FR3108532B1 - Production d’alcool allylique à partir de glycérol en utilisant un catalyseur réutilisable à base de rhénium - Google Patents
Production d’alcool allylique à partir de glycérol en utilisant un catalyseur réutilisable à base de rhénium Download PDFInfo
- Publication number
- FR3108532B1 FR3108532B1 FR2003019A FR2003019A FR3108532B1 FR 3108532 B1 FR3108532 B1 FR 3108532B1 FR 2003019 A FR2003019 A FR 2003019A FR 2003019 A FR2003019 A FR 2003019A FR 3108532 B1 FR3108532 B1 FR 3108532B1
- Authority
- FR
- France
- Prior art keywords
- glycerol
- rhenium
- allyl alcohol
- reusable
- production
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 title abstract 12
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 title abstract 8
- 239000003054 catalyst Substances 0.000 title abstract 4
- 229910052702 rhenium Inorganic materials 0.000 title abstract 2
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 title abstract 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 1
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 abstract 1
- 229910000420 cerium oxide Inorganic materials 0.000 abstract 1
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 abstract 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 abstract 1
- DYIZHKNUQPHNJY-UHFFFAOYSA-N oxorhenium Chemical compound [Re]=O DYIZHKNUQPHNJY-UHFFFAOYSA-N 0.000 abstract 1
- 229910003449 rhenium oxide Inorganic materials 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/32—Manganese, technetium or rhenium
- B01J23/36—Rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/082—Decomposition and pyrolysis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/082—Decomposition and pyrolysis
- B01J37/088—Decomposition of a metal salt
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
P roduction d’alcool allylique à partir de glycérol en utilisant un catalyseur réutilisable à base de rhénium La présente invention se rapporte à l’utilisation d'un catalyseur à base d'oxyde de rhénium supporté par de l’oxyde de cérium de formule ReOx/CeO2 (I), pour catalyser la désoxydéshydratation du glycérol en alcool allylique, ladite réaction étant effectuée dans des conditions hétérogènes en présence d'au moins un alcool aliphatique ; ainsi qu’à un procédé de production d'alcool allylique à partir de glycérol en présence dudit catalyseur. Figure pour l'abrégé : néant
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR2003019A FR3108532B1 (fr) | 2020-03-27 | 2020-03-27 | Production d’alcool allylique à partir de glycérol en utilisant un catalyseur réutilisable à base de rhénium |
PCT/EP2021/057525 WO2021191249A1 (fr) | 2020-03-27 | 2021-03-24 | Production d'alcool allylique à partir de glycérol en utilisant un catalyseur réutilisable à base de rhénium |
EP21713045.9A EP4126347A1 (fr) | 2020-03-27 | 2021-03-24 | Production d'alcool allylique à partir de glycérol en utilisant un catalyseur réutilisable à base de rhénium |
US17/907,359 US20230112595A1 (en) | 2020-03-27 | 2021-03-24 | Production of allyl alcohol from glycerol using a reusable catalyst made from rhenium |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR2003019A FR3108532B1 (fr) | 2020-03-27 | 2020-03-27 | Production d’alcool allylique à partir de glycérol en utilisant un catalyseur réutilisable à base de rhénium |
FR2003019 | 2020-03-27 |
Publications (2)
Publication Number | Publication Date |
---|---|
FR3108532A1 FR3108532A1 (fr) | 2021-10-01 |
FR3108532B1 true FR3108532B1 (fr) | 2022-03-04 |
Family
ID=70978183
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR2003019A Active FR3108532B1 (fr) | 2020-03-27 | 2020-03-27 | Production d’alcool allylique à partir de glycérol en utilisant un catalyseur réutilisable à base de rhénium |
Country Status (4)
Country | Link |
---|---|
US (1) | US20230112595A1 (fr) |
EP (1) | EP4126347A1 (fr) |
FR (1) | FR3108532B1 (fr) |
WO (1) | WO2021191249A1 (fr) |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3124462B1 (fr) | 2015-07-30 | 2019-01-30 | Centre National De La Recherche Scientifique | Utilisation de catalyseurs supportés hétérogènes contenant du rhénium pour la deoxydehydration directe de glycérol en alcool allylique |
-
2020
- 2020-03-27 FR FR2003019A patent/FR3108532B1/fr active Active
-
2021
- 2021-03-24 EP EP21713045.9A patent/EP4126347A1/fr active Pending
- 2021-03-24 WO PCT/EP2021/057525 patent/WO2021191249A1/fr active Application Filing
- 2021-03-24 US US17/907,359 patent/US20230112595A1/en active Pending
Also Published As
Publication number | Publication date |
---|---|
US20230112595A1 (en) | 2023-04-13 |
WO2021191249A1 (fr) | 2021-09-30 |
FR3108532A1 (fr) | 2021-10-01 |
EP4126347A1 (fr) | 2023-02-08 |
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