FR3113541B1 - Cellule au lithium solide, batterie comprenant lesdites cellules et procédé de fabrication pour fabriquer ladite batterie - Google Patents

Cellule au lithium solide, batterie comprenant lesdites cellules et procédé de fabrication pour fabriquer ladite batterie Download PDF

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Publication number
FR3113541B1
FR3113541B1 FR2008647A FR2008647A FR3113541B1 FR 3113541 B1 FR3113541 B1 FR 3113541B1 FR 2008647 A FR2008647 A FR 2008647A FR 2008647 A FR2008647 A FR 2008647A FR 3113541 B1 FR3113541 B1 FR 3113541B1
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France
Prior art keywords
battery
manufacturing
electrolyte
layer
solid lithium
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Active
Application number
FR2008647A
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English (en)
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FR3113541A1 (fr
Inventor
Mohamed Chakir
Akhil Dileep
Balaji Kalyanarangan
Madhumithaa Murali-A
Jayanth-Ramaswami Ramamurthy
Konda-Shiva Reddy
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Renault SAS
Original Assignee
Renault SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR2008647A priority Critical patent/FR3113541B1/fr
Application filed by Renault SAS filed Critical Renault SAS
Priority to PCT/EP2021/068652 priority patent/WO2022008506A1/fr
Priority to CN202180048069.XA priority patent/CN115836401A/zh
Priority to EP21737475.0A priority patent/EP4179582A1/fr
Priority to JP2022579026A priority patent/JP2023532438A/ja
Priority to US18/004,398 priority patent/US20230282887A1/en
Priority to KR1020237004972A priority patent/KR20230038258A/ko
Publication of FR3113541A1 publication Critical patent/FR3113541A1/fr
Application granted granted Critical
Publication of FR3113541B1 publication Critical patent/FR3113541B1/fr
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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0565—Polymeric materials, e.g. gel-type or solid-type
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/058—Construction or manufacture
    • H01M10/0585—Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0404—Methods of deposition of the material by coating on electrode collectors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0438—Processes of manufacture in general by electrochemical processing
    • H01M4/0459—Electrochemical doping, intercalation, occlusion or alloying
    • H01M4/0461—Electrochemical alloying
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/66—Selection of materials
    • H01M4/661—Metal or alloys, e.g. alloy coatings
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/70—Carriers or collectors characterised by shape or form
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/20—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
    • H01M50/204—Racks, modules or packs for multiple batteries or multiple cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/027—Negative electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Dispersion Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

Cellule au lithium solide formée par empilement d’un substrat de cuivre gravé (15), d’une couche de graphite (14), d’un électrolyte (12) et d’une couche d’oxydes de nickel, manganèse et cobalt (11), l’électrolyte (12) étant en contact avec la couche de graphite (14) et la couche d’oxydes de nickel, manganèse et cobalt (11), le substrat de cuivre (15) formant l’anode de la cellule, la couche d’oxydes de nickel, manganèse et cobalt (11) formant la cathode de la cellule, l’électrolyte (12) étant un électrolyte à base de lithium solide, et la couche de graphite (15) présentant une première interface d’électrolyte solide (16) réalisée pendant une pré-lithiation avec un électrolyte à base de lithium liquide et une deuxième interface d’électrolyte solide (17) réalisée pendant une pré-lithiation avec l’électrolyte à base de lithium solide. Figure pour l’abrégé : Fig 2
FR2008647A 2020-07-10 2020-08-24 Cellule au lithium solide, batterie comprenant lesdites cellules et procédé de fabrication pour fabriquer ladite batterie Active FR3113541B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR2008647A FR3113541B1 (fr) 2020-08-24 2020-08-24 Cellule au lithium solide, batterie comprenant lesdites cellules et procédé de fabrication pour fabriquer ladite batterie
CN202180048069.XA CN115836401A (zh) 2020-07-10 2021-07-06 固体锂电池单元、包含所述电池单元的电池以及用于制造所述电池的制造方法
EP21737475.0A EP4179582A1 (fr) 2020-07-10 2021-07-06 Cellule au lithium solide, batterie comprenant lesdites cellules et procédé de fabrication pour fabriquer ladite batterie
JP2022579026A JP2023532438A (ja) 2020-07-10 2021-07-06 固体リチウム電池セル、前記電池セルを備える電池、および前記電池を製造するための製造プロセス
PCT/EP2021/068652 WO2022008506A1 (fr) 2020-07-10 2021-07-06 Cellule au lithium solide, batterie comprenant lesdites cellules et procédé de fabrication pour fabriquer ladite batterie
US18/004,398 US20230282887A1 (en) 2020-07-10 2021-07-06 Solid lithium cell, battery comprising said cells and manufacturing process for manufacturing said battery
KR1020237004972A KR20230038258A (ko) 2020-07-10 2021-07-06 고체 리튬 셀, 상기 셀을 포함하는 배터리 및 상기 배터리를 제조하기 위한 제조 방법

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2008647A FR3113541B1 (fr) 2020-08-24 2020-08-24 Cellule au lithium solide, batterie comprenant lesdites cellules et procédé de fabrication pour fabriquer ladite batterie
FR2008647 2020-08-24

Publications (2)

Publication Number Publication Date
FR3113541A1 FR3113541A1 (fr) 2022-02-25
FR3113541B1 true FR3113541B1 (fr) 2022-11-25

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FR2008647A Active FR3113541B1 (fr) 2020-07-10 2020-08-24 Cellule au lithium solide, batterie comprenant lesdites cellules et procédé de fabrication pour fabriquer ladite batterie

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Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5759715A (en) 1995-09-26 1998-06-02 Valence Technology, Inc. Lithium ion batteries containing pre-lithiated electrodes
WO2004036668A2 (fr) * 2002-10-17 2004-04-29 Tel-Aviv University Future Technology Development L.P. Cathode a film mince pour micropile tridimensionnelle et procede de preparation de ladite cathode
US20160172710A1 (en) * 2014-12-10 2016-06-16 The Regents Of The University Of California Electrolyte and negative electrode structure
CN110010964B (zh) * 2018-01-04 2020-12-22 中国科学院苏州纳米技术与纳米仿生研究所 多孔膜增强的聚合物-塑晶固体电解质膜、其制法与应用
PL3793005T3 (pl) * 2018-09-12 2023-03-20 Lg Energy Solution, Ltd. Sposób wytwarzania elektrody ujemnej dla akumulatora litowego i akumulator litowy
CN109841796B (zh) * 2019-02-27 2021-01-12 中国第一汽车股份有限公司 电极制备方法及电池
CN111224154B (zh) * 2020-02-17 2021-09-10 中国科学院化学研究所 一种具有锂离子传导的介孔纳米粒子凝胶复合电解质及其制备方法与应用
CN111525184B (zh) * 2020-03-25 2022-11-11 东华大学 一种复合固态电解质薄膜及其制备和应用

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Publication number Publication date
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