FR3103817B1 - Composition comprenant un polymère à étapes multiples et un polymère (méth)acrylique, son procédé de préparation et son utilisation - Google Patents

Composition comprenant un polymère à étapes multiples et un polymère (méth)acrylique, son procédé de préparation et son utilisation Download PDF

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Publication number
FR3103817B1
FR3103817B1 FR1913528A FR1913528A FR3103817B1 FR 3103817 B1 FR3103817 B1 FR 3103817B1 FR 1913528 A FR1913528 A FR 1913528A FR 1913528 A FR1913528 A FR 1913528A FR 3103817 B1 FR3103817 B1 FR 3103817B1
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France
Prior art keywords
polymer
meth
composition
preparation
multistage
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FR1913528A
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English (en)
French (fr)
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FR3103817A1 (fr
Inventor
Aline Couffin
Philippe Hajji
Alexandre Vermogen
Elisabeth Bay
Jean-Claude Saint-Martin
Vinciane Chartois
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Arkema France SA
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Arkema France SA
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Priority to FR1913528A priority Critical patent/FR3103817B1/fr
Application filed by Arkema France SA filed Critical Arkema France SA
Priority to JP2022530753A priority patent/JP2023503984A/ja
Priority to EP20812067.5A priority patent/EP4065620A1/en
Priority to AU2020394556A priority patent/AU2020394556A1/en
Priority to CN202080094835.1A priority patent/CN114981328B/zh
Priority to KR1020227021359A priority patent/KR20220111287A/ko
Priority to US17/777,293 priority patent/US12643965B2/en
Priority to PCT/EP2020/083957 priority patent/WO2021105508A1/en
Publication of FR3103817A1 publication Critical patent/FR3103817A1/fr
Application granted granted Critical
Publication of FR3103817B1 publication Critical patent/FR3103817B1/fr
Priority to JP2025193989A priority patent/JP2026035638A/ja
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F36/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/04—Acids, Metal salts or ammonium salts thereof
    • C08F20/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10—Homopolymers or copolymers of methacrylic acid esters
    • C08L33/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/18—Bulk density
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/24—Polymer with special particle form or size
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/32—Glass transition temperature [Tg]

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Graft Or Block Polymers (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
FR1913528A 2019-11-29 2019-11-29 Composition comprenant un polymère à étapes multiples et un polymère (méth)acrylique, son procédé de préparation et son utilisation Active FR3103817B1 (fr)

Priority Applications (9)

Application Number Priority Date Filing Date Title
FR1913528A FR3103817B1 (fr) 2019-11-29 2019-11-29 Composition comprenant un polymère à étapes multiples et un polymère (méth)acrylique, son procédé de préparation et son utilisation
EP20812067.5A EP4065620A1 (en) 2019-11-29 2020-11-30 Composition comprising a multistage polymer and a (meth)acrylic polymer, its method of preparation and its use
AU2020394556A AU2020394556A1 (en) 2019-11-29 2020-11-30 Composition comprising a multistage polymer and a (meth)acrylic polymer, its method of preparation and its use
CN202080094835.1A CN114981328B (zh) 2019-11-29 2020-11-30 包含多级聚合物和(甲基)丙烯酸类聚合物的组合物、其制备方法及其用途
JP2022530753A JP2023503984A (ja) 2019-11-29 2020-11-30 多段ポリマー及び（メタ）アクリル系ポリマーを含む組成物、その調製方法並びにその使用
KR1020227021359A KR20220111287A (ko) 2019-11-29 2020-11-30 다단 중합체 및 (메트)아크릴 중합체를 포함하는 조성물, 이의 제조 방법 및 이의 용도
US17/777,293 US12643965B2 (en) 2019-11-29 2020-11-30 Composition comprising a multistage polymer and a (meth)acrylic polymer, its method of preparation and its use
PCT/EP2020/083957 WO2021105508A1 (en) 2019-11-29 2020-11-30 Composition comprising a multistage polymer and a (meth)acrylic polymer, its method of preparation and its use
JP2025193989A JP2026035638A (ja) 2019-11-29 2025-11-13 多段ポリマー及び（メタ）アクリル系ポリマーを含む組成物、その調製方法並びにその使用

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1913528 2019-11-29
FR1913528A FR3103817B1 (fr) 2019-11-29 2019-11-29 Composition comprenant un polymère à étapes multiples et un polymère (méth)acrylique, son procédé de préparation et son utilisation

Publications (2)

Publication Number Publication Date
FR3103817A1 FR3103817A1 (fr) 2021-06-04
FR3103817B1 true FR3103817B1 (fr) 2021-12-17

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FR1913528A Active FR3103817B1 (fr) 2019-11-29 2019-11-29 Composition comprenant un polymère à étapes multiples et un polymère (méth)acrylique, son procédé de préparation et son utilisation

Country Status (8)

Country Link
US (1) US12643965B2 (enExample)
EP (1) EP4065620A1 (enExample)
JP (2) JP2023503984A (enExample)
KR (1) KR20220111287A (enExample)
CN (1) CN114981328B (enExample)
AU (1) AU2020394556A1 (enExample)
FR (1) FR3103817B1 (enExample)
WO (1) WO2021105508A1 (enExample)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11867114B2 (en) 2020-10-16 2024-01-09 Vianney Rabhi Guide stud valve
EP4393963A1 (en) * 2022-12-31 2024-07-03 Arkema France Methods for preparing multistage polymer particle compositions and curable formulations for three-dimensional printing

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0066382B1 (en) 1981-06-01 1986-03-12 Rohm And Haas Company Bulk flowable impact modifier particles, processes for making them and compositions containing them
US4463131A (en) 1981-06-02 1984-07-31 Rohm And Haas Company Bulk flowable impact modifiers
US4620874A (en) 1984-06-28 1986-11-04 Btl Specialty Resins Corporation Metal modified phenolic resin color developers
JP3217225B2 (ja) * 1995-01-13 2001-10-09 三菱レイヨン株式会社 アクリル系多層構造ポリマー粉体
JP2983958B2 (ja) * 1998-05-12 1999-11-29 三菱レイヨン株式会社 耐衝撃性アクリル系重合体の製造方法
CN100427543C (zh) 2003-01-21 2008-10-22 株式会社可乐丽 丙烯酸类聚合物粉末、丙烯酸溶胶以及成形物
US8222324B2 (en) 2003-06-09 2012-07-17 Kaneka Corporation Process for producing modified epoxy resin
AU2004274270A1 (en) 2003-09-18 2005-03-31 Kaneka Corporation Process for producing rubbery polymer particle and process for producing resin composition containing the same
JP2005146139A (ja) * 2003-11-17 2005-06-09 Kuraray Co Ltd アクリル系重合体粉末、アクリルゾル及び成形物
JP2006306961A (ja) * 2005-04-27 2006-11-09 Mitsubishi Rayon Co Ltd アクリル系多層構造重合体混合粉末、その製造方法および樹脂組成物
JP5544162B2 (ja) 2007-02-28 2014-07-09 株式会社カネカ ゴム状重合体粒子分散熱硬化性樹脂組成物、及びその製造方法
JP5372765B2 (ja) * 2007-10-11 2013-12-18 株式会社クレハ フッ化ビニリデン系ポリマー粉体及びその利用
FR2934866B1 (fr) 2008-08-05 2012-12-28 Arkema France Particules de type "coeur-ecorce" comprenant une ecorce a base de monomeres hydrophiles.
FR2969158B1 (fr) * 2010-12-15 2013-01-18 Arkema France Procede pour modifiants chocs et composition thermoplastique modifiee choc ayant une resistance hydrolytique amelioree
FR3031108B1 (fr) 2014-12-24 2018-08-17 Arkema France Composition comprenant un polymere a phases multiples, son procede de preparation et son utlisation
FR3031106B1 (fr) 2014-12-24 2017-02-03 Arkema France Composition de polymeres a phases multiples, son procede de preparation, son utilisation et composition la comprenant
WO2016130734A1 (en) 2015-02-11 2016-08-18 Bristol-Myers Squibb Company Use of phenolic antioxidants in cell culture for the production of proteins
FR3046605B1 (fr) 2016-01-11 2019-09-06 Arkema France Composition liquide comprenant un polymere a phases multiples, son procede de preparation et son utilisation
FR3053349B1 (fr) * 2016-06-29 2020-06-19 Arkema France Composition comprenant un polymere thermoplastique, un polymere a phases multiples et un polymere (meth)acrylique, son procede de preparation et son utilisation
WO2019011984A1 (en) * 2017-07-12 2019-01-17 Hexcel Composites Limited RESIN COMPOSITION
FR3068977B1 (fr) 2017-07-12 2020-09-04 Arkema France Composition comprenant un polymere a phases multiples et un polymere (meth)acrylique, son procede de preparation et son utilisation

Also Published As

Publication number Publication date
KR20220111287A (ko) 2022-08-09
CN114981328A (zh) 2022-08-30
US20220411544A1 (en) 2022-12-29
JP2023503984A (ja) 2023-02-01
FR3103817A1 (fr) 2021-06-04
JP2026035638A (ja) 2026-03-04
AU2020394556A1 (en) 2022-05-26
EP4065620A1 (en) 2022-10-05
WO2021105508A1 (en) 2021-06-03
US12643965B2 (en) 2026-06-02
CN114981328B (zh) 2025-07-08

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