FR3108907B1 - Matériaux élastiques préparés à partir de compositions liquides durcissables par énergie - Google Patents

Matériaux élastiques préparés à partir de compositions liquides durcissables par énergie Download PDF

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Publication number
FR3108907B1
FR3108907B1 FR2003255A FR2003255A FR3108907B1 FR 3108907 B1 FR3108907 B1 FR 3108907B1 FR 2003255 A FR2003255 A FR 2003255A FR 2003255 A FR2003255 A FR 2003255A FR 3108907 B1 FR3108907 B1 FR 3108907B1
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FR
France
Prior art keywords
meth
acrylate
astm
molecular weight
per molecule
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR2003255A
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English (en)
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FR3108907A1 (fr
Inventor
Zackariah Weinert
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Original Assignee
Arkema France SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR2003255A priority Critical patent/FR3108907B1/fr
Application filed by Arkema France SA filed Critical Arkema France SA
Priority to PCT/EP2021/058550 priority patent/WO2021198398A1/fr
Priority to EP21714917.8A priority patent/EP4127004A1/fr
Priority to KR1020227037938A priority patent/KR20220162759A/ko
Priority to TW110112209A priority patent/TWI832041B/zh
Priority to CN202180039373.8A priority patent/CN115768807A/zh
Priority to JP2022560098A priority patent/JP2023520232A/ja
Priority to US17/915,178 priority patent/US20230124643A1/en
Publication of FR3108907A1 publication Critical patent/FR3108907A1/fr
Application granted granted Critical
Publication of FR3108907B1 publication Critical patent/FR3108907B1/fr
Priority to IL296891A priority patent/IL296891A/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06—Polymers provided for in subclass C08G
    • C08F290/067—Polyurethanes; Polyureas
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/281—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing only one oxygen, e.g. furfuryl (meth)acrylate or 2-methoxyethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/285—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing a polyether chain in the alcohol moiety
    • C08F220/286—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing a polyether chain in the alcohol moiety and containing polyethylene oxide in the alcohol moiety, e.g. methoxy polyethylene glycol (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
    • C08F220/343—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate in the form of urethane links
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4825—Polyethers containing two hydroxy groups

Abstract

Un matériau élastique est obtenu présentant une élongation supérieure à 150 % telle que mesurée selon la norme ASTM D638–02a, une résilience supérieure à 12 % telle que mesurée selon la norme ASTM D2632–01 (réapprouvée en 2008), et une dureté Shore A d’au moins 10 telle que mesurée selon la norme ASTM D2240–15e1. Le matériau élastique est un produit de réaction durci par énergie d’une composition durcissable qui est un liquide à 25 °C.La composition durcissable comprend au moins a) un oligomère fonctionnalisé par (méth)acrylate à masse moléculaire relativement élevée n’ayant pas plus de deux groupes fonctionnels (méth)acrylate par molécule en moyenne ; b) au moins un monomère fonctionnalisé par mono(méth)acrylate ayant une masse moléculaire inférieure à 500 Daltons et un unique groupe fonctionnel (méth)acrylate par molécule ; et c) au moins un monomère fonctionnalisé par multi(méth)acrylate ayant une masse moléculaire inférieure à 1 000 Daltons et au moins deux groupes fonctionnels (méth)acrylate par molécule.
FR2003255A 2020-04-01 2020-04-01 Matériaux élastiques préparés à partir de compositions liquides durcissables par énergie Active FR3108907B1 (fr)

Priority Applications (9)

Application Number Priority Date Filing Date Title
FR2003255A FR3108907B1 (fr) 2020-04-01 2020-04-01 Matériaux élastiques préparés à partir de compositions liquides durcissables par énergie
EP21714917.8A EP4127004A1 (fr) 2020-04-01 2021-04-01 Matériaux élastiques préparés à partir de compositions liquides durcissables par énergie
KR1020227037938A KR20220162759A (ko) 2020-04-01 2021-04-01 에너지-경화 가능한 액체 조성물로부터 제조된 탄성 물질
TW110112209A TWI832041B (zh) 2020-04-01 2021-04-01 從可能量固化的液體組成物製備之彈性材料及製備其之方法
PCT/EP2021/058550 WO2021198398A1 (fr) 2020-04-01 2021-04-01 Matériaux élastiques préparés à partir de compositions liquides durcissables par énergie
CN202180039373.8A CN115768807A (zh) 2020-04-01 2021-04-01 由能量固化性液体组合物制备的弹性材料
JP2022560098A JP2023520232A (ja) 2020-04-01 2021-04-01 エネルギー硬化性液体組成物から調製された弾性材料
US17/915,178 US20230124643A1 (en) 2020-04-01 2021-04-01 Elastic materials prepared from energy-curable liquid compositions
IL296891A IL296891A (en) 2020-04-01 2022-09-29 Elastic materials prepared from energy curable liquid compositions

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2003255 2020-04-01
FR2003255A FR3108907B1 (fr) 2020-04-01 2020-04-01 Matériaux élastiques préparés à partir de compositions liquides durcissables par énergie

Publications (2)

Publication Number Publication Date
FR3108907A1 FR3108907A1 (fr) 2021-10-08
FR3108907B1 true FR3108907B1 (fr) 2022-07-08

Family

ID=72088215

Family Applications (1)

Application Number Title Priority Date Filing Date
FR2003255A Active FR3108907B1 (fr) 2020-04-01 2020-04-01 Matériaux élastiques préparés à partir de compositions liquides durcissables par énergie

Country Status (8)

Country Link
US (1) US20230124643A1 (fr)
EP (1) EP4127004A1 (fr)
JP (1) JP2023520232A (fr)
KR (1) KR20220162759A (fr)
CN (1) CN115768807A (fr)
FR (1) FR3108907B1 (fr)
IL (1) IL296891A (fr)
WO (1) WO2021198398A1 (fr)

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5268396A (en) 1990-11-02 1993-12-07 Lai Juey H Organosilicon soft denture liners
EP0973815B1 (fr) 1997-04-08 2003-10-22 DSM IP Assets B.V. Compositions de liant durcissant sous l'effet de rayons et demontrant apres durcissement un fort allongement et une grande tenacite
US6214522B1 (en) * 1998-08-28 2001-04-10 Macdermid, Incorporated Photosensitive resin composition useful in fabricating printing plates
US7198576B2 (en) 2003-06-17 2007-04-03 Acushnet Company Golf ball comprising UV-cured non-surface layer
JPWO2007129704A1 (ja) * 2006-05-08 2009-09-17 旭化成イーマテリアルズ株式会社 印刷用クッション材料
JP5649292B2 (ja) 2009-08-25 2015-01-07 株式会社ブリヂストン エネルギー線硬化型エラストマー組成物
WO2014126830A2 (fr) 2013-02-12 2014-08-21 Eipi Systems, Inc. Procédé et appareil pour fabrication en trois dimensions
MX352989B (es) 2013-02-12 2017-12-14 Carbon3D Inc Impresión de interfase líquida continua.

Also Published As

Publication number Publication date
WO2021198398A1 (fr) 2021-10-07
US20230124643A1 (en) 2023-04-20
KR20220162759A (ko) 2022-12-08
JP2023520232A (ja) 2023-05-16
TW202146565A (zh) 2021-12-16
EP4127004A1 (fr) 2023-02-08
IL296891A (en) 2022-12-01
CN115768807A (zh) 2023-03-07
FR3108907A1 (fr) 2021-10-08

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