FR3035880B1 - Utilisation de nouveaux composes pour l'extraction selective de terres rares de solutions aqueuses comprenant de l'acide phosphorique et procede d'extraction associe - Google Patents
Utilisation de nouveaux composes pour l'extraction selective de terres rares de solutions aqueuses comprenant de l'acide phosphorique et procede d'extraction associeInfo
- Publication number
- FR3035880B1 FR3035880B1 FR1554119A FR1554119A FR3035880B1 FR 3035880 B1 FR3035880 B1 FR 3035880B1 FR 1554119 A FR1554119 A FR 1554119A FR 1554119 A FR1554119 A FR 1554119A FR 3035880 B1 FR3035880 B1 FR 3035880B1
- Authority
- FR
- France
- Prior art keywords
- extracting
- phosphoric acid
- aqueous solutions
- same
- novel compounds
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 title 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 title 1
- 239000007864 aqueous solution Substances 0.000 title 1
- 150000001875 compounds Chemical class 0.000 title 1
- 238000000605 extraction Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
- C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B59/00—Obtaining rare earth metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Metallurgy (AREA)
- Geology (AREA)
- Environmental & Geological Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Geochemistry & Mineralogy (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Extraction Or Liquid Replacement (AREA)
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1554119A FR3035880B1 (fr) | 2015-05-07 | 2015-05-07 | Utilisation de nouveaux composes pour l'extraction selective de terres rares de solutions aqueuses comprenant de l'acide phosphorique et procede d'extraction associe |
RU2017142529A RU2718439C2 (ru) | 2015-05-07 | 2016-05-03 | Применение новых соединений для селективного экстрагирования редкоземельных металлов из водных растворов, содержащих фосфорную кислоту, и соответствующий способ экстракции |
CN201680026542.3A CN107636178B (zh) | 2015-05-07 | 2016-05-03 | 新颖化合物从含磷酸的水溶液中选择性萃取稀土元素的用途及相关萃取方法 |
PCT/EP2016/059827 WO2016177695A1 (fr) | 2015-05-07 | 2016-05-03 | Utilisation de nouveaux composés pour l'extraction sélective de terres rares de solutions aqueuses comprenant de l'acide phosphorique et procédé d'extraction associé |
BR112017023820-9A BR112017023820B1 (pt) | 2015-05-07 | 2016-05-03 | Uso de pelo menos um composto, método de recuperação de pelo menos uma terra rara e compostos da fórmula específica |
MA41356A MA41356B1 (fr) | 2015-05-07 | 2016-05-03 | Utilisation de nouveaux composés pour l'extraction sélective de terres rares de solutions aqueuses comprenant de l'acide phosphorique et procédé d'extraction associé |
US15/571,967 US10450629B2 (en) | 2015-05-07 | 2016-05-03 | Use of novel compounds for selectively extracting rare earths from aqueous solutions including phosphoric acid and associated extraction method |
AU2016258868A AU2016258868B2 (en) | 2015-05-07 | 2016-05-03 | Use of novel compounds for selectively extracting rare earths from aqueous solutions including phosphoric acid and associated extraction method |
CA2984579A CA2984579C (fr) | 2015-05-07 | 2016-05-03 | Utilisation de composes pour l'extraction selective de terres rares de solutions aqueuses comprenant de l'acide phosphorique et procede d'extraction associe |
US16/559,972 US10934604B2 (en) | 2015-05-07 | 2019-09-04 | Use of novel compounds for selectively extracting rare earths from aqueous solutions including phosphoric acid and associated extraction method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1554119A FR3035880B1 (fr) | 2015-05-07 | 2015-05-07 | Utilisation de nouveaux composes pour l'extraction selective de terres rares de solutions aqueuses comprenant de l'acide phosphorique et procede d'extraction associe |
Publications (2)
Publication Number | Publication Date |
---|---|
FR3035880A1 FR3035880A1 (fr) | 2016-11-11 |
FR3035880B1 true FR3035880B1 (fr) | 2017-06-02 |
Family
ID=54014955
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR1554119A Active FR3035880B1 (fr) | 2015-05-07 | 2015-05-07 | Utilisation de nouveaux composes pour l'extraction selective de terres rares de solutions aqueuses comprenant de l'acide phosphorique et procede d'extraction associe |
Country Status (9)
Country | Link |
---|---|
US (2) | US10450629B2 (fr) |
CN (1) | CN107636178B (fr) |
AU (1) | AU2016258868B2 (fr) |
BR (1) | BR112017023820B1 (fr) |
CA (1) | CA2984579C (fr) |
FR (1) | FR3035880B1 (fr) |
MA (1) | MA41356B1 (fr) |
RU (1) | RU2718439C2 (fr) |
WO (1) | WO2016177695A1 (fr) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR3055906B1 (fr) | 2016-09-15 | 2018-09-28 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | Nouvel extractant, utile pour extraire des terres rares d'une solution aqueuse d'acide phosphorique, et ses applications |
FR3086302B1 (fr) | 2018-09-26 | 2020-12-25 | Commissariat Energie Atomique | Utilisation d'un melange synergique d'extractants pour extraire des terres rares d'un milieu aqueux comprenant de l'acide phosphorique |
CN110029371A (zh) * | 2019-04-25 | 2019-07-19 | 江西自立环保科技有限公司 | 一种铜电解液开路铁离子的方法 |
CN111471860B (zh) * | 2020-06-17 | 2021-07-13 | 济南大学 | 一种利用酰胺荚醚萃取剂从混合稀土中分离镧铈的方法 |
CN111961849B (zh) * | 2020-09-02 | 2022-04-19 | 济南大学 | 一种萃取分离钪的方法 |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SU283588A1 (ru) * | 1969-03-24 | 1978-07-30 | Институт Физической Химии Ан Ссср | Способ экстракционного разделени редкоземельных элементов |
GB2101601B (en) * | 1981-05-28 | 1985-10-02 | Johnson Matthey Plc | Bisphosphine synthesis |
FR2515630B1 (fr) * | 1981-10-30 | 1985-10-04 | Rhone Poulenc Spec Chim | Procede d'extraction et de separation de l'uranium, du thorium et des terres rares par traitement de solutions aqueuses de chlorures de ces elements |
US4574072A (en) * | 1983-07-26 | 1986-03-04 | The United States Of America As Represented By The United States Department Of Energy | Method for extracting lanthanides and actinides from acid solutions by modification of purex solvent |
US4770807A (en) * | 1985-07-31 | 1988-09-13 | Commissariat A L'energie Atomique | Novel extraction agents and novel propane diamides |
FR2612911B1 (fr) * | 1987-03-23 | 1991-04-05 | Rhone Poulenc Chimie | Procede de separation des terres rares par extraction liquide-liquide |
RU2165653C1 (ru) * | 1999-08-09 | 2001-04-20 | Государственное унитарное предприятие Научно-производственное объединение "Радиевый институт им. В.Г. Хлопина" | Способ экстракционного извлечения трансплутониевых и редкоземельных элементов из кислых растворов и их разделения |
CN1298030A (zh) * | 1999-11-25 | 2001-06-06 | 罗狄亚稀土公司 | 稀土的液-液分离方法 |
RU2180868C2 (ru) * | 1999-12-07 | 2002-03-27 | Государственное унитарное предприятие Научно-производственное объединение "Радиевый институт им. В.Г. Хлопина" | Способ экстракционного выделения цезия, стронция, технеция, редкоземельных и актинидных элементов из жидких радиоактивных отходов |
EP1496063B1 (fr) * | 2002-03-04 | 2009-08-19 | Japan Science and Technology Agency | Procédé d'extraction des métaux de terres rares en utilisant un composé phosphonamide |
US7589196B2 (en) * | 2003-04-07 | 2009-09-15 | Solvias Ag | Amine-substituted biphenyldiphosphines |
RU2441087C1 (ru) * | 2010-12-30 | 2012-01-27 | Государственное образовательное учреждение высшего профессионального образования "Санкт-Петербургский государственный горный институт имени Г.В. Плеханова (технический университет)" | Способ экстракции редкоземельных элементов иттрия (iii), церия (iii) и эрбия (iii) из водных растворов |
CN102512848B (zh) * | 2011-12-07 | 2014-09-24 | 中国科学院过程工程研究所 | 一种大相比液液两相连续萃取装置 |
RU2544731C2 (ru) * | 2013-07-17 | 2015-03-20 | Федеральное государственное бюджетное учреждение науки Ордена Ленина и Ордена Октябрьской революции Институт геохимии и аналитической химии им. В.И. Вернадского Российской академии наук (ГЕОХИ РАН) | Способ извлечения редкоземельных элементов из экстракционной фосфорной кислоты |
CN103435649B (zh) * | 2013-07-31 | 2015-12-02 | 宁波大学 | 一种双齿膦功能化离子液体及其合成方法 |
CN103773954B (zh) * | 2014-01-27 | 2015-10-14 | 中国科学院长春应用化学研究所 | 中性磷酰胺萃取剂用于萃取分离Ce4+的用途 |
JP6573115B2 (ja) * | 2015-11-25 | 2019-09-11 | 国立研究開発法人日本原子力研究開発機構 | アミド化リン酸エステル化合物、抽出剤、及び抽出方法 |
-
2015
- 2015-05-07 FR FR1554119A patent/FR3035880B1/fr active Active
-
2016
- 2016-05-03 BR BR112017023820-9A patent/BR112017023820B1/pt active IP Right Grant
- 2016-05-03 MA MA41356A patent/MA41356B1/fr unknown
- 2016-05-03 CA CA2984579A patent/CA2984579C/fr active Active
- 2016-05-03 RU RU2017142529A patent/RU2718439C2/ru active
- 2016-05-03 CN CN201680026542.3A patent/CN107636178B/zh active Active
- 2016-05-03 AU AU2016258868A patent/AU2016258868B2/en active Active
- 2016-05-03 US US15/571,967 patent/US10450629B2/en active Active
- 2016-05-03 WO PCT/EP2016/059827 patent/WO2016177695A1/fr active Application Filing
-
2019
- 2019-09-04 US US16/559,972 patent/US10934604B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
US10450629B2 (en) | 2019-10-22 |
AU2016258868B2 (en) | 2021-04-01 |
MA41356B1 (fr) | 2019-12-31 |
RU2718439C2 (ru) | 2020-04-06 |
BR112017023820A2 (pt) | 2018-07-31 |
US20180142321A1 (en) | 2018-05-24 |
BR112017023820B1 (pt) | 2021-09-21 |
MA41356A1 (fr) | 2018-11-30 |
AU2016258868A1 (en) | 2017-11-30 |
US10934604B2 (en) | 2021-03-02 |
WO2016177695A1 (fr) | 2016-11-10 |
RU2017142529A3 (fr) | 2019-11-01 |
FR3035880A1 (fr) | 2016-11-11 |
CN107636178A (zh) | 2018-01-26 |
CA2984579C (fr) | 2023-12-12 |
CN107636178B (zh) | 2019-12-20 |
US20190390297A1 (en) | 2019-12-26 |
RU2017142529A (ru) | 2019-06-07 |
CA2984579A1 (fr) | 2016-11-10 |
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Legal Events
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Year of fee payment: 2 |
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