FR3108532B1 - Production d’alcool allylique à partir de glycérol en utilisant un catalyseur réutilisable à base de rhénium - Google Patents

Production d’alcool allylique à partir de glycérol en utilisant un catalyseur réutilisable à base de rhénium Download PDF

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Publication number
FR3108532B1
FR3108532B1 FR2003019A FR2003019A FR3108532B1 FR 3108532 B1 FR3108532 B1 FR 3108532B1 FR 2003019 A FR2003019 A FR 2003019A FR 2003019 A FR2003019 A FR 2003019A FR 3108532 B1 FR3108532 B1 FR 3108532B1
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France
Prior art keywords
glycerol
rhenium
allyl alcohol
reusable
production
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR2003019A
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English (en)
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FR3108532A1 (fr
Inventor
Benjamin Katryniok
Karen Silva
Marcia Araque
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
Universite Lille 2 Droit et Sante
Ecole Centrale de Lille
Original Assignee
Centre National de la Recherche Scientifique CNRS
Universite Lille 2 Droit et Sante
Ecole Centrale de Lille
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centre National de la Recherche Scientifique CNRS, Universite Lille 2 Droit et Sante, Ecole Centrale de Lille filed Critical Centre National de la Recherche Scientifique CNRS
Priority to FR2003019A priority Critical patent/FR3108532B1/fr
Priority to PCT/EP2021/057525 priority patent/WO2021191249A1/fr
Priority to EP21713045.9A priority patent/EP4126347A1/fr
Priority to US17/907,359 priority patent/US20230112595A1/en
Publication of FR3108532A1 publication Critical patent/FR3108532A1/fr
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Publication of FR3108532B1 publication Critical patent/FR3108532B1/fr
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/36—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

P roduction d’alcool allylique à partir de glycérol en utilisant un catalyseur réutilisable à base de rhénium La présente invention se rapporte à l’utilisation d'un catalyseur à base d'oxyde de rhénium supporté par de l’oxyde de cérium de formule ReOx/CeO2 (I), pour catalyser la désoxydéshydratation du glycérol en alcool allylique, ladite réaction étant effectuée dans des conditions hétérogènes en présence d'au moins un alcool aliphatique ; ainsi qu’à un procédé de production d'alcool allylique à partir de glycérol en présence dudit catalyseur. Figure pour l'abrégé : néant
FR2003019A 2020-03-27 2020-03-27 Production d’alcool allylique à partir de glycérol en utilisant un catalyseur réutilisable à base de rhénium Active FR3108532B1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
FR2003019A FR3108532B1 (fr) 2020-03-27 2020-03-27 Production d’alcool allylique à partir de glycérol en utilisant un catalyseur réutilisable à base de rhénium
PCT/EP2021/057525 WO2021191249A1 (fr) 2020-03-27 2021-03-24 Production d'alcool allylique à partir de glycérol en utilisant un catalyseur réutilisable à base de rhénium
EP21713045.9A EP4126347A1 (fr) 2020-03-27 2021-03-24 Production d'alcool allylique à partir de glycérol en utilisant un catalyseur réutilisable à base de rhénium
US17/907,359 US20230112595A1 (en) 2020-03-27 2021-03-24 Production of allyl alcohol from glycerol using a reusable catalyst made from rhenium

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2003019A FR3108532B1 (fr) 2020-03-27 2020-03-27 Production d’alcool allylique à partir de glycérol en utilisant un catalyseur réutilisable à base de rhénium
FR2003019 2020-03-27

Publications (2)

Publication Number Publication Date
FR3108532A1 FR3108532A1 (fr) 2021-10-01
FR3108532B1 true FR3108532B1 (fr) 2022-03-04

Family

ID=70978183

Family Applications (1)

Application Number Title Priority Date Filing Date
FR2003019A Active FR3108532B1 (fr) 2020-03-27 2020-03-27 Production d’alcool allylique à partir de glycérol en utilisant un catalyseur réutilisable à base de rhénium

Country Status (4)

Country Link
US (1) US20230112595A1 (fr)
EP (1) EP4126347A1 (fr)
FR (1) FR3108532B1 (fr)
WO (1) WO2021191249A1 (fr)

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3124462B1 (fr) 2015-07-30 2019-01-30 Centre National De La Recherche Scientifique Utilisation de catalyseurs supportés hétérogènes contenant du rhénium pour la deoxydehydration directe de glycérol en alcool allylique

Also Published As

Publication number Publication date
US20230112595A1 (en) 2023-04-13
WO2021191249A1 (fr) 2021-09-30
FR3108532A1 (fr) 2021-10-01
EP4126347A1 (fr) 2023-02-08

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