720D0 (en)

Priority Applications (24)

Application Number Priority Date Filing Date Title
GBGB0400720.9A GB0400720D0 (en) 2004-01-14 2004-01-14 Novel ferrocene-based phosphorus chiral phosphines
CNA2005800037221A CN1914218A (zh) 2004-01-14 2005-01-14 制备不对称转化反应催化剂的方法
CA002553608A CA2553608A1 (en) 2004-01-14 2005-01-14 Process for the production of asymmetric transformation catalysts
ES05701880T ES2323717T3 (es) 2004-01-14 2005-01-14 Ligandos de fosfina o arsina quiral a base de metaloceno.
ES05701893T ES2313282T3 (es) 2004-01-14 2005-01-14 Procedimiento para la produccion de catalizadores de transformacion asimetrica.
AU2005205224A AU2005205224B2 (en) 2004-01-14 2005-01-14 Metallocene-based chiral phosphine or arsine ligands
EP05701880A EP1709054B1 (en) 2004-01-14 2005-01-14 Metallocene-based chiral phosphine or arsine ligands
JP2006548397A JP2007517849A (ja) 2004-01-14 2005-01-14 メタロセン基体のキラルホスフィンまたはアルシンリガンド
GB0500701A GB2410950B (en) 2004-01-14 2005-01-14 Process for the production of asymmetric transformation catalysts
AU2005205229A AU2005205229B2 (en) 2004-01-14 2005-01-14 Process for the production of asymmetric transformation catalysts
GB0500704A GB2410951B (en) 2004-01-14 2005-01-14 Novel metallocene-based phosphorus chiral phosphines
US10/586,204 US20080281106A1 (en) 2004-01-14 2005-01-14 Process for the Production of Asymmetric Transformation Catalysts
AT05701880T ATE424404T1 (de) 2004-01-14 2005-01-14 Chirale phosphin- bzw. arsinliganden auf metallocenbasis
CNA2005800037217A CN1914217A (zh) 2004-01-14 2005-01-14 基于金属茂的手性膦或胂配位体
DE602005008917T DE602005008917D1 (de) 2004-01-14 2005-01-14 Ymmetrische umwandlungen
AT05701893T ATE404573T1 (de) 2004-01-14 2005-01-14 Verfahren zur herstellung von katalysatoren für asymmetrische umwandlungen
CA002553607A CA2553607A1 (en) 2004-01-14 2005-01-14 Metallocene-based chiral phosphine or arsine ligands
JP2006548403A JP2007517850A (ja) 2004-01-14 2005-01-14 不斉変換触媒を製造するための方法
DE602005013062T DE602005013062D1 (de) 2004-01-14 2005-01-14 Chirale phosphin- bzw. arsinliganden auf metallocenbasis
US10/586,287 US7994355B2 (en) 2004-01-14 2005-01-14 Metallocene-based chiral phosphine or arsine ligands
PCT/GB2005/000125 WO2005068478A1 (en) 2004-01-14 2005-01-14 Process for the production of asymmetric transformation catalysts
EP05701893A EP1725570B1 (en) 2004-01-14 2005-01-14 Process for the production of asymmetric transformation catalysts
PCT/GB2005/000112 WO2005068477A1 (en) 2004-01-14 2005-01-14 Metallocene-based chiral phosphine or arsine ligands
GBGB0905212.7A GB0905212D0 (en) 2004-01-14 2009-03-26 Novel metallocene-based phosphorus chiral phosphines

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GBGB0400720.9A GB0400720D0 (en) 2004-01-14 2004-01-14 Novel ferrocene-based phosphorus chiral phosphines

Publications (1)

Publication Number Publication Date
GB0400720D0 true GB0400720D0 (en) 2004-02-18

Family

ID=31726125

Family Applications (4)

Application Number Title Priority Date Filing Date
GBGB0400720.9A Ceased GB0400720D0 (en) 2004-01-14 2004-01-14 Novel ferrocene-based phosphorus chiral phosphines
GB0500704A Expired - Fee Related GB2410951B (en) 2004-01-14 2005-01-14 Novel metallocene-based phosphorus chiral phosphines
GB0500701A Expired - Fee Related GB2410950B (en) 2004-01-14 2005-01-14 Process for the production of asymmetric transformation catalysts
GBGB0905212.7A Ceased GB0905212D0 (en) 2004-01-14 2009-03-26 Novel metallocene-based phosphorus chiral phosphines

Family Applications After (3)

Application Number Title Priority Date Filing Date
GB0500704A Expired - Fee Related GB2410951B (en) 2004-01-14 2005-01-14 Novel metallocene-based phosphorus chiral phosphines
GB0500701A Expired - Fee Related GB2410950B (en) 2004-01-14 2005-01-14 Process for the production of asymmetric transformation catalysts
GBGB0905212.7A Ceased GB0905212D0 (en) 2004-01-14 2009-03-26 Novel metallocene-based phosphorus chiral phosphines

Country Status (11)

Country Link
US (2) US7994355B2 (enExample)
EP (2) EP1725570B1 (enExample)
JP (2) JP2007517850A (enExample)
CN (2) CN1914217A (enExample)
AT (2) ATE424404T1 (enExample)
AU (2) AU2005205229B2 (enExample)
CA (2) CA2553608A1 (enExample)
DE (2) DE602005008917D1 (enExample)
ES (2) ES2313282T3 (enExample)
GB (4) GB0400720D0 (enExample)
WO (2) WO2005068477A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109078653A (zh) * 2018-10-08 2018-12-25 浙江工业大学上虞研究院有限公司 手性二茂铁磷酸催化剂及其在不对称Friedel-Crafts反应中的应用

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0400720D0 (en) * 2004-01-14 2004-02-18 Stylacats Ltd Novel ferrocene-based phosphorus chiral phosphines
WO2005108409A2 (en) * 2004-05-07 2005-11-17 Umicore Ag & Co. Kg Ferrocenyl ligands for homogeneous, enantioselective hydrogenation catalysts
US6906212B1 (en) * 2004-06-25 2005-06-14 Eastman Chemical Company Phosphine-phosphoramidite compounds
US6906213B1 (en) * 2004-06-25 2005-06-14 Eastman Chemical Company Preparation of aminophosphines
US20060135804A1 (en) * 2004-12-21 2006-06-22 Boaz Neil W Tetradentate ligands and metal complexes thereof for asymmetric catalysis
GB0500702D0 (en) * 2005-01-14 2005-02-23 Stylacats Ltd Novel metallocene-based phosphorus chiral phosphines
GB0500700D0 (en) * 2005-01-14 2005-02-23 Stylacats Ltd Process for the manufacture of 2-alkyl-3-phenylpropionic acids and alcohols
CN101421285B (zh) * 2006-04-12 2013-02-06 索尔维亚斯股份公司 二茂铁二膦
JP5209611B2 (ja) * 2006-05-23 2013-06-12 ソルヴィーアス アクチェンゲゼルシャフト 不斉付加反応、特に水素化における遷移金属触媒に使用されるキラルリガンド
JP5232989B2 (ja) * 2006-07-18 2013-07-10 国立大学法人豊橋技術科学大学 光学活性２，６−ビスアミノメチルピリジン誘導体とその製造方法およびその使用
JP5493346B2 (ja) * 2008-12-11 2014-05-14 東ソー株式会社 フェロセン誘導体およびその用途
BR112012016059A2 (pt) 2009-12-29 2015-09-01 Mapi Pharma Ltd "compostos intermediários e processos para a preparação de tapentadol e compostos relacionados".
CN102775418B (zh) * 2012-06-11 2014-12-24 中国人民解放军第四军医大学 新型手性季铵盐相转移催化剂的合成及应用
CN104592313B (zh) * 2014-12-30 2017-08-25 陕西师范大学 基于二茂铁的双功能氢键有机催化剂及其制备方法和应用
CN104861001B (zh) * 2015-06-11 2017-08-04 河南省科学院化学研究所有限公司 一种二茂铁双膦配体的制备方法
US9725398B2 (en) * 2015-07-23 2017-08-08 Evonik Degussa Gmbh Benzene-based diphosphine ligands for alkoxycarbonylation
ES2732998T3 (es) * 2016-07-19 2019-11-27 Evonik Operations Gmbh Ligandos 1,1'-bis(fosfino)ferroceno para la alcoxicarbonilación
CN112824422B (zh) * 2019-11-21 2023-01-13 中国科学院大连化学物理研究所 一种手性二茂铁-吲哚双膦配体及其制备方法和其应用
CN114560893B (zh) * 2022-03-16 2024-02-06 中国科学院上海有机化学研究所 平面手性茂金属化合物、其合成方法及应用
CN116178455B (zh) * 2023-04-26 2023-08-18 江苏欣诺科催化剂股份有限公司 一种二茂铁类手性膦配体的制备方法

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG42938A1 (en) * 1993-02-26 1997-10-17 Ciba Geigy Ag Ferrocenc diphosphines as ligands for homogeneous catalysts
CA2122511A1 (en) * 1993-05-14 1994-11-15 John Mcgarrity Asymmetric hydrogenation of furoimidazole derivatives
DE59408655D1 (de) * 1993-10-01 1999-09-30 Novartis Ag Mit Fluoralkyl substituierte Ferrocenyldiphosphine als Liganden für homogene Katalysatoren
AU5499296A (en) * 1995-04-11 1996-10-30 Novartis Ag Dihalogenated ferrocenes and processes for the preparation hereof
ATE223925T1 (de) 1996-04-25 2002-09-15 Hoechst Ag 2,2'-disubstituierte 1,1'-diphosphino-ferrocene und 1',2-disubstituierte 1-phosphino-ferrocene, verfahren zu ihrer herstellung, ihre verwendung sowie sie enthaltende übergangsmetallkomplexe
CZ292412B6 (cs) 1996-10-07 2003-09-17 Syngenta Participations Ag Chirální ferocenylové sloučeniny, způsob jejich přípravy a jejich použití
EP0967015B1 (de) * 1998-06-19 2005-01-12 Degussa AG Verwendung von Ferrocenylliganden zur katalytischen enantioselektiven Hydrierung
DE19840279A1 (de) 1998-09-04 2000-03-09 Studiengesellschaft Kohle Mbh Neue chirale Diphosphonite auf Ferrocenbasis für die asymmetrische Katalyse
DE19952348A1 (de) * 1998-12-19 2000-06-21 Degussa Liganden und Komplexe zur enantioselektiven Hydrierung
US6258979B1 (en) * 1999-11-22 2001-07-10 Henri Kagan Chiral ferrocene phosphines active in asymmetric catalysis
US6194593B1 (en) * 2000-01-28 2001-02-27 Nippon Chemical Industrial Co., Ltd. 1, 2-bis(dialkylphosphino) benzene derivates having optical activites, process for producing same, and rhodium metal complexes containing same as ligands
AU2001236912A1 (en) * 2000-02-10 2001-08-20 The Penn State Research Foundation Chiral ferrocene phosphines and their use in asymmetric catalytic reactions
ATE312111T1 (de) * 2000-07-03 2005-12-15 Solvias Ag Ferrocenyl-diphosphane und ihre verwendung
US6590115B2 (en) * 2000-09-29 2003-07-08 Eastman Chemical Company Phosphino-aminophosphines
ES2316646T3 (es) * 2001-10-05 2009-04-16 Solvias Ag Ligandos para reacciones asimetricas.
DE10211250A1 (de) * 2002-03-13 2003-10-23 Degussa Ferrocenylliganden und ihre Verwendung in der Katalyse
DE10219490A1 (de) * 2002-04-30 2003-11-13 Degussa Ferrocenylliganden und ein Verfahren zur Herstellung solcher Liganden
GB0400720D0 (en) * 2004-01-14 2004-02-18 Stylacats Ltd Novel ferrocene-based phosphorus chiral phosphines
DE502005001692D1 (de) * 2004-07-05 2007-11-22 Solvias Ag 1,1'diphosphinoferrocene mit 2,2'-gebundenen achiralen oder chiralen resten

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109078653A (zh) * 2018-10-08 2018-12-25 浙江工业大学上虞研究院有限公司 手性二茂铁磷酸催化剂及其在不对称Friedel-Crafts反应中的应用

Also Published As

Publication number Publication date
ES2323717T3 (es) 2009-07-23
AU2005205224A1 (en) 2005-07-28
EP1709054A1 (en) 2006-10-11
AU2005205229A1 (en) 2005-07-28
CA2553607A1 (en) 2005-07-28
DE602005008917D1 (de) 2008-09-25
GB2410950A (en) 2005-08-17
JP2007517850A (ja) 2007-07-05
GB2410951B (en) 2009-07-22
GB2410951A (en) 2005-08-17
US7994355B2 (en) 2011-08-09
CN1914218A (zh) 2007-02-14
EP1725570B1 (en) 2008-08-13
GB2410950B (en) 2009-05-20
AU2005205229B2 (en) 2010-03-04
US20080281106A1 (en) 2008-11-13
WO2005068477A1 (en) 2005-07-28
EP1725570A1 (en) 2006-11-29
EP1709054B1 (en) 2009-03-04
CN1914217A (zh) 2007-02-14
GB0500704D0 (en) 2005-02-23
ATE424404T1 (de) 2009-03-15
ES2313282T3 (es) 2009-03-01
ATE404573T1 (de) 2008-08-15
US20070161762A1 (en) 2007-07-12
GB0905212D0 (en) 2009-05-13
GB0500701D0 (en) 2005-02-23
JP2007517849A (ja) 2007-07-05
DE602005013062D1 (de) 2009-04-16
CA2553608A1 (en) 2005-07-28
WO2005068478A1 (en) 2005-07-28
AU2005205224B2 (en) 2009-04-23

Similar Documents

Publication Publication Date Title
GB0905212D0 (en) Novel metallocene-based phosphorus chiral phosphines
Knight et al. Predetermination of chirality at octahedral centres with tetradentate ligands: prospects for enantioselective catalysis
Solà et al. N‐phosphino sulfinamide ligands: an efficient manner to combine sulfur chirality and phosphorus coordination behavior
IL127397A0 (en) Cyclic chiral phosphine ligands
ATE447020T1 (de) Ligationscodierung unter verwendung von oligonukleotidbausteinen
Kleman et al. Rh catalyzed asymmetric olefin hydrogenation: enamides, enol esters and beyond
MXPA04008152A (es) Compuestos azabiciclicos para el tratamiento de enfermedades.
CA2377069A1 (en) Synthesis of non-c2-symmetric bisphosphine ligands as catalysts for asymmetric hydrogenation
ATE372343T1 (de) Verfahren zur herstellung von 6-alkoxy-(6h)- dibenz(c,e)(1,2)-oxaphosphorinen
ATE289610T1 (de) Synthone zur herstellung von oligonukleotiden
ATE227262T1 (de) Perfluor-n-alkansulfonsäure-derivate
ATE211479T1 (de) Chirale ferrocene
AU2002218459A1 (en) P-chirale bisphospholane ligands, their transition metal complexes
Curnow et al. Synthesis and coordination chemistry of the tethered bis (cyclopentadienyl)-phosphine ligand precursor PPh (CH2CH2C5H5) 2: X-ray structure oftrans-PdCl2 [PPh (CH2CH2-η5-C5H4) 2Fe] 2
CA2399089A1 (en) Process for exchanging functional groups by halogen-metal exchange reaction
DE50113061D1 (de) Oberfläche zur immobilisierung von liganden
Perlikowska et al. Kinetic resolution of P-chiral tertiary phosphines and chlorophosphines: a new approach to optically active phosphoryl and thiophosphoryl compounds
DE60102587D1 (de) Chirale ligande für asymmetrische katalysatoren
WO2006081384A3 (en) Heterogeneous copper catalysts
DE50102861D1 (de) Cycloaliphatisch-aromatische diphosphine und ihre verwendung in der katalyse
EP1355912A1 (en) Ligands and their use
Marinetti et al. Synthesis and characterisation of monophosphines and aminophosphines bearing chiral phosphetane units
WO2004084834A3 (en) Chiral porous metal phosphonates for heterogeneous asymmetric catalysis
DE602004004894D1 (de) Verfahren zur rückgewinnung von phosphor aus phosphorproduktionsschlamm
Zirakzadeh et al. Synthesis of chiral, non-racemic ferrocene derivatives by ortho-metallation and partial reductive removal of ortho-directing amino groups

Legal Events

Date Code Title Description
AT Applications terminated before publication under section 16(1)