FR2980722B1 - Masse de captation a performances ameliorees et son utilisation dans la captation de metaux lourds - Google Patents

Masse de captation a performances ameliorees et son utilisation dans la captation de metaux lourds

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Publication number
FR2980722B1
FR2980722B1 FR1103016A FR1103016A FR2980722B1 FR 2980722 B1 FR2980722 B1 FR 2980722B1 FR 1103016 A FR1103016 A FR 1103016A FR 1103016 A FR1103016 A FR 1103016A FR 2980722 B1 FR2980722 B1 FR 2980722B1
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France
Prior art keywords
heavy metals
improved performance
capturing heavy
captation
mass
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1103016A
Other languages
English (en)
Other versions
FR2980722A1 (fr
Inventor
Fabien Porcheron
Karin Barthelet
Arnaud Baudot
Antoine Daudin
Marc Antoine Lelias
Yannick Gelie
Alexandre Nicolaos
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR1103016A priority Critical patent/FR2980722B1/fr
Priority to PCT/FR2012/000361 priority patent/WO2013050667A1/fr
Priority to GB1407446.2A priority patent/GB2514916B/en
Priority to US14/349,081 priority patent/US9561487B2/en
Publication of FR2980722A1 publication Critical patent/FR2980722A1/fr
Application granted granted Critical
Publication of FR2980722B1 publication Critical patent/FR2980722B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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FR1103016A 2011-10-04 2011-10-04 Masse de captation a performances ameliorees et son utilisation dans la captation de metaux lourds Active FR2980722B1 (fr)

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FR1103016A FR2980722B1 (fr) 2011-10-04 2011-10-04 Masse de captation a performances ameliorees et son utilisation dans la captation de metaux lourds
PCT/FR2012/000361 WO2013050667A1 (fr) 2011-10-04 2012-09-12 Masse de captation a performances ameliorees et son utilisation dans la captation de metaux lourds
GB1407446.2A GB2514916B (en) 2011-10-04 2012-09-12 Capture mass with improved performance, and its use in the capture of heavy metals
US14/349,081 US9561487B2 (en) 2011-10-04 2012-09-12 Performance trapping mass and use thereof in heavy metal trapping

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FR1103016A FR2980722B1 (fr) 2011-10-04 2011-10-04 Masse de captation a performances ameliorees et son utilisation dans la captation de metaux lourds

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US8734740B1 (en) * 2013-03-15 2014-05-27 Clariant Corporation Process and composition for removal of arsenic and other contaminants from synthetic gas
FR3022155A1 (fr) * 2014-06-13 2015-12-18 IFP Energies Nouvelles Masse de captation a porosite trimodale pour la captation des metaux lourds.
FR3039161B1 (fr) 2015-07-24 2019-01-25 IFP Energies Nouvelles Procede de traitement de coupes hydrocarbures comprenant du mercure
FR3039164B1 (fr) 2015-07-24 2019-01-25 IFP Energies Nouvelles Procede d'elimination de mercure d'une charge hydrocarbonee lourde en amont d'une unite de fractionnement
FR3052686B1 (fr) * 2016-06-21 2020-01-17 IFP Energies Nouvelles Masse de captation de metaux lourds a performances ameliorees
FR3053260B1 (fr) * 2016-06-30 2020-12-11 Ifp Energies Now Masse de captation constitue d'une phase active sous forme cristalline
FR3130636A1 (fr) 2021-12-20 2023-06-23 IFP Energies Nouvelles Procede de rejuvenation de masses de captation de metaux lourds
FR3130635A1 (fr) 2021-12-20 2023-06-23 IFP Energies Nouvelles Procede de captation de metaux lourds par co-alimentation d’un flux sulfurant

Family Cites Families (12)

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DE1224287B (de) * 1963-09-23 1966-09-08 Grace W R & Co Verfahren zur Herstellung eines Tonerdegels
DE2656803C2 (de) * 1975-12-18 1986-12-18 Institut Français du Pétrole, Rueil-Malmaison, Hauts-de-Seine Verfahren zur Entfernung von in einem Gas oder in einer Flüssigkeit vorhandenem Quecksilber
FR2335257A2 (fr) * 1975-12-18 1977-07-15 Inst Francais Du Petrole Procede d'elimination du mercure present dans un gaz ou un liquide par absorption sur une masse solide contenant un support et un metal capable de former un alliage avec le mercure
SU967546A1 (ru) * 1980-01-24 1982-10-23 Воронежский технологический институт Способ получени неорганического сорбента
FR2764214B1 (fr) * 1997-06-10 1999-07-16 Inst Francais Du Petrole Procede et masses de captation pour l'elimination du mercure et de l'arsenic dans les coupes hydrocarbonees
US7645306B2 (en) 2007-12-13 2010-01-12 Uop Llc Removal of mercury from fluids by supported metal oxides
JP2012509758A (ja) * 2008-11-25 2012-04-26 ジョンソン、マッセイ、パブリック、リミテッド、カンパニー 重金属除去用還元型硫化銅収着剤
GB0914272D0 (en) * 2009-08-17 2009-09-30 Johnson Matthey Plc Sorbent
US8876952B2 (en) * 2012-02-06 2014-11-04 Uop Llc Method of removing mercury from a fluid stream using high capacity copper adsorbents
US9006508B2 (en) * 2012-02-06 2015-04-14 Uop Llc Protected adsorbents for mercury removal and method of making and using same
GB201213360D0 (en) * 2012-07-26 2012-09-12 Johnson Matthey Plc Process
AU2013270629B2 (en) * 2012-12-21 2017-10-19 IFP Energies Nouvelles Polymetallic capture mass for capturing heavy metals

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US20150034561A1 (en) 2015-02-05
GB2514916B (en) 2018-02-07
GB201407446D0 (en) 2014-06-11
FR2980722A1 (fr) 2013-04-05
US9561487B2 (en) 2017-02-07
GB2514916A (en) 2014-12-10
WO2013050667A1 (fr) 2013-04-11

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