FR3065649B1 - Monolithe poreux contenant du tio2 et son procede de preparation - Google Patents

Monolithe poreux contenant du tio2 et son procede de preparation Download PDF

Info

Publication number
FR3065649B1
FR3065649B1 FR1753757A FR1753757A FR3065649B1 FR 3065649 B1 FR3065649 B1 FR 3065649B1 FR 1753757 A FR1753757 A FR 1753757A FR 1753757 A FR1753757 A FR 1753757A FR 3065649 B1 FR3065649 B1 FR 3065649B1
Authority
FR
France
Prior art keywords
porous
monolithe
preparing same
containing tio2
monolith
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR1753757A
Other languages
English (en)
Other versions
FR3065649A1 (fr
Inventor
Sophie Bernadet
Antoine Fecant
Denis Uzio
Renal Backov
Serge Ravaine
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1753757A priority Critical patent/FR3065649B1/fr
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to JP2019557592A priority patent/JP7203755B2/ja
Priority to AU2018258982A priority patent/AU2018258982A1/en
Priority to EP18724473.6A priority patent/EP3615210A1/fr
Priority to US16/608,312 priority patent/US11077427B2/en
Priority to CN201880027993.8A priority patent/CN110545917A/zh
Priority to PCT/EP2018/060376 priority patent/WO2018197432A1/fr
Publication of FR3065649A1 publication Critical patent/FR3065649A1/fr
Application granted granted Critical
Publication of FR3065649B1 publication Critical patent/FR3065649B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/85—Coating or impregnation with inorganic materials
    • C04B41/87—Ceramics
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B01J35/31—
    • B01J35/39—
    • B01J35/56—
    • B01J35/60—
    • B01J35/615—
    • B01J35/617—
    • B01J35/633—
    • B01J35/635—
    • B01J35/638—
    • B01J35/643—
    • B01J35/647—
    • B01J35/653—
    • B01J35/657—
    • B01J35/69—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/04—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of inorganic compounds, e.g. ammonia
    • C01B3/042—Decomposition of water
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/0045—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by a process involving the formation of a sol or a gel, e.g. sol-gel or precipitation processes
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/0051—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof characterised by the pore size, pore shape or kind of porosity
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/0051—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof characterised by the pore size, pore shape or kind of porosity
    • C04B38/0058—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof characterised by the pore size, pore shape or kind of porosity open porosity
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/0067—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof characterised by the density of the end product
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/007—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof characterised by the pore distribution, e.g. inhomogeneous distribution of pores
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5025—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with ceramic materials
    • C04B41/5041—Titanium oxide or titanates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0081—Uses not provided for elsewhere in C04B2111/00 as catalysts or catalyst carriers
    • C04B2111/00827—Photocatalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Abstract

Monolithe poreux comprenant entre 20% et 70% en poids de TiO2 par rapport au poids total du monolithe, entre 30% et 80% en poids d'un oxyde réfractaire choisi parmi la silice, l'alumine ou la silice-alumine par rapport au poids total du monolithe, caractérisé en ce que ledit monolithe poreux comprend une densité apparente inférieure à 0,19 g/mL.
FR1753757A 2017-04-28 2017-04-28 Monolithe poreux contenant du tio2 et son procede de preparation Expired - Fee Related FR3065649B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR1753757A FR3065649B1 (fr) 2017-04-28 2017-04-28 Monolithe poreux contenant du tio2 et son procede de preparation
AU2018258982A AU2018258982A1 (en) 2017-04-28 2018-04-23 Porous monolith containing TiO2 and method for the production thereof
EP18724473.6A EP3615210A1 (fr) 2017-04-28 2018-04-23 Monolithe poreux contenant du tio2 et son procédé de preparation
US16/608,312 US11077427B2 (en) 2017-04-28 2018-04-23 Porous monolith containing TiO2 and method for the production thereof
JP2019557592A JP7203755B2 (ja) 2017-04-28 2018-04-23 ＴｉＯ２を含有している細孔性モノリスおよびその製造方法
CN201880027993.8A CN110545917A (zh) 2017-04-28 2018-04-23 含有TiO2的多孔整料及其生产方法
PCT/EP2018/060376 WO2018197432A1 (fr) 2017-04-28 2018-04-23 MONOLITHE POREUX CONTENANT DU TiO2 ET SON PROCEDE DE PREPARATION

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1753757 2017-04-28
FR1753757A FR3065649B1 (fr) 2017-04-28 2017-04-28 Monolithe poreux contenant du tio2 et son procede de preparation

Publications (2)

Publication Number Publication Date
FR3065649A1 FR3065649A1 (fr) 2018-11-02
FR3065649B1 true FR3065649B1 (fr) 2020-05-29

Family

ID=59381453

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1753757A Expired - Fee Related FR3065649B1 (fr) 2017-04-28 2017-04-28 Monolithe poreux contenant du tio2 et son procede de preparation

Country Status (7)

Country Link
US (1) US11077427B2 (fr)
EP (1) EP3615210A1 (fr)
JP (1) JP7203755B2 (fr)
CN (1) CN110545917A (fr)
AU (1) AU2018258982A1 (fr)
FR (1) FR3065649B1 (fr)
WO (1) WO2018197432A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110038595A (zh) * 2019-03-28 2019-07-23 昆明理工大学 一种Cr、S共掺杂TiO2纳米粉体的制备方法
FR3115219B1 (fr) 2020-10-15 2023-07-14 Ifp Energies Now Lit catalytique comprenant un catalyseur photocatalytique particulaire

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2199541A (en) 1986-10-16 1988-07-13 Rig Design Services Production of engineering drawings
CN1030601C (zh) * 1992-08-17 1996-01-03 中国石油化工总公司 低密度、大孔容、高强度氧化铝载体的制备方法
US5322821A (en) 1993-08-23 1994-06-21 W. R. Grace & Co.-Conn. Porous ceramic beads
JP2008105905A (ja) * 2006-10-26 2008-05-08 Matsushita Electric Ind Co Ltd 水の光分解装置
JP4939319B2 (ja) * 2007-06-29 2012-05-23 信越石英株式会社 多孔質光触媒体の製造方法及び多孔質光触媒体並びに浄化装置
FR2919811B1 (fr) 2007-08-08 2010-10-15 Saint Gobain Quartz Sas Media pour filtre photocatalytique
CN101722052A (zh) * 2008-10-15 2010-06-09 赢创德固赛有限责任公司 催化剂载体
FR2937970B1 (fr) * 2008-10-30 2012-06-15 Univ Paris Curie Procede de preparation d'un monolithe de carbone ou de ceramique alveolaire comportant un reseau poreux hierarchise
CA2755648A1 (fr) * 2009-03-16 2010-09-23 Basf Se Support de catalyseur a base de gel de silice
CN101974314B (zh) * 2010-09-29 2013-03-27 北京航空航天大学 隔热材料用二氧化硅基多孔块材及其包覆-干压成型的制备方法
FR2975309A1 (fr) 2011-05-19 2012-11-23 Centre Nat Rech Scient Monolithe macrocellulaire de dioxyde de titane, procede de preparation, utilisation a titre de photocatalyseur et procede de decontamination
FR3011547B1 (fr) * 2013-10-03 2015-12-11 Centre Nat Rech Scient Materiau composite solide alveolaire comportant des nanoparticules metalliques, procede de preparation et utilisations pour le stockage reversible de l'hydrogene
FR3016813B1 (fr) 2014-01-27 2017-11-24 Total Sa Materiau a base de ti02 absorbant dans le visible et procede pour sa fabrication
CN103861574B (zh) * 2014-02-28 2015-11-04 中国海洋石油总公司 一种钛硅复合氧化物的制备方法
CN104150525B (zh) * 2014-08-21 2016-05-18 安徽理工大学 氧化物多孔材料及其普适性制备方法
JP2016143742A (ja) * 2015-01-30 2016-08-08 シャープ株式会社 波長変換部材、発光装置、および波長変換部材の製造方法

Also Published As

Publication number Publication date
AU2018258982A1 (en) 2019-10-17
CN110545917A (zh) 2019-12-06
FR3065649A1 (fr) 2018-11-02
US11077427B2 (en) 2021-08-03
JP7203755B2 (ja) 2023-01-13
WO2018197432A1 (fr) 2018-11-01
US20210101133A1 (en) 2021-04-08
EP3615210A1 (fr) 2020-03-04
JP2020517443A (ja) 2020-06-18

Similar Documents

Publication Publication Date Title
Kretschmer et al. Differential expansion of T central memory precursor and effector subsets is regulated by division speed
Sun et al. CD4+ T cells are required for the maintenance, not programming, of memory CD8+ T cells after acute infection
Lotfi et al. Human mesenchymal stem cells respond to native but not oxidized damage associated molecular pattern molecules from necrotic (tumor) material
PH12017500918A1 (en) Antibodies against cd73 and uses thereof
PH12014502280A1 (en) Indole and indazole compounds that activate ampk
SG163554A1 (en) Human monoclonal antibodies to programmed death ligand 1 (pd-l1)
TW200801013A (en) Substituted benzofused derivatives and their use as vanilloid receptor ligands
DE60224843D1 (de) Herstellung von viren, virusisolaten, und impfstoffen
FR3065649B1 (fr) Monolithe poreux contenant du tio2 et son procede de preparation
EA200601894A1 (ru) Производные пиперазинилпиперидина в качестве антагонистов хемокинового рецептора
MA33276B1 (fr) Anticorps spécifiques à la cadhérine-17
MA30954B1 (fr) Procede de generation d'anticorps actifs contre un antigene de resistance, anticorps obtenus par ce procede et utilisations de ces anticorps
MX2021013774A (es) Compuestos anticancerigenos dirigidos a los receptores hormonales nucleares.
WO2018104909A3 (fr) Profilage de méthylation de l'adn pour immunothérapie par lymphocytes t
MX2022003365A (es) Anticuerpos de un solo dominio dirigidos contra lilrb2.
FR3034430A1 (fr) Lignee cellulaire surexprimant l'antigene cd303 humain
Bhat et al. Arenavirus induced CCL5 expression causes NK cell-mediated melanoma regression
MA41956B1 (fr) Système de revêtement, son utilisation pour revêtir des pièces et pièces ainsi revêtues pour des véhicules ferroviaires et aériens
MX2020012613A (es) Composiciones y usos de las mismas para el tratamiento de enfermedades o afecciones.
MX2018013072A (es) Anticuerpos del ligando similar al factor de necrosis tumoral 1a (tl1a) y usos de los mismos.
BR112023000501A2 (pt) Partículas de lapatinibe e usos das mesmas
NO20082919L (no) Heteroringsubstituerte 3-alkylazetidinderivater
Mishra et al. NK cells and virus-related cancers
CR20240074A (es) Anticuerpos anti-receptor de quimiocinas de motivo c-c 8 (ccr8) y métodos de uso
FR2998488B1 (fr) Catalyseur d hydrotraitement a partir d alumine gel et methode de preparation d un tel catalyseur

Legal Events

Date Code Title Description
PLFP Fee payment

Year of fee payment: 2

PLSC Publication of the preliminary search report

Effective date: 20181102

PLFP Fee payment

Year of fee payment: 3

PLFP Fee payment

Year of fee payment: 4

PLFP Fee payment

Year of fee payment: 5

PLFP Fee payment

Year of fee payment: 6

ST Notification of lapse

Effective date: 20231205