FR3089356B1 - Cathode pour accumulateur électrochimique, accumulateur, dispositif de stockage d’énergie et procédé de fabrication associés - Google Patents

Cathode pour accumulateur électrochimique, accumulateur, dispositif de stockage d’énergie et procédé de fabrication associés Download PDF

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Publication number
FR3089356B1
FR3089356B1 FR1872042A FR1872042A FR3089356B1 FR 3089356 B1 FR3089356 B1 FR 3089356B1 FR 1872042 A FR1872042 A FR 1872042A FR 1872042 A FR1872042 A FR 1872042A FR 3089356 B1 FR3089356 B1 FR 3089356B1
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accumulator
cathode
storage device
energy storage
manufacturing process
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FR1872042A
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FR3089356A1 (fr
Inventor
Pierre Guichard
Marie-Anne Blin
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ARMOR BATTERY FILMS, FR
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Armor SAS
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Priority to FR1872042A priority Critical patent/FR3089356B1/fr
Priority to US16/698,219 priority patent/US12494480B2/en
Priority to CN201911181285.2A priority patent/CN111244389A/zh
Priority to AU2019271962A priority patent/AU2019271962A1/en
Priority to JP2019215309A priority patent/JP7529397B2/ja
Priority to BR102019025127-1A priority patent/BR102019025127B1/pt
Priority to KR1020190155545A priority patent/KR102825685B1/ko
Priority to EP19212644.9A priority patent/EP3660954B1/fr
Priority to ES19212644T priority patent/ES2972663T3/es
Publication of FR3089356A1 publication Critical patent/FR3089356A1/fr
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/366—Composites as layered products
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/04—Construction or manufacture in general
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0404—Methods of deposition of the material by coating on electrode collectors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621—Binders
    • H01M4/622—Binders being polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621—Binders
    • H01M4/622—Binders being polymers
    • H01M4/623—Binders being polymers fluorinated polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/625—Carbon or graphite
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/66—Selection of materials
    • H01M4/661—Metal or alloys, e.g. alloy coatings
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/66—Selection of materials
    • H01M4/663—Selection of materials containing carbon or carbonaceous materials as conductive part, e.g. graphite, carbon fibres
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/66—Selection of materials
    • H01M4/665—Composites
    • H01M4/667—Composites in the form of layers, e.g. coatings
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/027—Negative electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028—Positive electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Cell Electrode Carriers And Collectors (AREA)
  • Secondary Cells (AREA)
  • Electric Double-Layer Capacitors Or The Like (AREA)

Abstract

Cathode pour accumulateur électrochimique, accumulateur, dispositif de stockage d’énergie et procédé de fabrication associés L’invention concerne une cathode (16) pour accumulateur électrochimique comportant : - un collecteur de courant (22), - une couche d’interfaçage (20), la couche d’interfaçage (20) étant enduite sur le collecteur de courant (22), et - une électrode (18), l’électrode étant formée par dépôt, notamment par enduction, d’une première composition sur la couche d’interfaçage (20), la première composition présentant un potentiel hydrogène supérieur ou égal à 10, de préférence supérieur ou égal à 12, le potentiel hydrogène étant mesuré à une température de 25°C. Figure pour l'abrégé : Figure 2
FR1872042A 2018-11-29 2018-11-29 Cathode pour accumulateur électrochimique, accumulateur, dispositif de stockage d’énergie et procédé de fabrication associés Active FR3089356B1 (fr)

Priority Applications (9)

Application Number Priority Date Filing Date Title
FR1872042A FR3089356B1 (fr) 2018-11-29 2018-11-29 Cathode pour accumulateur électrochimique, accumulateur, dispositif de stockage d’énergie et procédé de fabrication associés
CN201911181285.2A CN111244389A (zh) 2018-11-29 2019-11-27 电化学蓄电体的阴极和相关蓄电体、储能装置和制造方法
AU2019271962A AU2019271962A1 (en) 2018-11-29 2019-11-27 Cathode for electrochemical accumulator and associated accumulator, energy storage device and manufacturing method
US16/698,219 US12494480B2 (en) 2018-11-29 2019-11-27 Cathode for electrochemical accumulator and associated accumulator, energy storage device and manufacturing method
JP2019215309A JP7529397B2 (ja) 2018-11-29 2019-11-28 電気化学蓄電池用のカソード及び関連した蓄電池、エネルギー貯蔵装置、並びに製造する方法
BR102019025127-1A BR102019025127B1 (pt) 2018-11-29 2019-11-28 Catodo para acumulador eletroquímico, acumulador eletroquímico, dispositivo de armazenamento de energia e método de fabricação de um catodo para um acumulador eletroquímico
KR1020190155545A KR102825685B1 (ko) 2018-11-29 2019-11-28 전기화학 축전지 및 연관된 축전지용 캐소드, 에너지 저장 장치 및 제조 방법
EP19212644.9A EP3660954B1 (fr) 2018-11-29 2019-11-29 Cathode pour accumulateur électrochimique, accumulateur, dispositif de stockage d'énergie et procédé de fabrication associés
ES19212644T ES2972663T3 (es) 2018-11-29 2019-11-29 Cátodo para un acumulador electroquímico, acumulador, dispositivo de almacenamiento de energía y procedimiento de fabricación asociados

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1872042A FR3089356B1 (fr) 2018-11-29 2018-11-29 Cathode pour accumulateur électrochimique, accumulateur, dispositif de stockage d’énergie et procédé de fabrication associés

Publications (2)

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FR3089356A1 FR3089356A1 (fr) 2020-06-05
FR3089356B1 true FR3089356B1 (fr) 2021-04-02

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US (1) US12494480B2 (fr)
EP (1) EP3660954B1 (fr)
JP (1) JP7529397B2 (fr)
KR (1) KR102825685B1 (fr)
CN (1) CN111244389A (fr)
AU (1) AU2019271962A1 (fr)
ES (1) ES2972663T3 (fr)
FR (1) FR3089356B1 (fr)

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KR20240110664A (ko) * 2021-12-02 2024-07-15 쥐알에스티 인터내셔널 리미티드 2차 전지용 변형된 집전체

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JP3959708B2 (ja) * 2001-11-19 2007-08-15 株式会社デンソー リチウム電池用正極の製造方法およびリチウム電池用正極
JP2011501383A (ja) * 2007-10-26 2011-01-06 サイオン パワー コーポレイション バッテリ電極用プライマー
KR101147601B1 (ko) * 2008-12-17 2012-05-21 주식회사 엘지화학 표면이 개질되어 있는 양극 활물질
KR101171734B1 (ko) * 2009-04-01 2012-08-07 주식회사 엘지화학 리튬 이차전지용 양극 활물질
WO2011028251A2 (fr) * 2009-08-24 2011-03-10 Sion Power Corporation Système de démoulage pour cellules électrochimiques
KR101513821B1 (ko) * 2010-10-21 2015-04-20 도요타지도샤가부시키가이샤 전지용 전극 및 그 이용
KR101593767B1 (ko) 2011-02-23 2016-02-12 다이니치 세이카 고교 가부시키가이샤 수성 액상 조성물, 수성 도공액, 기능성 도공막 및 복합재료
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KR102209822B1 (ko) * 2014-01-28 2021-01-29 삼성에스디아이 주식회사 양극, 이를 채용한 리튬전지 및 양극제조방법
CN108292759B (zh) * 2015-09-14 2020-10-30 纳米技术仪器公司 具有高体积能量密度和重量能量密度的碱金属或碱离子电池
WO2017138192A1 (fr) * 2016-02-08 2017-08-17 国立研究開発法人産業技術総合研究所 Procédé de production de suspension d'électrode positive de batterie secondaire à électrolyte non aqueux et suspension d'électrode positive de batterie secondaire à électrolyte non aqueux
KR20180022161A (ko) * 2016-08-23 2018-03-06 삼성에스디아이 주식회사 리튬 이차 전지용 양극 활물질, 이의 제조 방법 및 이를 포함하는 리튬 이차 전지
JP2018060604A (ja) 2016-09-30 2018-04-12 日立オートモティブシステムズ株式会社 リチウムイオン二次電池
JPWO2018180742A1 (ja) * 2017-03-30 2020-02-06 昭和電工株式会社 リチウムイオン二次電池用正極およびリチウムイオン二次電池
JP7078464B2 (ja) 2018-06-14 2022-05-31 株式会社Subaru ナビゲーションシステム、ナビゲーション方法及び航空機

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Publication number Publication date
JP7529397B2 (ja) 2024-08-06
KR20200064940A (ko) 2020-06-08
BR102019025127A2 (pt) 2020-06-09
ES2972663T3 (es) 2024-06-13
US20200176765A1 (en) 2020-06-04
US12494480B2 (en) 2025-12-09
FR3089356A1 (fr) 2020-06-05
EP3660954C0 (fr) 2024-01-24
EP3660954B1 (fr) 2024-01-24
KR102825685B1 (ko) 2025-06-26
AU2019271962A1 (en) 2020-06-18
EP3660954A1 (fr) 2020-06-03
JP2020087934A (ja) 2020-06-04
CN111244389A (zh) 2020-06-05

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