FR3044012B1 - Liant permettant de fixer un materiau contenant du poly fluorure de vinylidene sur un metal - electrode pour batterie lithium-ion associee - Google Patents

Liant permettant de fixer un materiau contenant du poly fluorure de vinylidene sur un metal - electrode pour batterie lithium-ion associee Download PDF

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Publication number
FR3044012B1
FR3044012B1 FR1561286A FR1561286A FR3044012B1 FR 3044012 B1 FR3044012 B1 FR 3044012B1 FR 1561286 A FR1561286 A FR 1561286A FR 1561286 A FR1561286 A FR 1561286A FR 3044012 B1 FR3044012 B1 FR 3044012B1
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France
Prior art keywords
binder
ion battery
electrode
metal
lithium ion
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Active
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FR1561286A
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English (en)
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FR3044012A1 (fr
Inventor
Stephane Bizet
Anthony Bonnet
Jerôme Chauveau
Nadine Rivas
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Arkema France SA
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Arkema France SA
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Priority to FR1561286A priority Critical patent/FR3044012B1/fr
Application filed by Arkema France SA filed Critical Arkema France SA
Priority to PL16815585T priority patent/PL3380575T3/pl
Priority to US15/778,466 priority patent/US10717890B2/en
Priority to KR1020187017737A priority patent/KR102698367B1/ko
Priority to CN201680068873.3A priority patent/CN108291106B/zh
Priority to EP16815585.1A priority patent/EP3380575B1/fr
Priority to HUE16815585A priority patent/HUE046041T2/hu
Priority to JP2018545698A priority patent/JP6856658B2/ja
Priority to PCT/FR2016/052996 priority patent/WO2017089683A1/fr
Publication of FR3044012A1 publication Critical patent/FR3044012A1/fr
Application granted granted Critical
Publication of FR3044012B1 publication Critical patent/FR3044012B1/fr
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C09D127/16—Homopolymers or copolymers of vinylidene fluoride
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621—Binders
    • H01M4/622—Binders being polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08L27/16—Homopolymers or copolymers or vinylidene fluoride
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/24—Electrically-conducting paints
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621—Binders
    • H01M4/622—Binders being polymers
    • H01M4/623—Binders being polymers fluorinated polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/625—Carbon or graphite
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/66—Selection of materials
    • H01M4/661—Metal or alloys, e.g. alloy coatings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2203—Oxides; Hydroxides of metals of lithium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Cell Electrode Carriers And Collectors (AREA)

Abstract

La présente invention concerne un liant utilisable dans une batterie lithium-ion et comprenant au moins un polymère de fluorure de vinylidène et au moins un copolymère acrylique comportant des monomères ayant des groupements fonctionnels présentant une affinité pour les métaux ou aptes à se fixer sur les métaux. Selon l'invention, de manière caractéristique, ledit polymère de fluorure de vinylidène est tel qu'une solution de N-méthyl-2-pyrrolidone contenant 5% en masse dudit polymère de fluorure de vinylidène présente une viscosité, mesurée à 23°C avec une vitesse de cisaillement imposée de 30 tours/min, allant de 125 mPa. à 1500 mPa.s.
FR1561286A 2015-11-24 2015-11-24 Liant permettant de fixer un materiau contenant du poly fluorure de vinylidene sur un metal - electrode pour batterie lithium-ion associee Active FR3044012B1 (fr)

Priority Applications (9)

Application Number Priority Date Filing Date Title
FR1561286A FR3044012B1 (fr) 2015-11-24 2015-11-24 Liant permettant de fixer un materiau contenant du poly fluorure de vinylidene sur un metal - electrode pour batterie lithium-ion associee
US15/778,466 US10717890B2 (en) 2015-11-24 2016-11-17 Binder containing polyvinylidene fluoride capable of fixing to a metal and associated lithium-ion battery electrode
KR1020187017737A KR102698367B1 (ko) 2015-11-24 2016-11-17 금속에 고정될 수 있는 폴리비닐리덴 플루오라이드를 함유하는 바인더 및 관련 리튬-이온 배터리 전극
CN201680068873.3A CN108291106B (zh) 2015-11-24 2016-11-17 含有聚偏二氟乙烯的能够固定到金属上的粘合剂和相关的锂离子电池电极
PL16815585T PL3380575T3 (pl) 2015-11-24 2016-11-17 Spoiwo zawierające polifluorek winylidenu zdolne do wiązania się na metalu i elektroda do stosownej baterii litowo-jonowej
EP16815585.1A EP3380575B1 (fr) 2015-11-24 2016-11-17 Liant contenant du poly fluorure de vinylidène capable de se fixer sur un métal et electrode pour batterie lithium-ion associée
HUE16815585A HUE046041T2 (hu) 2015-11-24 2016-11-17 Fémre rögzíteni képes, polivinilidén-fluoridot tartalmazó kötõanyag és elektród lítium-ion akkumulátorokhoz
JP2018545698A JP6856658B2 (ja) 2015-11-24 2016-11-17 金属への固定が可能なポリビニリデンフルオライドを含有するバインダー及び関連するリチウムイオンバッテリー用電極
PCT/FR2016/052996 WO2017089683A1 (fr) 2015-11-24 2016-11-17 Liant contenant du poly fluorure de vinylidène capable de se fixer sur un métal et electrode pour batterie lithium-ion associée

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1561286 2015-11-24
FR1561286A FR3044012B1 (fr) 2015-11-24 2015-11-24 Liant permettant de fixer un materiau contenant du poly fluorure de vinylidene sur un metal - electrode pour batterie lithium-ion associee

Publications (2)

Publication Number Publication Date
FR3044012A1 FR3044012A1 (fr) 2017-05-26
FR3044012B1 true FR3044012B1 (fr) 2019-04-05

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FR1561286A Active FR3044012B1 (fr) 2015-11-24 2015-11-24 Liant permettant de fixer un materiau contenant du poly fluorure de vinylidene sur un metal - electrode pour batterie lithium-ion associee

Country Status (9)

Country Link
US (1) US10717890B2 (fr)
EP (1) EP3380575B1 (fr)
JP (1) JP6856658B2 (fr)
KR (1) KR102698367B1 (fr)
CN (1) CN108291106B (fr)
FR (1) FR3044012B1 (fr)
HU (1) HUE046041T2 (fr)
PL (1) PL3380575T3 (fr)
WO (1) WO2017089683A1 (fr)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3106702B1 (fr) * 2020-01-29 2022-10-07 Arkema France Formulation d’electrode pour batterie li-ion et procede de fabrication d’electrode sans solvant
CN112103509B (zh) * 2020-08-20 2023-06-06 欣旺达电动汽车电池有限公司 正极集流体、正极片、锂离子电池及电池模组
KR102864401B1 (ko) * 2021-03-26 2025-09-24 주식회사 엘지에너지솔루션 리튬 이차전지용 양극 및 리튬 이차전지
JP2024516671A (ja) * 2021-04-29 2024-04-16 アーケマ・インコーポレイテッド 電気化学デバイスのバインダーとしてのフルオロポリマーと官能性アクリルポリマーのブレンド
US20240317913A1 (en) * 2021-04-29 2024-09-26 Trinseo Europe Gmbh High heat acrylic copolymers containing a functional comonomer as binders for batteries
CN119343783A (zh) 2022-04-12 2025-01-21 索尔维特殊聚合物意大利有限公司 用于锂离子电池的正电极粘合剂
CN120814057A (zh) 2023-03-09 2025-10-17 世索科特殊聚合物意大利有限公司 电池电极及其制造方法
CN121464504A (zh) 2023-05-05 2026-02-03 世索科特殊聚合物意大利有限公司 用于锂离子电池的正电极粘合剂
WO2025082898A1 (fr) 2023-10-16 2025-04-24 Solvay Specialty Polymers Italy S.P.A. Liants d'électrodes de batteries secondaires
WO2026022130A1 (fr) 2024-07-26 2026-01-29 Specialty Operations France Membranes souples
WO2026022129A1 (fr) 2024-07-26 2026-01-29 Specialty Operations France Liants d'électrode de batteries au lithium

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CA2243354A1 (fr) 1996-01-22 1997-07-31 Yoshiyuki Shimonishi Procede pour l'adherence de resines fluorees a des metaux
JPH09231977A (ja) 1996-02-27 1997-09-05 Elf Atochem Japan Kk 電極およびその製法
WO1997049777A2 (fr) 1996-06-26 1997-12-31 Elf Atochem S.A. Compositions de poly(fluorure de vinylidene) ayant des proprietes d'adhesion a un metal
JPH10306265A (ja) 1997-05-02 1998-11-17 Elf Atochem Japan Kk ポリフッ化ビニリデン系金属接着性組成物および電池用電極
JPH1145720A (ja) * 1997-07-25 1999-02-16 Hitachi Maxell Ltd リチウム二次電池
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Also Published As

Publication number Publication date
CN108291106A (zh) 2018-07-17
FR3044012A1 (fr) 2017-05-26
US20180355206A1 (en) 2018-12-13
KR20180081815A (ko) 2018-07-17
US10717890B2 (en) 2020-07-21
EP3380575A1 (fr) 2018-10-03
CN108291106B (zh) 2021-01-05
WO2017089683A1 (fr) 2017-06-01
JP6856658B2 (ja) 2021-04-07
KR102698367B1 (ko) 2024-08-22
HUE046041T2 (hu) 2020-01-28
EP3380575B1 (fr) 2019-09-25
PL3380575T3 (pl) 2020-03-31
JP2018535533A (ja) 2018-11-29

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