FR3103817B1 - Composition comprenant un polymère à étapes multiples et un polymère (méth)acrylique, son procédé de préparation et son utilisation - Google Patents

Composition comprenant un polymère à étapes multiples et un polymère (méth)acrylique, son procédé de préparation et son utilisation Download PDF

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Publication number
FR3103817B1
FR3103817B1 FR1913528A FR1913528A FR3103817B1 FR 3103817 B1 FR3103817 B1 FR 3103817B1 FR 1913528 A FR1913528 A FR 1913528A FR 1913528 A FR1913528 A FR 1913528A FR 3103817 B1 FR3103817 B1 FR 3103817B1
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Prior art keywords
polymer
meth
composition
preparation
multistage
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FR1913528A
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English (en)
French (fr)
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FR3103817A1 (fr
Inventor
Aline Couffin
Philippe Hajji
Alexandre Vermogen
Elisabeth Bay
Jean-Claude Saint-Martin
Vinciane Chartois
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Arkema France SA
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Arkema France SA
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Priority to FR1913528A priority Critical patent/FR3103817B1/fr
Application filed by Arkema France SA filed Critical Arkema France SA
Priority to AU2020394556A priority patent/AU2020394556A1/en
Priority to JP2022530753A priority patent/JP2023503984A/ja
Priority to PCT/EP2020/083957 priority patent/WO2021105508A1/en
Priority to US17/777,293 priority patent/US20220411544A1/en
Priority to CN202080094835.1A priority patent/CN114981328B/zh
Priority to KR1020227021359A priority patent/KR20220111287A/ko
Priority to EP20812067.5A priority patent/EP4065620A1/en
Publication of FR3103817A1 publication Critical patent/FR3103817A1/fr
Application granted granted Critical
Publication of FR3103817B1 publication Critical patent/FR3103817B1/fr
Priority to JP2025193989A priority patent/JP2026035638A/ja
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F36/06Butadiene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C08F265/06Polymerisation of acrylate or methacrylate esters on to polymers thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/12Polymerisation in non-solvents
    • C08F2/16Aqueous medium
    • C08F2/22Emulsion polymerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/04Acids, Metal salts or ammonium salts thereof
    • C08F20/06Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/14Methyl esters, e.g. methyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10Homopolymers or copolymers of methacrylic acid esters
    • C08L33/12Homopolymers or copolymers of methyl methacrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/18Bulk density
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/24Polymer with special particle form or size
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/32Glass transition temperature [Tg]

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Graft Or Block Polymers (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
FR1913528A 2019-11-29 2019-11-29 Composition comprenant un polymère à étapes multiples et un polymère (méth)acrylique, son procédé de préparation et son utilisation Active FR3103817B1 (fr)

Priority Applications (9)

Application Number Priority Date Filing Date Title
FR1913528A FR3103817B1 (fr) 2019-11-29 2019-11-29 Composition comprenant un polymère à étapes multiples et un polymère (méth)acrylique, son procédé de préparation et son utilisation
JP2022530753A JP2023503984A (ja) 2019-11-29 2020-11-30 多段ポリマー及び(メタ)アクリル系ポリマーを含む組成物、その調製方法並びにその使用
PCT/EP2020/083957 WO2021105508A1 (en) 2019-11-29 2020-11-30 Composition comprising a multistage polymer and a (meth)acrylic polymer, its method of preparation and its use
US17/777,293 US20220411544A1 (en) 2019-11-29 2020-11-30 Composition comprising a multistage polymer and a (meth)acrylic polymer, its method of preparation and its use
AU2020394556A AU2020394556A1 (en) 2019-11-29 2020-11-30 Composition comprising a multistage polymer and a (meth)acrylic polymer, its method of preparation and its use
CN202080094835.1A CN114981328B (zh) 2019-11-29 2020-11-30 包含多级聚合物和(甲基)丙烯酸类聚合物的组合物、其制备方法及其用途
KR1020227021359A KR20220111287A (ko) 2019-11-29 2020-11-30 다단 중합체 및 (메트)아크릴 중합체를 포함하는 조성물, 이의 제조 방법 및 이의 용도
EP20812067.5A EP4065620A1 (en) 2019-11-29 2020-11-30 Composition comprising a multistage polymer and a (meth)acrylic polymer, its method of preparation and its use
JP2025193989A JP2026035638A (ja) 2019-11-29 2025-11-13 多段ポリマー及び(メタ)アクリル系ポリマーを含む組成物、その調製方法並びにその使用

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1913528A FR3103817B1 (fr) 2019-11-29 2019-11-29 Composition comprenant un polymère à étapes multiples et un polymère (méth)acrylique, son procédé de préparation et son utilisation
FR1913528 2019-11-29

Publications (2)

Publication Number Publication Date
FR3103817A1 FR3103817A1 (fr) 2021-06-04
FR3103817B1 true FR3103817B1 (fr) 2021-12-17

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FR1913528A Active FR3103817B1 (fr) 2019-11-29 2019-11-29 Composition comprenant un polymère à étapes multiples et un polymère (méth)acrylique, son procédé de préparation et son utilisation

Country Status (8)

Country Link
US (1) US20220411544A1 (https=)
EP (1) EP4065620A1 (https=)
JP (2) JP2023503984A (https=)
KR (1) KR20220111287A (https=)
CN (1) CN114981328B (https=)
AU (1) AU2020394556A1 (https=)
FR (1) FR3103817B1 (https=)
WO (1) WO2021105508A1 (https=)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11867114B2 (en) 2020-10-16 2024-01-09 Vianney Rabhi Guide stud valve
EP4393963A1 (en) * 2022-12-31 2024-07-03 Arkema France Methods for preparing multistage polymer particle compositions and curable formulations for three-dimensional printing

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE18570T1 (de) 1981-06-02 1986-03-15 Rohm & Haas Freifliessbare teilchen eines schlagfestigkeitsmodifikators, verfahren zu ihrer herstellung und sie enthaltende mischungen.
JP3217225B2 (ja) * 1995-01-13 2001-10-09 三菱レイヨン株式会社 アクリル系多層構造ポリマー粉体
JP2983958B2 (ja) * 1998-05-12 1999-11-29 三菱レイヨン株式会社 耐衝撃性アクリル系重合体の製造方法
US8222324B2 (en) 2003-06-09 2012-07-17 Kaneka Corporation Process for producing modified epoxy resin
US7485680B2 (en) 2003-09-18 2009-02-03 Kaneka Corporation Process for producing rubbery polymer particle and process for producing resin composition containing the same
JP2005146139A (ja) * 2003-11-17 2005-06-09 Kuraray Co Ltd アクリル系重合体粉末、アクリルゾル及び成形物
JP2006306961A (ja) * 2005-04-27 2006-11-09 Mitsubishi Rayon Co Ltd アクリル系多層構造重合体混合粉末、その製造方法および樹脂組成物
EP2123711B1 (en) 2007-02-28 2016-12-14 Kaneka Corporation Thermosetting resin composition having rubbery polymer particle dispersed therein, and process for production thereof
JP5372765B2 (ja) * 2007-10-11 2013-12-18 株式会社クレハ フッ化ビニリデン系ポリマー粉体及びその利用
FR2934866B1 (fr) 2008-08-05 2012-12-28 Arkema France Particules de type "coeur-ecorce" comprenant une ecorce a base de monomeres hydrophiles.
FR2969158B1 (fr) * 2010-12-15 2013-01-18 Arkema France Procede pour modifiants chocs et composition thermoplastique modifiee choc ayant une resistance hydrolytique amelioree
FR3031108B1 (fr) 2014-12-24 2018-08-17 Arkema France Composition comprenant un polymere a phases multiples, son procede de preparation et son utlisation
FR3031106B1 (fr) 2014-12-24 2017-02-03 Arkema France Composition de polymeres a phases multiples, son procede de preparation, son utilisation et composition la comprenant
FR3053349B1 (fr) * 2016-06-29 2020-06-19 Arkema France Composition comprenant un polymere thermoplastique, un polymere a phases multiples et un polymere (meth)acrylique, son procede de preparation et son utilisation
FR3068977B1 (fr) 2017-07-12 2020-09-04 Arkema France Composition comprenant un polymere a phases multiples et un polymere (meth)acrylique, son procede de preparation et son utilisation
JP2020526635A (ja) * 2017-07-12 2020-08-31 ヘクセル コンポジッツ、リミテッド 樹脂組成物

Also Published As

Publication number Publication date
JP2023503984A (ja) 2023-02-01
WO2021105508A1 (en) 2021-06-03
AU2020394556A1 (en) 2022-05-26
US20220411544A1 (en) 2022-12-29
CN114981328B (zh) 2025-07-08
FR3103817A1 (fr) 2021-06-04
EP4065620A1 (en) 2022-10-05
JP2026035638A (ja) 2026-03-04
KR20220111287A (ko) 2022-08-09
CN114981328A (zh) 2022-08-30

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